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231.
以乙酸锌和Se粉为原料,环己酮为溶剂,于180 ℃反应24 h制得黄色纳米球ZnSe,其结构和性能经XRD,SEM及TEM表征. 相似文献
232.
Milindkumar S. Kalekar 《Journal of Dispersion Science and Technology》2013,34(7):1027-1034
Adsorption of various surfactants at the gas liquid interface is studied with equilibrium and dynamic surface tension measurements. The Wilhelmey plate method and maximum bubble pressure method are used for this study. Dynamic surface tension of solutions of different surfactants, sodium lauryl sulfate (SLS), polyoxyethylene glycol 4‐tert‐octyl phenyl ether (Triton X 100), poly‐oxyethylene(20) cetyl ether (Brij 58), and tetraethylene glycol mono‐n‐dodecyl ether (Brij 30), is measured at different concentrations. Adsorption of different surfactants is compared on the basis of equilibrium and dynamic behavior. Effectiveness and efficiency of different surfactants is found from equilibrium surface tension measurement. A new parameter is defined to quantify the dynamic behavior of adsorption, which gives the concentration of surfactant needed to reduce surface tension to half of its maximum reduction within a defined time available for adsorption. The dynamics of surfactant solution is quantified by using this parameter. 相似文献
233.
层状四水硫酸锆催化合成乙二醇单乙醚醋酸酯反应机理的理论研究 总被引:1,自引:0,他引:1
采用以量子化学ASED-MO(含原子对排斥的EHMO法)为基础的结构自动优化EHTOPT法,研究了层状四水硫酸锆催化合成乙二醇乙醚醋酸酯的反应机理;构筑了反应组分乙二醇单乙醚羟基上的氢原子通过氢 键与层状四水硫酸锆结晶水上的氧原子结合。同时,还研究了醋酸在四水硫酸锆表面形成正碳离子的结合状态,提出了相应的酯化反应机理,在此基础上推导出的动力学方程与实验结果相符。 相似文献
234.
粗糙表面分维计算的立方体覆盖法 总被引:16,自引:0,他引:16
针对三角形棱柱表面积法和投影覆盖法在计算粗糙表面分形维数中存在的问题,提出了计算粗糙表面分维的立方体覆盖法,对计算结果进行了对比分析,并进一步对表面分维计算中的有关理论问题进行了分析,发现立方体覆盖法作为一种几何意义上的覆盖法,并计算结果比三角形棱柱表面积法和投影覆盖法更接近实际。 相似文献
235.
BEM for simulation of a 2D elastic body with randomly distributed circular inclusions 总被引:7,自引:0,他引:7
Based on our 2D BEM software THBEM2 which can be applied to the simulation of an elastic body with randomly distributed identical
circular holes, a scheme of BEM for the simulation of elastic bodies with randomly distributed circular inclusions is proposed.
The numerical examples given show that the boundary element method is more accurate and more effective than the finite element
method for such a problem. The scheme presented can also be successfully used to estimate the effective elastic properties
of composite materials.
Project supported by the National Natural Science Foundation of China (No. 19772025). 相似文献
236.
AN IMPROVED ARC-LENGTH METHOD AND APPLICATION IN THE POST-BUCKLING ANALYSIS FOR COMPOSITE STRUCTURES
Based on the conventional arc- length method, an improved arc- length method with high-efficiency is proposed. The weighted modifications with respect to the variation of structural stiffness and extra-interpolation modification by using the information of known equilibrium points are introduced to improve the incremental arc- length . An approximate expansion method for the accumulated and expected arc-length is used to ensure the convergence at given load levels in large range of applications. Numerical results show that the improved arc-length method has well adaptability and higher efficiency in the post-buckling analysis of plates and sheik structures for tracing whole load-deflection path and obtaining the convergence values at any specified load levels. 相似文献
237.
Benjamin D. Leonard Arnab Ghosh Farshid Sadeghi Sachin Shinde Marc Mittelbach 《International Journal of Solids and Structures》2014
A new approach was developed for modeling the effect of the third body on fretting. This was accomplished using the combined finite-discrete element method (FDEM) in which the third body is analyzed as discrete elements while the first bodies are modeled using finite elements. This approach provides a link between large scale models which treat the mass of wear debris as a single or small number of bodies and small scale models which only study a control volume. The FDEM was used to analyze the behavior of third body particles between flat sliding surfaces. When the third body mass is composed of unconnected particles, it behaves as a Newtonian fluid, but this behavior ceases when the particles are connected into platelets. The FDEM was also used to study the behavior of third body particles inside a Hertzian line contact. As the number of particles and platelet size increase the load carried by the worn slip zone grows larger in relationship to the unworn stick zone. 相似文献
238.
To reveal some dynamic properties of the deploying process for the solar power satellite via an arbitrarily large phased array (SPS-ALPHA) solar receiver, the symplectic Runge-Kuttamethod is used to simulate the simplified model with the consideration of the Rayleigh damping effect. The system containing the Rayleigh damping can be separated and transformed into the equivalent nondamping system formally to insure the application condition of the symplectic Runge-Kutta method©First, the Lagrange equation with the Rayleigh damping governing the motion of the system is derived via the variational principle. Then, with some reasonable assumptions on the relations among the damping, mass, and stiffness matrices, the Rayleigh damping system is equivalently converted into the nondamping system formally, so that the symplectic Runge-Kutta method can be used to simulate the deploying process for the solar receiver. Finally, some numerical results of the symplectic Runge-Kutta method for the dynamic properties of the solar receiver are reported. The numerical results show that the proposed simplified model is valid for the deploying process for the SPS-ALPHA solar receiver, and the symplectic Runge-Kutta method can preserve the displacement constraints of the system well with excellent long-time numerical stability. 相似文献
239.
本文将无网格自然邻接点Petrov-Galerkin 法应用于轴对称弹性体扭转问题的求解.无网格自然邻接点Petrov-Galerkin 法采用自然邻接点插值构造试函数,并且采用三角形线性单元的形函数作为加权残值法的加权函数.自然邻接点插值构造的试函数满足Kronecker delta 函数性质,因此本质边界条件的施加十分方便.由于几何形状和边界条件的轴对称特点,原来的空间问题简化为二维问题求解,因此计算时只需要横截面上离散节点的信息.数值算例结果表明,所提出的方法对求解轴对称弹性体扭转问题是行之有效的. 相似文献
240.
位错和夹杂的干涉效应对于理解材料的强化和韧化机理具有十分重要的意义。文中研究了晶体材料中刃型位错和多条共圆弧刚性线夹杂的干涉作用。利用Riemann—Schwarz反照原理和复势函数的奇性主部分析技术,得到了问题的一般解答;对于只含一条刚性线夹杂的情况,给出了复势函数的封闭形式解。由Peach-Koehler公式求出了作用在刃型位错上的位错力,并讨论了圆弧形刚性线夹杂对位错力的影响规律,发现弧形刚性线对刃型位错有很强的排斥作用。本文解答不但可作为格林函数获得任意分布位错的相应解答,而且可以用于研究刚性线夹杂和任意形状裂纹的干涉效应问题。 相似文献