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41.
采用密度泛涵理论(density functional theory,DFT)中的广义梯度近似(generally gradient approximation,GGA)对富勒烯C72和内掺金属La富勒烯La2@C72三种同分异构体的几何结构和电子结构进行研究.发现在C72的三种同分异构体中,满足独立五边形规则(isolated-pentagon-rule,IPR)的C72(D6d)结构最为稳定;在La2@C72三种同分异构体中,有着两对两两相邻五元环(twofused-pentagon)的La2@C72(#10611)结构最为稳定,而满足IPR的La2@C72(D6d)的结构变成了最不稳定结构.从能级图和态密度图分析得知,笼子稳定性的变化与La原子的原子轨道与C72原子轨道之间的杂化有关.Mulliken电荷分析得知,La2@C72(#10611)的两个La原子共转移了约3个电子给C72,并且,它们几乎分布在整个C笼上,形成的电子结构为La23+@C3-72.净自旋分析得知,La2@C72(#10611)中La原子磁性完全淬灭. 相似文献
42.
采用化学自燃烧法制备了不同Ag+掺杂浓度的Y2O3:Eu纳米晶体粉末样品([Y3+]∶[Eu3+]∶[Ag+]=99∶1∶X,X=0—3.5×10-2),以及通过退火处理得到了相应的体材料.根据X射线衍射谱确定所得纳米和体材料样品均为纯立方相.实验表明在纳米尺寸样品中随着Ag离子浓度的增加,荧光发射强度随之增加,当X=2×10-2时达到最大值,其发光强度比X=0时提高了近50%.当Ag离子浓度继续增加,样品发光强度保持不变.在相应的体材料样品中则没有观察到此现象.通过对各样品的发射光谱,激发光谱,X射线衍射图谱,透射电镜(TEM)照片和荧光衰减曲线的研究,分析了引起纳米样品荧光强度变化的原因是由于Ag离子与表面悬键氧结合,从而使这一无辐射通道阻断,使发光中心Eu3+的量子效率提高;Ag+的引入所带来的另一个效应是使激发更为有效.这两方面原因使发光效率得到了提高. 相似文献
43.
采用顶部籽晶提拉法(TSSG)生长出Yb:KY(WO4)2(Yb:KYW)激光晶体.对预烧后的原料及晶体进行了XRD分析,结果表明,分别在920℃和600℃预烧8h后的熔质和助熔剂基本上形成一相,抑止了实验中的挥发问题;所生长的晶体为β-Yb:KYW,计算其晶格常数为a=1.063nm,b=1.034nm,c=0.755nm,β=130.75°.测得不同厚度样品的吸收光谱,结果表明样品在933nm和981nm有较强的吸收峰,计算出主峰981nm的吸收截面σ关键词:
Yb:KYW
TSSG法
晶体结构
光谱参数 相似文献
44.
For z1,z2,z3∈Zn, the tristance d3(z1,z2,z3) is a generalization of the L1-distance on Zn to a quantity that reflects the relative dispersion of three points rather than two. A tristance anticodeAd of diameter d is a subset of Zn with the property that d3(z1,z2,z3)?d for all z1,z2,z3∈Ad. An anticode is optimal if it has the largest possible cardinality for its diameter d. We determine the cardinality and completely classify the optimal tristance anticodes in Z2 for all diameters d?1. We then generalize this result to two related distance models: a different distance structure on Z2 where d(z1,z2)=1 if z1,z2 are adjacent either horizontally, vertically, or diagonally, and the distance structure obtained when Z2 is replaced by the hexagonal lattice A2. We also investigate optimal tristance anticodes in Z3 and optimal quadristance anticodes in Z2, and provide bounds on their cardinality. We conclude with a brief discussion of the applications of our results to multi-dimensional interleaving schemes and to connectivity loci in the game of Go. 相似文献
45.
Knut Smoczyk 《Mathematische Zeitschrift》2002,240(4):849-883
We prove that symplectic maps between Riemann surfaces L, M of constant, nonpositive and equal curvature converge to minimal symplectic maps, if the Lagrangian angle for the corresponding Lagrangian submanifold in the cross product space satisfies . If one considers a 4-dimensional K?hler-Einstein manifold of nonpositive scalar curvature that admits two complex structures J, K which commute and assumes that is a compact oriented Lagrangian submanifold w.r.t. J such that the K?hler form w.r.t.K restricted to L is positive and , then L converges under the mean curvature flow to a minimal Lagrangian submanifold which is calibrated w.r.t. .
Received: 11 April 2001 / Published online: 29 April 2002 相似文献
46.
47.
Formalization for problems of multicriteria decision making under uncertainty is constructed in terms of guaranteed and weak
estimates. A relevant definition of the vector maximinimax value is given. Parameterization and approximation of maximum,
minimax, and maximinimax values based on the inverse logical convolution are suggested. An application for multicommodity
networks is considered.
Received: December 13, 2000 / Accepted: August 21, 2001?Published online May 8, 2002 相似文献
48.
M. Brokate D. Rachinskii 《NoDEA : Nonlinear Differential Equations and Applications》2006,13(4):385-411
The paper is concerned with the study of plasticity models described by differential equations with stop and play operators.
We suggest sufficient conditions for the global stability of a unique periodic solution for the scalar models and for the
vector models with biaxial inputs of a particular form, namely the sum of a uniaxial function and a constant term. For another
class of simple biaxial inputs, we present an example of the existence of unstable periodic solutions.
The paper was written during the research stay of D. Rachinskii at the Technical University Munich supported by the research
fellowship from the Alexander von Humboldt Foundation. His work was partially supported by the Russian Science Support Foundation, Russian Foundation for Basic Research (Grant No. 01-01-00146, 03-01-00258), and the Grants of the President of Russia (Grant No. MD-87.2003.01, NS-1532.2003.1). The support is gratefully acknowledged. 相似文献
49.
In this paper, the influence functions and limiting distributions of the canonical correlations and coefficients based on affine equivariant scatter matrices are developed for elliptically symmetric distributions. General formulas for limiting variances and covariances of the canonical correlations and canonical vectors based on scatter matrices are obtained. Also the use of the so-called shape matrices in canonical analysis is investigated. The scatter and shape matrices based on the affine equivariant Sign Covariance Matrix as well as the Tyler's shape matrix serve as examples. Their finite sample and limiting efficiencies are compared to those of the Minimum Covariance Determinant estimators and S-estimator through theoretical and simulation studies. The theory is illustrated by an example. 相似文献
50.
In this paper we give a realization of some symmetric space G/K as a closed submanifold P of G. We also give several equivalent representations of the submanifold P. Some properties of the set gK∩P are also discussed, where gK is a coset space in G. 相似文献