有机化合物ZnTBP/CA/PhR的非线性光吸收谱测定

测定了新型光功能有机材料锌 四苯并卟吩 巴豆酸 苯氧树脂 (Zn Tetrabenzoporphin CrotonicAcid/PhenoxyResin ,简称ZnTBP/CA/PhR)体系薄膜样品在可见光范围内的吸收谱 ,定点测量了其主要吸收谱带在激光作用下的变化情况 ,实验观察到此种材料显著的饱和及反饱和吸收现象 ,还首次观察到它的再反饱和过程。文章定性分析了变化过程中的物理机制 ,讨论了ZnTBP/CA/PhR的非线性吸收特性在光子学领域的一些应用     

Temporal reflectance from a light pulse irradiated medium embedded with highly scattering cores

This paper presents a new approach to utilize ultrashort pulsed laser for optical diagnostics with numerical simulations. The method is based on the use of ultrafast pulses with a pulsewidth selected according to the probed medium's radiative property and/or size. Our previous work in nonhomogeneous media has shown that the resulting time-resolved reflectance signal will have a unique characteristic: it will show a direct correlation of ballistic photon travel time and interface location, which is in between different layers or nonhomogeneous regions. The premise is based on utilizing the medium's structural information carried by the ballistic and snake photons without being masked by the diffuse photons. In this study, the space-time correlation is further explored in the case of minimally scattered photons from a large scattering coefficient core region embedded within a less-scattering medium. Time-resolved reflectance signals of the single scattering core and multiple scattering cores within a three-dimensional medium demonstrate the concept and illustrate the additional effect due to the scattered photons from the core region. A unique temporal signal profile's correlation at various detector positions with respect to the scattering core is explained in detail. The result has important implications. This approach will lead to a much simpler and more precise determination of the probed medium's composition or structure. Due to the large computational requirement to obtain the physical details of the light pulse propagation inside highly scattering multi-dimensional media, the reverse Monte-Carlo method is used. The potential applications of the method include non-destructive diagnostics, optical imaging, and remote sensing of underwater objects.     

Synthesis and decoloration capacity of well-defined and PMMA-grafted palygorskite nanocomposites

Structurally well-defined PMMA-grafted palygorskite nanoparticles were prepared by modifying the surface of palygorskite nanoparticles with initiators for reverse atom transfer radical polymerization (reverse ATRP) and by using these initiator-modified nanoparticles as macroinitiators. Reverse ATRP from palygorskite nanoparticles was then performed to attach well-defined polymer on to an inorganic core. It has been found that the dispersibility of palygorskite particles in organic solvents is significantly improved by grafting polymers onto the surface of palygorskite particles. The polymer-grafted palygorskite nanoparticles possess excellent decoloration capacity in organic solvents.     

Synthesis of silver nanoparticle in imidazolium and pyrolidium based ionic liquid reverse micelles: A step forward in nanostructure inorganic material in room temperature ionic liquid field

Two silver salts, silver tetrafluoroborate and silver trifluoromethanesulfonate were dissolved in two different room temperature ionic liquids (RTILs), 1-Butyl-3 methyl imidazolium tetrafluoroborate ([Bmim][BF₄]) and 1-Butyl-1 methyl pyrrolidinium trifluoromethanesulfonate ([Bmpy][Tfms]). Triton x-100 (TX-100) surfactant and cyclohexane as nonpolar medium are used to dissolve these RTILs to create reverse micellar system. Pure reverse micellar system is characterized by dynamic light scattering (DLS) measurement. These pure RTIL reverse micellar systems are used to prepare stable silver nanoparticle solution without using any other auxiliary solvent in the whole process.     

Nonstandard second-order arithmetic and Riemannʼs mapping theorem

In this paper, we introduce systems of nonstandard second-order arithmetic which are conservative extensions of systems of second-order arithmetic. Within these systems, we do reverse mathematics for nonstandard analysis, and we can import techniques of nonstandard analysis into analysis in weak systems of second-order arithmetic. Then, we apply nonstandard techniques to a version of Riemannʼs mapping theorem, and show several different versions of Riemannʼs mapping theorem.     

应急物流中库存与运输集成决策模型研究

已有的研究表明,在物流管理中权衡库存与运输成本之间的关系,实现两者的集成决策,可改进系统的运作绩效。在给定的仓库布局条件下,针对应急物流的配送特点,构建了单周期物资的运输与库存集成决策的随机规划模型。考虑到模型求解的复杂性,首先通过对模型的分析,获得了最优解的性质和上界,然后设计了基于BP神经网络和遗传算法的混合智能算法。在算例分析部分,揭示了服务水平、运输、和库存成本在应急物流中之间的复杂关系,说明合理权衡三者之间的关系,可以提升应急物流的管理水平。