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41.
The GC–MS characteristics of trifluoroacetate esters of phenolic compounds are discussed. Linear temperature programmed retention indices and total ion current MS response factors of over 120 phenolic esters are reported. The main GC advantages from analysis of trifluoroacetate esters as compared to plain phenols are enhanced volatility and improved resolution. For example, the elution temperature of a given phenol is typically 50 °C greater than that of the corresponding trifluoroacetate ester. Also, while retention of compounds with two trifluoroacetate groups is only moderately greater than mono esters, underivatized dihydroxy compounds are very difficult to elute from any GC column. Complete resolution of isomeric C0-, C1- and C2-alkylphenol esters is readily achieved on conventional fused silica GC columns; resolution of the corresponding underivatized compounds requires specialized GC columns with low temperature limits. In general, mass spectra of trifluoroacetate esters are more characteristic of a given structure than those of the corresponding phenols and may be more rigorously interpreted towards structural elucidation. A table in the report summarizes some of the more important spectral features used in compound identification. Example applications in analysis of coal-, shale- and petroleum-derived materials are presented. Selected ion monitoring is used to determine individual phenolic components in whole distillates; reconstructed ion chromatograms are used to illustrate distributions of selected species as a function of fuel storage and thermal stress. 相似文献
42.
L. Belvisi S. Brossa A. Salimbeni C. Scolastico R. Todeschini 《Journal of computer-aided molecular design》1991,5(6):571-584
Summary A structure-activity relationship study has been done on 8 compounds with the activity known as Ca2+ channel blockers. Conformational analysis was carried out using a molecular mechanics method. The 3D-QSAR approach was used and the most polar functional groups present in all the molecules were considered. Eight interatomic distances are necessary to define the relative spatial disposition of these relevant molecular fragments. The structure-activity relationship between interatomic distances and biological activity was performed using statistic and chemometric methods. In particular, with Principal Component Analysis, it was possible to reduce the number of interatomic distances: only six of the eight distances are sufficient to describe the system in a useful way. A classification method was iteratively used to select the most probable conformations linked to the biological activity and to build a model able to classify conformations according to their biological behaviour. Cluster analysis on the active selected conformations subsequently allowed the identification of two different geometrical patterns for the active compounds. Finally the validity of the model was verified by correctly predicting the activity of other molecules not used in the construction of the model but possessing known activity. 相似文献
43.
Alessandro Agneni 《Meccanica》1992,26(4):221-228
This paper deals with some aliasing effects in the time domain that can lead to unacceptable misestimations of modal parameters. When a frequency response function of a vibrating system is sampled and inverse Fourier transformed, the resulting impulse response is given by an infinite geometric series, the single term of which is the impulse response itself shifted in time. For this reason, some modal parameters, if estimated in the time domain, are biased; in particular, while the damping factor and the natural frequency are not influenced by the aliasing phenomenon, the magnitude and phase of the residue can be highly biased. Corrective terms are theoretically evaluated and their efficiency is shown in numerical simulations.
Sommario In questo articolo e' presentato un metodo per correggere gli errori che si compiono nella stima di alcuni parametri modali, quando essi vengono ricavati nel dominio del tempo. Infatti se la funzione di risposta in frequenza e' ottenuta con eccitazioni particolari—quali ad esempio lo pseudo-random, lo stepped-sine a passo costante o lo sweep in frequenza-la risposta impulsiva, ottenuta per mezzo dell'antitrasformata discreta di Fourier, risulta periodica, con periodo pari all'inverso della spaziatura tra le righe spettrali. Cio' comporta un errore nella stima dell'ampiezza e della fase del residuo, mentre nessuna conseguenza si ha sulla frequenza naturale e sul fattore di smorzamento. L'errore sulle stime risulta tanto piu' grande, quanto meno smorzata e' la risposta impulsiva all'interno dell'intervallo di osservazione.Partendo dall'inviluppo e dalla fase istantanea dei segnali complessi, ottenibili per mezzo della trasformata di Hilbert, si sono ricavati i termini correttivi sia per il modulo, che per la fase del residuo. La validita' delle correzioni e' mostrata con esempi numerici.相似文献
44.
M. Hoorfar M.A. Kurz A.W. Neumann 《Colloids and surfaces. A, Physicochemical and engineering aspects》2005,260(1-3):277-285
A quantitative criterion called “shape parameter” to evaluate the quality of surface tension measurement of Axisymmetric Drop Shape Analysis (ADSA) is presented. ADSA is a powerful technique for the measurement of interfacial tensions and contact angles of pendant drops, sessile drops, and bubbles. Despite the general success of ADSA, deficient results may be obtained for drops close to spherical shape. Therefore, the “shape parameter” was used to determine the range of drop shapes in which ADSA succeeds or fails. The “shape parameter” is a dimensionless parameter that expresses quantitatively the difference in shape between a given experimental profile and an inscribed circle. The surface tension measurements of ADSA were evaluated for both pendant drop and constrained sessile drop configurations using the shape parameter. Different shapes of the pendant drop were studied using different sizes and materials of holders. For each drop configuration, a “critical shape parameter” was defined based on the minimum value of the shape parameter that guarantees an error of less than ±0.1 mJ/m2. Furthermore, the effects of the type of liquid and constellation on the “critical shape parameter” were studied. 相似文献
45.
Gerhard Schomburg Alfred Deege Heike Hinrichs Eduard Hübinger Heribert Husmann 《Journal of separation science》1992,15(9):579-584
Methods of alkylation of α-, β- and γ-cyclodextrins have been optimized with regard to the parameters of reaction, degree of alkylation and yields. The analysis of the reaction mixtures and of the isolated single species has been performed by high temperature GC and HPLC. The phase systems of the preferably applied HPLC have been carefully adjusted by variation of both the stationary and mobile phases to the very different hydrophobicities of the various alkylated CD species which have been synthesized. Several partially or fully alkylated CD species were isolated from preparative scale HPLC separations in high purity. 相似文献
46.
Ludovic Kurunczi Simona Timofei Smaranda Iliescu 《Phosphorus, sulfur, and silicon and the related elements》2013,188(6-7):1713-1716
Using the step-by-step build-up approach, the possible conformations of compound PhOP(O)(Me)OPh(Me) 2 Ph were constructed and geometrically optimized. Among the obtained structures 32 conformations belonging to low, comparable energy levels were used to construct the most stable dimers and tetramers of the title polymer. The results allowed us to estimate the geometrical structure of the polymer. 相似文献
47.
An ESR study has been made on the course of grafting of tetrafluoroethylene onto polyethylene. Alkyl and allyl radicals trapped in the polymers were measured under various grafting conditions. It was observed that alkyl radicals decay very rapidly when monomers are in contact with the irradiated polymer, while allyl radicals decay very slowly even in the presence of monomers as in the decay of radicals in irradiated polymers without monomers. The effect of pre-irradiation temperature on grafting was also studied, and the rate of grafting was found to be much faster for lower pre-irradiation temperatures. From these experimental results it was concluded that alkyl radicals play an important Tole in the initiation reaction of grafting. 相似文献
48.
49.
过渡金属络合物中过渡金属与配体间所形成的化学键的成键本质,可以在理论化学基础上,采用定量的方法进行分析。本文重点以铁羰基络合物为例,对常用的分析方法,如自然键轨道方法(NBO)、电荷分解分析(CDA)、分子中的原子(AIM)拓扑分析方法以及ETS和EDA能量分解方法等,在应用中的优缺点进行了分析和评述。借助于这些方法提供的电荷、能量和电子密度等配分项可以深刻认识和理解过渡金属-配体间形成的化学键的成键本质。 相似文献
50.
采用气相色谱法和高效液相色谱法两种方法分别对克菌丹和灭菌丹进行定性定量分析。气相色谱法均以邻苯二甲酸二戊酯为内标物,色谱柱采用3%OV-101 chromosorb AW DMCS 150~177μm,1 m×3 mm玻璃柱,柱温为195℃,汽化温和检测温均为230℃,克菌丹和灭菌丹的回收率分别为99.2%~100.7%和98.8%~99.9%;方法相对标准偏差分别为0.46%和0.59%。高效液相色谱法中使用Nova-PaK C18250 mm×4.6 mm色谱柱,以V(甲醇)∶V(水)=85∶15为流动相,检测波长为225 nm。克菌丹和灭菌丹的回收率分别为99.5%~100.6%和98.9%~99.7%;方法相对标准偏差分别为0.68%和0.51%。 相似文献