首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   19104篇
  免费   445篇
  国内免费   516篇
化学   2676篇
晶体学   102篇
力学   169篇
综合类   26篇
数学   15383篇
物理学   1709篇
  2023年   68篇
  2022年   104篇
  2021年   100篇
  2020年   118篇
  2019年   413篇
  2018年   427篇
  2017年   246篇
  2016年   197篇
  2015年   236篇
  2014年   504篇
  2013年   1209篇
  2012年   604篇
  2011年   1108篇
  2010年   892篇
  2009年   1207篇
  2008年   1331篇
  2007年   1363篇
  2006年   1048篇
  2005年   734篇
  2004年   615篇
  2003年   571篇
  2002年   425篇
  2001年   365篇
  2000年   358篇
  1999年   482篇
  1998年   461篇
  1997年   383篇
  1996年   448篇
  1995年   483篇
  1994年   450篇
  1993年   415篇
  1992年   345篇
  1991年   188篇
  1990年   178篇
  1989年   186篇
  1988年   133篇
  1987年   133篇
  1986年   131篇
  1985年   199篇
  1984年   165篇
  1983年   122篇
  1982年   178篇
  1981年   146篇
  1980年   121篇
  1979年   87篇
  1978年   111篇
  1977年   91篇
  1976年   89篇
  1975年   34篇
  1974年   24篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
31.
The Banach algebra generated by one-dimensional linear singular integral operators with matrix valued piecewise continuous coefficients in the spaceL p (,) with an arbitrary weight is studied. The contour consists of a finite number of closed curves and open arcs with satisfy the Carleson condition. The contour may have a finite number of points of selfintersection. The symbol calculus in this algebra is the main result of the paper.  相似文献   
32.
It is widely believed that order of exactness is a good measure of the quality of an algorithm for numerical quadrature. We show that this is not the case, by exhibiting a situation in which the optimal algorithm does not even integrate constants exactly. We also show that there are situations in which the penalty for using equidistant nodes is unbounded. Finally, we show that the complexity of obtaining an -approximation can be an arbitrary function of , i.e., there is no hardest quadrature problem.  相似文献   
33.
LetP be a finite partially ordered set. The lengthl(x) of an elementx ofP is defined by the maximal number of elements, which lie in a chain withx at the top, reduced by one. Letw(P) (d(P)) be the maximal number of elements ofP which have the same length (which form an antichain). Further let . The numbers and as well as all partially ordered sets for which these maxima are attained are determined.  相似文献   
34.
The surface chemical composition of raw unscoured cotton was successfully investigated by the surface analytical techniques X-ray Photoelectron Spectroscopy (XPS) and Time of Flight Secondary Ion Mass Spectrometry (ToF-SIMS). The presence of non-cellulosic material at the fibre surface was established and determined to be a complex mixture of fatty acids, alcohols, alkanes, esters and glycerides. The effect of scouring and bleaching was to reduce the surface concentration of these materials but even after aqueous processing some non-cellulosic material residue was still detected at the fibre surface.  相似文献   
35.
JIANG Qi-Jun 《结构化学》2005,24(10):1140-1144
1 INTRODUCTION The electron-transfer reaction of C60 derivatives, especially light-induced electron-transfer reaction, has been an active research field for a long time. Many researches are focused on the long-live charge- separated state caused by electron-transfer[1]. And several electron-transfers between electron donor and C60 or intramolecular electron-transfer have been confirmed. As an example, TTF-C60 is proved to be a short-live charge-separated compound[2].Due to the excelle…  相似文献   
36.
Yu-Wu Zhong  Guo-Qiang Lin 《Tetrahedron》2004,60(40):8861-8868
Some new pyridyl alcohols with the cis-bicyclo[3.3.0]octane scaffold were synthesized and used as chiral ligands for the enantioselective addition of diethylzinc to aldehydes. Ligands 4 were found to be far superior to the C2-symmetric ligands 2 in terms of enantioselectivities. Quantitative yields and enantiomeric excesses of up to 92% were obtained when the ligand 4 was used. The carbonyl function in 4 proved to be beneficial for the high enantioselectivities in the addition of diethylzinc to aldehydes. Conversion of the carbonyl group into oxime or oxime ether group led to a sort of more active ligands, which catalyzed the same reaction with rate acceleration.  相似文献   
37.
The equations of the title appear in the author's paper Chromatic Sums for Rooted Planar Triangulations, V: Special Equations. (Canadian Journal of Mathematics, 26 (1974), 893–907). They appear in that paper as Equations (24) and (25). They are simultaneous equations for two unknown functionsl andy 2 of two variablesy 1 andz. A parameter is involved. The main result is that for = 2 cos (2/n), wheren is a positive integer >1, the two equations can be reduced to a single equation (numbered (49)). Solutions of this are known forn <7. From such solutions we can expect to get information about the averaged chromatic polynomials of planar triangulations with a given number of triangles.The present work is basically an expository paper on the theory given in Chromatic Sums, V, but it includes some new results and many simplifications.  相似文献   
38.
This paper contains applications of theorems of [1] for quadratic statistics which have constant regression on linear statistics. Two theorems are proved. The first is a sufficient condition which assumes that the characteristic function of a sample is an entire function. The second gives a new characterization of the normal distribution.  相似文献   
39.
Many polysaccharide chains can adopt ordered helical and ribbon-like secondary structures. It seems however that these chains are often so stiff and extended that the cooperative interactions necessary for stability in the solvent environment can only be achieved when inter-chain as well as intra-chain interactions are favorable. Hence we commonly find two-or more-stranded associations of helices, of ribbons, or of helices with ribbons. These can be regarded as tertiary and higher levels of structure. The ordered secondary structure characteristically requires a regular repeating sequence of sugar residues, and the termination of this sequence by insertion of a residue of different type may also terminate the secondary structure and hence the association in which it is involved. This is the mechanism by which native polysaccharides may link up to form three dimensional networks, or gels, in which state they perform their natural roles in maintaining the hydration and integrity of biological tissues. For several polysaccharides there is evidence that the mechanism of biological control over the fine topology and properties of the gel network is mediated by enzymes which modify sugar residues at the polymer level to change the pattern of “interrupting” sugar residues.  相似文献   
40.
Summary Let (X 1,Y 1), (X 2,Y 2),…, (X n,Y n) be i.i.d. as (X, Y). TheY-variate paired with therth orderedX-variateX rn is denoted byY rn and terms the concomitant of therth order statistic. Statistics of the form are considered. The asymptotic normality ofT n is established. The asymptotic results are used to test univariate and bivariate normality, to test independence and linearity ofX andY, and to estimate regression coefficient based on complete and censored samples.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号