全文获取类型
收费全文 | 4478篇 |
免费 | 476篇 |
国内免费 | 727篇 |
专业分类
化学 | 2719篇 |
晶体学 | 69篇 |
力学 | 138篇 |
综合类 | 72篇 |
数学 | 1003篇 |
物理学 | 1680篇 |
出版年
2024年 | 6篇 |
2023年 | 37篇 |
2022年 | 75篇 |
2021年 | 78篇 |
2020年 | 100篇 |
2019年 | 113篇 |
2018年 | 111篇 |
2017年 | 136篇 |
2016年 | 155篇 |
2015年 | 107篇 |
2014年 | 175篇 |
2013年 | 305篇 |
2012年 | 267篇 |
2011年 | 269篇 |
2010年 | 210篇 |
2009年 | 285篇 |
2008年 | 300篇 |
2007年 | 323篇 |
2006年 | 269篇 |
2005年 | 263篇 |
2004年 | 222篇 |
2003年 | 212篇 |
2002年 | 166篇 |
2001年 | 160篇 |
2000年 | 142篇 |
1999年 | 137篇 |
1998年 | 119篇 |
1997年 | 107篇 |
1996年 | 107篇 |
1995年 | 99篇 |
1994年 | 88篇 |
1993年 | 51篇 |
1992年 | 78篇 |
1991年 | 61篇 |
1990年 | 53篇 |
1989年 | 49篇 |
1988年 | 38篇 |
1987年 | 32篇 |
1986年 | 32篇 |
1985年 | 22篇 |
1984年 | 19篇 |
1983年 | 10篇 |
1982年 | 19篇 |
1981年 | 18篇 |
1980年 | 11篇 |
1979年 | 11篇 |
1978年 | 7篇 |
1977年 | 6篇 |
1976年 | 9篇 |
1973年 | 6篇 |
排序方式: 共有5681条查询结果,搜索用时 21 毫秒
11.
Yousef Bisabr 《International Journal of Theoretical Physics》2004,43(10):2137-2148
We investigate a conformal invariant gravitational model which is taken to hold at early universe. The conformal invariance allows us to make a dynamical distinction between the two unit systems (or conformal frames) usually used in cosmology and elementary particle physics. In this model we argue that when the universe suffers phase transition, the resulting mass scale introduced by particle physics should have a variable contribution to vacuum energy density. This variation is controlled by the conformal factor which is taken as a dynamical field. We then deal with the cosmological consequences of this model. In particular, we shall show that there is an inationary phase at early times. At late times, on the other hand, it provides a mechanism which makes a large effective cosmological constant relax to a sufficiently small value. Moreover, we shall show that the conformal factor acts as a quintessence field that leads the universe to accelerate at late times. 相似文献
12.
Franois Lavaud Michel Fontanille Yves Gnanou 《Journal of polymer science. Part A, Polymer chemistry》2004,42(19):4964-4975
Studies on the anionic polymerization of methyl methacrylate in tetrahydrofuran and in the presence of sparteine have revealed a beneficial effect due to this additive, resulting in a decrease in the extent of termination. Better control of the definition of the polymers formed can thus be achieved in the presence of this additive. On the other hand, macromolecular engineering requires a range of active species concentrations lower than 10?3 mol L?1 and particularly the synthesis of polymers of high molar masses. For a better understanding of the mechanism of chain growth under such concentration conditions, the kinetics of polymerization have been investigated with a technique based on adiabatic calorimetry. Sparteine has been found to lack sufficient cation‐binding power to prevent the propagating enolate ion pairs from aggregating. The rate constant of propagation of nonaggregated species has been estimated, as well as the aggregation constant of equilibrium. For very low initiator concentrations, termination reactions have been shown to profoundly alter the control of the polymerization and to prevent a quantitative monomer conversion. Theoretical maximal conversions have been calculated from kinetic data and compare well with the experimental values. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 4964–4975, 2004 相似文献
13.
Per B. Zetterlund Kazuki Miyake Kunihiro Goto Bunichiro Yamada 《Journal of polymer science. Part A, Polymer chemistry》2004,42(11):2640-2650
A detailed investigation of addition–fragmentation chain transfer (AFCT) in the free‐radical polymerization of methyl methacrylate (MMA) in the presence of methyl α‐(bromomethyl)acrylate (MBMA) was carried out to elucidate mechanistic details with efficient macromonomer synthesis as an underlying goal. Advanced modeling techniques were used in connection with the experimental work. Curve fitting of simulated and experimental molecular weight distributions with respect to the rate coefficient for addition of propagating radicals to MBMA (kadd) over 60–120 °C resulted in Eadd = 21.7 kJ mol?1 and Aadd = 2.18 × 106 M?1 s?1 and a very weak temperature dependence of the chain‐transfer constant (Eadd ≈ Ep). The rate coefficient for fragmentation of adduct radicals at 60 °C was estimated as kf ≈ 39 s?1 on the basis of experimental data of the MMA conversion and the concentration of 2‐carbomethoxy‐2‐propenyl end groups. The approach developed is generic and can be applied to any AFCT system in which copolymerization does not occur and in which the resulting unsaturated end groups do not undergo further reactions. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 2640–2650, 2004 相似文献
14.
15.
神经网络法计算镉(Ⅱ),羟基及碳酸根三元体系的形态分布 总被引:2,自引:0,他引:2
采用前馈线笥网络BP算法,计算了Cd62+-OH^-CO^2-3三元体系的累积稳定常数。用Hopfield反馈网络研究了体系中络合物的形态分布。溶液中溶解的CO2对lgβ1的计算结果有重要影响,对lgβ2,lgβ3,lgβ4的结果影响不大。 相似文献
16.
Riemannian manifolds for which a natural curvature operator has constant eigenvalues on circles are studied. A local classification in dimensions two and three is given. In the 3-dimensional case one gets all locally symmetric spaces and all Riemannian manifolds with the constant principal Ricci curvatures r
1 = r
2 = 0, r
3= 0 , which are not locally homogeneous, in general. 相似文献
17.
The theory of Ribaucour transformations for hypersurfaces in space forms is established. For any such hypersurface M, that admits orthonormal principal vector fields, it was shown the existence of a totally umbilic hypersurface locally associated to M by a Ribaucour transformation. A method of obtaining linear Weingarten surfaces in a three-dimensional space form is provided. By applying the theory, a new one-parameter family of complete constant mean curvature (cmc) surfaces in the unit sphere, locally associated to the flat torus, is obtained. The family contains a class of complete cmc cylinders in the sphere. In particular, one gets a family of complete minimal surfaces and minimal cylinders, locally associated to the Clifford torus.Mathematics Subject Classifications (2000): 53C20. 相似文献
18.
Frank Morgan 《Annals of Global Analysis and Geometry》2006,30(1):73-79
In a product M
1 × M
2 of Riemannian manifolds, the least perimeter required to enclose given volume among general regions is at least 1/√ 2 times that among regions of product form, assuming that the isoperimetric profiles of M
1 and M
2 are concave. This result sharpens earlier work of Grigor'yan, generalizes results of Bollobás and Leader and of Barthe, and yields a lower bound on the Cheeger isoperimetric constant of a product. 相似文献
19.
We study the corrections to the Clausius-Mossotti formula for the dielectric constant of a disordered system of polarizable spherical particles. Previously we have derived an exact cluster expansion for the correction terms. Here we study the three-body correction in detail. We derive an explicit expression for the integrand of the three-body cluster integral for a system of polarizable point dipoles. 相似文献
20.
The mass spectrum ofcb meson is investigated with an effective quark-antiquark potential of the form -αc/r +Ar
νwith ν varying from 0.5 to 2.0. TheS andP-wave masses, pseudoscalar decay constant, weak decay partial widths in spectator model and the lifetime ofB
cmeson are computed. The properties calculated here are found to be in good agreement with other theoretical and experimental
values at potential index,ν = 1 相似文献