碳纳米管在接枝二元胺过程中微结构的变化

通过对酸化的多壁碳纳米管(MWNTs)进行酰氯化, 在碳纳米管表面接枝己二胺. 用红外光谱、热重分析、拉曼光谱和场发射扫描电镜对处理前后的碳纳米管进行分析表征. 结果表明, 经过酰氯活化, 己二胺比较容易被接枝到碳纳米管上. 而且还发现碳纳米管在酸化后形成紧密块状结构, 在接枝胺后重新变得蓬松, 其表观比容甚至大于原始碳纳米管. 从理论上分析了碳纳米管的反应过程, 对碳纳米管在接枝胺过程中微结构的变化机理进行推测, 认为通过接枝, 己二胺插入碳纳米管之间, 改变了碳纳米管之间的相互作用, 使得酸化后因形成氢键而导致的紧密堆砌结构被破坏.     

低压下酞菁裂解法制备定向碳纳米管阵列

在低压条件下以酞菁铁为原料, 采用独立双温控加热系统在石英玻璃基底上气相沉积制备了大面积准直性好和管径均匀的碳纳米管. 利用扫描电子显微镜(SEM/FESEM)和透射电子显微镜(TEM)研究了定向碳纳米管的生长形态和结构. 详细讨论了系统真空度、反应温度、气体流速及氢气和氩气的体积比例等参数对碳纳米管生长的影响, 并测试了该碳纳米管的场发射性能及超电容性能.     

Enhancing Built-in Electric Fields for Efficient Photocatalytic Hydrogen Evolution by Encapsulating C60 Fullerene into Zirconium-Based Metal-Organic Frameworks

High-efficiency photocatalysts based on metal-organic frameworks (MOFs) are often limited by poor charge separation and slow charge-transfer kinetics. Herein, a novel MOF photocatalyst is successfully constructed by encapsulating C₆₀ into a nano-sized zirconium-based MOF, NU-901. By virtue of host-guest interactions and uneven charge distribution, a substantial electrostatic potential difference is set-up in C₆₀@NU-901. The direct consequence is a robust built-in electric field, which tends to be 10.7 times higher in C₆₀@NU-901 than that found in NU-901. In the catalyst, photogenerated charge carriers are efficiently separated and transported to the surface. For example, photocatalytic hydrogen evolution reaches 22.3 mmol g⁻¹ h⁻¹ for C₆₀@NU-901, which is among the highest values for MOFs. Our concept of enhancing charge separation by harnessing host-guest interactions constitutes a promising strategy to design photocatalysts for efficient solar-to-chemical energy conversion.     

Significant Acceleration of Photocatalytic CO2 Reduction at the Gas-Liquid Interface of Microdroplets**

Solar-driven CO₂ reduction reaction (CO₂RR) is largely constrained by the sluggish mass transfer and fast combination of photogenerated charge carriers. Herein, we find that the photocatalytic CO₂RR efficiency at the abundant gas-liquid interface provided by microdroplets is two orders of magnitude higher than that of the corresponding bulk phase reaction. Even in the absence of sacrificial agents, the production rates of HCOOH over WO₃ ⋅ 0.33H₂O mediated by microdroplets reaches 2536 μmol h⁻¹ g⁻¹ (vs. 13 μmol h⁻¹ g⁻¹ in bulk phase), which is significantly superior to the previously reported photocatalytic CO₂RR in bulk phase reaction condition. Beyond the efficient delivery of CO₂ to photocatalyst surfaces within microdroplets, we reveal that the strong electric field at the gas-liquid interface of microdroplets essentially promotes the separation of photogenerated electron-hole pairs. This study provides a deep understanding of ultrafast reaction kinetics promoted by the gas-liquid interface of microdroplets and a novel way of addressing the low efficiency of photocatalytic CO₂ reduction to fuel.     

Electric Field Enhanced Ammoxidation of Aldehydes Using Supported Fe Clusters Under Ambient Oxygen Pressure

Heterogeneous catalytic ammoxidation provides an eco-friendly route for the cyanide-free synthesis of nitrile compounds, which are important precursors for synthetic chemistry and pharmaceutical applications. However, in general such a process requires high pressures of molecular oxygen at elevated temperatures to accelerate the oxygen reduction and imine dehydrogenation steps, which is highly risky in practical applications. Here, we report an electric field enhanced ammoxidation system using a supported Fe clusters catalyst (Fe/NC), which enables efficient synthesis of nitriles from the corresponding aldehydes under ambient air pressure at room temperature (RT). A synergistic effect between the external electric field and the Fe/NC catalyst promotes the ammonia activation and the dehydrogenation of the generated imine intermediates and avoids the unwanted backwards reaction to aldehydes. This electric field enhanced ammoxidation system presents high efficiency and selectivity for the conversion of a series of aldehydes under mild conditions with high durability, rendering it an attractive process for the green synthesis of nitriles with fragile functional groups.     

Supremizers of inner <Emphasis Type="Italic">γ</Emphasis>-convex functions

A real-valued function f defined on a convex subset D of some normed linear space is said to be inner γ-convex w.r.t. some fixed roughness degree γ > 0 if there is a such that holds for all satisfying ||x ₀ − x ₁|| = νγ and . This kind of roughly generalized convex functions is introduced in order to get some properties similar to those of convex functions relative to their supremum. In this paper, numerous properties of their supremizers are given, i.e., of such satisfying lim . For instance, if an upper bounded and inner γ-convex function, which is defined on a convex and bounded subset D of some inner product space, has supremizers, then there exists a supremizer lying on the boundary of D relative to aff D or at a γ-extreme point of D, and if D is open relative to aff D or if dim D ≤ 2 then there is certainly a supremizer at a γ-extreme point of D. Another example is: if D is an affine set and is inner γ-convex and bounded above, then for all , and if 2 ≤ dim D < ∞ then each is a supremizer of f.      

基于精度的属性约简新方法

自Pawlak提出粗糙集概念以来,人们就一直对粗糙集的近似精度很感兴趣,出现了不少有关近似精度的文献.在粗糙集理论中,精度是量化由粗糙集边界引起的不精确性的一种重要数字特征.在分析传统精度和基于等价关系图的过剩熵的近似精度的基础上,提出了一种新的精度定义.比较发现,新定义的精度更具有合理性.同时把这个新定义的精度运用到了属性约简上,通过实例比较发现,本文提出的属性约简更具有可行性.     

Four matroidal structures of covering and their relationships with rough sets

Covering is a common form of data representation, and covering-based rough sets serve as an efficient technique to process this type of data. However, many important problems such as covering reduction in covering-based rough sets are NP-hard so that most algorithms to solve them are greedy. Matroids provide well-established platforms for greedy algorithm foundation and implementation. Therefore, it is necessary to integrate covering-based rough set with matroid. In this paper, we propose four matroidal structures of coverings and establish their relationships with rough sets. First, four different viewpoints are presented to construct these four matroidal structures of coverings, including 1-rank matroids, bigraphs, upper approximation numbers and transversals. The respective advantages of these four matroidal structures to rough sets are explored. Second, the connections among these four matroidal structures are studied. It is interesting to find that they coincide with each other. Third, a converse view is provided to induce a covering by a matroid. We study the relationship between this induction and the one from a covering to a matroid. Finally, some important concepts of covering-based rough sets, such as approximation operators, are equivalently formulated by these matroidal structures. These interesting results demonstrate the potential to combine covering-based rough sets with matroids.