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991.
A novel method is firstly presented for field and rapid analysis of short-chain aliphatic amines in water as their pentafluorobenzaldehyde (PFBAY) derivative using solid-phase microextraction (SPME) and portable GC. In the proposed method, short-chain aliphatic amines in water rapidly reacted with PFBAY, and then were headspace extracted and concentrated by SPME. The formed amines derivatives were analyzed by portable GC. The SPME parameters of fiber selection, extraction temperature, extraction time, and stirring rate were studied. The method validations including LOD, recovery, precision, and linearity were studied. It was found that the proposed method required the whole analysis time 22 min, and provided low LOD of 1.2-4.6 ng/mL, good recovery of 91-106%, good precision of RSD value 3.5-9.3%, and linear range 20.0-500 ng/mL (r(2) >0.99). The obtained results demonstrated that the SPME-portable GC is a simple, rapid, and efficient method for the field analysis of short-chain aliphatic amines. Finally, the proposed method was further applied to the quantification of ethylamine, propylamine, and butylamine in environmental water. 相似文献
992.
If A is a strongly noetherian graded algebra generated in degree one, then there is a canonically constructed graded ring homomorphism
from A to a twisted homogeneous coordinate ring , which is surjective in large degree. This result is a key step in the study of projectively simple rings. The proof relies
on some results concerning the growth of graded rings which are of independent interest.
D. Rogalski was partially supported by NSF grant DMS-0202479.
J. J. Zhang was partially supported by NSF grant DMS-0245420 and Leverhulme Research Interchange Grant F/00158/X (UK). 相似文献
993.
994.
Xuehou Tan 《Discrete Applied Mathematics》2008,156(17):3312-3324
Given a simple polygon P with two vertices u and v, the three-guard problem asks whether three guards can move from u to v such that the first and third guards are separately on two boundary chains of P from u to v and the second guard is always kept to be visible from two other guards inside P. It is a generalization of the well-known two-guard problem, in which two guards move on the boundary chains from u to v and are always kept to be mutually visible. In this paper, we introduce the concept of link-2-ray shots, which can be considered as ray shots under the notion of link-2-visibility. Then, we show a one-to-one correspondence between the structure of the restrictions placed on the motion of two guards and the one placed on the motion of three guards, and generalize the solution for the two-guard problem to that for the three-guard problem. We can decide whether there exists a solution for the three-guard problem in O(nlogn) time, and if so generate a walk in O(nlogn+m) time, where n denotes the number of vertices of P and the size of the optimal walk. This improves upon the previous time bounds O(n2) and O(n2logn), respectively. Moreover, our results can be used to solve other more sophisticated geometric problems. 相似文献
995.
Sumeet K. Sharma Parimal A. Parikh Raksh V. Jasra 《Journal of molecular catalysis. A, Chemical》2008,286(1-2):55-62
The catalytic activity of hydrotalcite ([M(II)1−xM(III)x(OH2)]x+(CO32−)x/n·mH2O; where M(II) = Mg, Ni, Zn and M(III) = Al) was evaluated for the synthesis of jasminaldehyde by solvent free condensation of 1-heptanal with benzaldehyde. The effect of activation of as-synthesized Mg-Al hydrotalcite samples of varied Mg/Al molar ratio on its catalytic activity was studied and correlated with their basicity as determined from the model test reaction. The effect of reaction parameters such as, amount of catalyst, benzaldehyde to 1-heptanal molar ratio and reaction temperature on conversion of 1-heptanal and selectivity of jasminaldehyde was studied in detail. Maximum selectivity of jasminaldehyde (86%) with 98% conversion of 1-heptanal was observed using as-synthesized Mg-Al hydrotalcite of Mg/Al molar ratio of 3.5 as a catalyst. The kinetics of the reaction was measured and reaction rate and order of reaction were determined under optimum reaction conditions. The catalyst was re-used upto three cycles without significant loss in its activity. The base catalyzed reaction mechanism for condensation of 1-heptanal with benzaldehyde is proposed. 相似文献
996.
Rolando Roque-Malherbe F. Diaz-Castro 《Journal of molecular catalysis. A, Chemical》2008,280(1-2):194-202
997.
Billes F Várady B 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2008,70(4):729-734
Infrared and Raman spectra of protoporphyrin IX were recorded. DFT quantum chemical calculations were performed. Optimised molecular geometry, electric charge distribution, vibrational force constants were computed. The normal coordinate analysis and the scaling of the force constants yielded all the necessary data for the simulation of the infrared and Raman spectra and the potential energy distribution calculations. The result was the interpretation of all vibrational modes of the molecule. Conclusions were drawn from the difficulties arisen during the assignment of the vibrational spectra of such large molecules. 相似文献
998.
A quaternary super-ion-conducting system, 20CdI2 − 80[xAg2O − y(0.7V2O5 − 0.3B2O3)] where 1 ≤ x/y ≤ 3, has been prepared by melt quenching technique. The electrical conductivity measured was the order of 10−4 S/cm at room temperature. The values of silver-ion transport number obtained by electromotive force technique are nearly
unity. The thermoelectric power and electrochemical studies were done on the CdI2–Ag2O–V2O5–B2O3 system. The discharge and polarization characteristics were examined for different cathodes to evaluate the utility of these
cells as power sources for low energy applications. 相似文献
999.
Araujo RG Oleszczuk N Rampazzo RT Costa PA Silva MM Vale MG Welz B Ferreira SL 《Talanta》2008,77(1):400-406
Two analytical methods for the determination of cadmium in wheat flour by electrothermal atomic absorption spectrometry without prior sample digestion have been compared: direct solid sampling analysis (SS) and slurry sampling (SlS). Besides the conventional modifier mixture of palladium and magnesium nitrates (10 μg Pd + 3 μg Mg), 0.05% (v/v) Triton X-100 has been added to improve the penetration of the modifier solution into the solid sample, and 0.1% H2O2 in order to promote an in situ digestion for SS. For SlS, 30 μg Pd, 12 μg Mg and 0.05% (v/v) Triton X-100 have been used as the modifier mixture. Under these conditions, and using a pyrolysis temperature of 800 °C, essentially no background absorption was observed with an atomization temperature of 1600 °C. About 2 mg of sample have been typically used for SS, although as much as 3-5 mg could have been introduced. In the case of SlS multiple injections had to be used to achieve the sensitivity required for this determination. Calibration against aqueous standards was feasible for both methods. The characteristic mass obtained with SS was 0.6 pg, and that with SlS was 1.0 pg. The limits of detection were 0.4 and 0.7 ng g−1, the limits of quantification were 1.3 and 2.3 ng g−1 and the relative standard deviation (n = 5) was 6-16% and 9-23% for SS and SlS, respectively. The accuracy was confirmed by the analysis of certified reference materials. The two methods were applied for the determination of cadmium in six wheat flour samples acquired in supermarkets of different Brazilian cities. The cadmium content varied between 8.9 ± 0.5 and 13 ± 2 ng g−1 (n = 5). Direct SS gave results similar to those obtained with SlS using multi-injections; the values of both techniques showed no statistically significant difference at the 95% confidence level. Direct SS was finally adopted as the method of choice, due to its greater simplicity, the faster speed of analysis and the better figures of merit. 相似文献
1000.
A two-dimensional biomimetic optrode for the detection and quantification of uranium in natural waters was fabricated. The sensing element was designed by the inclusion of uranyl ion imprinted polymer particles into polymethyl methacrylate followed by casting a thin film on a glass slide without any plasticizer. The ion imprinted polymer material was prepared via covalent immobilization of the newly synthesised ligand 4-vinyl phenylazo-2-naphthol by thermal polymerization. Operational parameters such as pH, response time and the amount of sensing material were optimized. The response characteristics of the imprinted and the corresponding non-imprinted polymer inclusion optrodes of uranium were compared under optimum conditions. The imprinted polymer inclusion optrode responds linearly to uranium in the concentration range 0–1.0 μg mL−1 with a detection limit of 0.18 μg mL−1, which is much better than the solution studies using 4-vinyl phenylazo-2-naphthol (1.5 μg mL−1). Triplicate determinations of 100 μg of uranium(VI) present in 250 mL of solution gave a mean absorbance of 0.018 with a relative standard deviation of 8.33%. The superior sensitivity of imprinted polymer inclusion optrode is exemplified by lower detection limits and broader dynamic range over non-imprinted polymer inclusion optrode. The developed imprinted polymer inclusion optrode was found to give stable and precise response for 3 months and can be used without any loss in sensitivity. The applicability for analysing ground, lake and tap-water samples collected in the vicinity of uranium deposits was successfully demonstrated. 相似文献