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91.
92.
93.
Itoh T 《Journal of fluorescence》2006,16(6):739-742
Effects of the reflection mirrors mounted to the sample holder of a fluorimeter have been investigated. Analytical expressions
are given for the emission intensity measured as a function of the concentration or optical density of the sample, in case
one or two reflection mirrors are attached beside the sample holder to intensify the emission signals. The emission intensity
calculated as a function of the sample concentration agreed well with the experimental data. By mounting two reflection mirrors,
the emission signal was intensified by a factor of near 3.5. However, the degree of intensification depended strongly on the
sample concentration and the linearity between the sample concentration and the emission intensity deviated significantly
with increasing the sample concentration. 相似文献
94.
The transport of scalar quantities passively advected by velocity fields with a component at small scale ℓ can be modeled at scales larger than ℓ by means of an effective drift and an effective diffusivity, which can be determined by means of multiple-scale techniques. We show that the presence of a weak flow at large scales Lℓ induces interesting effects on the scalar transport at the meso-scales (i.e. at scales intermediate between ℓ and L). In particular, it gives rise to non-isotropic and non-homogeneous corrections to the meso-scale drift and diffusivity. We discuss an approximation that allows us to retain the second-order effects caused by the large-scale flow. This provides a rather accurate meso-scale modeling for both asymptotic and pre-asymptotic scalar transport properties. Numerical simulations in model flows are used to illustrate the importance of such large-scale effects. 相似文献
95.
Miros?aw Kwiatkowski 《Applied Surface Science》2011,257(21):8912-8922
The aim of this work has been to analyze the problems related to the identification of microporous structure parameters of carbonaceous materials. The new methods for microporous structure parameters identification have been explored with special focus on the influence of the analyzed relative pressure range on the reliability of parameters identification. For that purpose, the adsorption isotherm of nitrogen on active carbon for different ranges of relative pressures p/p0 was analyzed. The conducted research was to provide for an answer to the question of whether the range of the analyzed relative pressures has any effect on the quality of adsorption system parameters identification, as well as what range of the relative pressure permits execution of the reliable identification of microporous structure parameters. 相似文献
96.
Z. Liu R. BrandtO. Hellwig S. FlorezT. Thomson B. TerrisH. Schmidt 《Journal of magnetism and magnetic materials》2011,323(12):1623-1626
We present the measurements of the picosecond magnetization dynamics of Co/Pd multilayer films. The dynamic magnetization properties of sputtered multilayer films were analyzed as a function of Co layer thicknesses and applied bias field. Both the eigenfrequencies of the magnetization precession in the multilayers and the associated Gilbert damping exhibit extreme sensitivity to the magnetic layer thickness on an atomic monolayer scale. The eigenfrequency increases more than threefold when the Co thickness decreases from 7.5 to 2.8 Å, mainly due to the changes in effective saturation magnetization and perpendicular anisotropy constant. A concomitant 2.6-fold increase in the damping of the oscillations is observed and attributed to stronger interface dissipation in thinner Co layers. In addition, we introduce a quasi-1D micromagnetic model in which the multilayer stack is described as a one-dimensional chain of macrospins that represent each Co layer. This model yields excellent agreement with the observed resonance frequencies without any free parameters, while being much simpler and faster than full 3D micromagnetic modeling. 相似文献
97.
A combination of molecular dynamics (MD), continuum elasticity and FEM is used to predict the effect of CNT orientation on the shear modulus of SWCNT-polymer nanocomposites. We first develop a transverse-isotropic elastic model of SWCNTs based on the continuum elasticity and MD to compute the transverse-isotropic elastic constants of SWCNTs. These constants are then used in an FEM-based simulation to investigate the effect of SWCNT alignment on the shear modulus of nanocomposites. Furthermore, shear stress distributions along the nanotube axis and over its cross-sectional area are investigated to study the effect of CNT orientation on the shear load transfer. 相似文献
98.
99.
We describe the optimisation of RadLine®; a small, real time, remotely operated radiation detector, which consists of an inorganic scintillation crystal coupled to a fibre optic cable transporting produced photons to a CCD camera some distance away. RadLine® is tested in a beta and gamma narrow radiation field of 2.4 GBq, from a Caesium-137 (662 KeV) source, at doses rates between 0.125 mSvhr−1 and 10 mSvhr−1. Our results establish that the lower limit of the device corresponds to a dose rate of 0.2 mSvhr−1, constrained by the signal to noise ratio of the instrument. We also demonstrate the process of characterising the RadLine® for utilisation underwater due to its partial electrical inactiveness; and to consider how the instrument might perform in aquatic environments and ultimately in a First Generation Magnox Storage Ponds (FGMSP). The RadLine® brings a marked difference to actual underwater radiation monitoring devices such as; HPGe, CZT and GM detectors, which not only incorporate the whole electronics within and are more bulky, only perform over a short range. The RadLine®’s design offers signification value for intermediate (>100 m) and long range detection. 相似文献
100.
The paper describes a novel transmission electron microscopy (TEM) experiment with in situ ion irradiation designed to improve and validate a computer model. TEM thin foils of molybdenum were irradiated in situ by 1?MeV Kr ions up to ~0.045 displacements per atom (dpa) at 80°C at three dose rates ?5?×?10?6, 5?×?10?5, and 5?×?10?4?dpa/s – at the Argonne IVEM-Tandem Facility. The low-dose experiments produced visible defect structure in dislocation loops, allowing accurate, quantitative measurements of defect number density and size distribution. Weak beam dark-field plane-view images were used to obtain defect density and size distribution as functions of foil thickness, dose, and dose rate. Diffraction contrast electron tomography was performed to image defect clusters through the foil thickness and measure their depth distribution. A spatially dependent cluster dynamic model was developed explicitly to model the damage by 1?MeV Kr ion irradiation in an Mo thin foil with temporal and spatial dependence of defect distribution. The set of quantitative data of visible defects was used to improve and validate the computer model. It was shown that the thin foil thickness is an important variable in determining the defect distribution. This additional spatial dimension allowed direct comparison between the model and experiments of defect structures. The defect loss to the surfaces in an irradiated thin foil was modeled successfully. TEM with in situ ion irradiation of Mo thin foils was also explicitly designed to compare with neutron irradiation data of the identical material that will be used to validate the model developed for thin foils. 相似文献