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61.
62.
Dorin Dusciac Jean-Noël Chazalviel François Ozanam Philippe Allongue Catherine Henry de Villeneuve 《Surface science》2007,601(18):3961-3964
Direct grafting of organic monolayers on Si is of prime interest in order to give specific properties to a silicon surface. However, for microelectronics applications, this possibility is hampered by the limited stability of the grafted layers. It has been previously established that alkyl layers attached to Si surfaces through Si-C bonds become unstable at 250-300 °C, by desorption of alkenes. Changing the nature of the bonding to the surface might allow one to circumvent this desorption pathway and increase the layer stability. In our work, decanol and decyl aldehyde are reacted with the Si(1 1 1)-H surface at ∼100 °C during 20 h in order to obtain alkoxy monolayers. FTIR measurements performed in ATR geometry show that the grafted molecule surface coverage is on the order of 33% after reaction with decanol and 50% after reaction with decyl aldehyde. Characterization by AFM essentially reveals that the morphology of the grafted surfaces is unaffected as compared to that of Si-H surfaces. However, the edges of the terraces at alcohol-grafted surfaces exhibit some pitting, probably due to the presence of water in the grafting liquid. Thermal stability studies show that alkoxy chains progressively disappear from the Si surface between 200 and 400 °C. From the CH2/CH3 ratio in the CH region (2760-3070 cm−1), it appears that the chains undergo progressive dissociation by C-C bond breaking before their complete disappearance from the surface. Therefore, the thermal behaviour of alkoxy monolayers appears quite distinct from that of alkyl monolayers that tend to leave the surface in a much narrower temperature range (250-350 °C), essentially via breaking of the Si-C bonds. 相似文献
63.
The goal in this work is to investigate the effectiveness of time-frequency representations for analysing dispersive waves by comparing the performance of three different methods. In particular, the smoothed pseudo-Wigner distribution, the continuous wavelet transform and the Hilbert-Huang transform are compared and evaluated in terms of their ability to analyse dispersive elastic waves. The waves under consideration are transient flexural ones generated by an impact in a beam. In view of the results of the comparative study, the advantages and shortcomings of each method are presented and discussed. 相似文献
64.
Interferometry is well established as an optical technique in which a measurand is encoded as the phase of a periodically varying intensity pattern. In view of the inherent accuracy of interferometry, many methods have been developed to retrieve the phase from images of the fringe pattern. Our focus in this paper is one such technique—the continuous wavelet transform (CWT). We begin by reviewing the CWT and the space–spatial–frequency localisation properties of wavelets. We show that a path which follows the maximum modulus of the CWT (the wavelet ridge) gives the instantaneous fringe frequency as a function of spatial displacement. The phase is automatically and trivially obtained, without discontinuities, by integration. Examples of practical wavelets are given and algorithms to isolate the wavelet ridge reviewed. 相似文献
65.
在含有Sr2+,Ca2+,PO3-4和壳聚糖(CHI)的电沉积液中,用恒电流沉积法,在医用纯钛(Ti)表面上得到壳聚糖/掺锶羟基磷灰石(SrHAP)复合涂层。采用扫描电镜(SEM)、能量弥散X射线谱(EDS)、X射线衍射(XRD)对涂层进行检测,用傅里叶变换红外光谱(FTIR)考察了壳聚糖和锶离子的掺杂对HAP涂层构象和生物活性的影响。结果表明:锶部分取代磷灰石中的钙,表面形貌由疏松的针状变为较致密的片状。FTIR分析表明,涂层中出现了典型的amideⅠ和amideⅡ的壳聚糖振动峰,则CHI与SrHAP杂化良好;模拟生理液浸泡后表面覆盖有球状类骨磷灰石,则涂层具备较好的生物活性。塔菲尔测试表明,复合涂层使得Ti表面的抗生理腐蚀性显著提高。 相似文献
66.
The capability to classify, recognize and to identify objects from spatially low resolution images has high significance in security related applications especially in a case that recognition of camouflaged object is required.In this paper we present a novel approach in which the scenery containing obscured objects which we wish to classify, recognize or identify is illuminated by spatially coherent beam (e.g. laser) and therefore secondary speckles pattern is reflected from the objects. By special image processing algorithm developed for this research and which is basically based upon temporal tracking of the random speckle pattern one may extract the temporal signature of the object. And right after, to use it for its classification (e.g. its separation from the other objects in the scenery), its recognition and identification even in a case that the imager provides poor spatial resolution that by itself does not allow doing the specified detection related operations. 相似文献
67.
68.
Since the Jost solutions of the DNLS equation does not tend to the free Jost solutioins as |λ| →∞, the usual inverse scattering transform (IST) must be revised. Beside the Kaup and Newell's approach, we propose a simple revision in constructing the equations of IST, where the usual Zakharov-Shabat kern is revised by multiplying λ-2 or λ-1. To justify the revision we show that the Jost solutions obtained do satisfy the pair of compatibility equations. 相似文献
69.
We present a novel multi-image encryption and decryption algorithm based on Fourier transform and fractional Fourier transforms. Lower frequency parts of the original images are selected, frequency shifted and encrypted by using double phase encoding in fractional Fourier domains. Multiple images are encrypted together into a single one. A simple optical setup is given to implement the proposed algorithm. This scheme has features of enhancement in decryption accuracy and high optical efficiency. Numerical results have been given to verify the validity and efficiency of the proposed scheme. 相似文献
70.
通过研究爬壁式机器人的控制和运动特征,提出一种基于复小波包分形理论的故障检测方法.利用复小波包的平移不变性,将爬壁式机器人传感器输出信号分解成独立的频谱,并进行阀值处理和重构,从而有效去除高频噪音并提取故障的特征频率;依据信号分形维数的多尺度不变性,在嵌入维数空间,采用维数最大距离法,确定复小波包域故障信号的关联雏数.仿真实验表明,爬壁式机器人在各种异常工作模式下的故障信号关联维数能比较真实地反映其故障状态空间,同时也验证了故障信号的关联维数低于正常信号的关联维数作为故障发生与否的定量判据的正确性. 相似文献