液相色谱-串联质谱法同时测定黄鳝肌肉组织中6种激素残留

建立了同时测定黄鳝肌肉中苯丙酸诺龙、苯甲酸雌二醇、丙酸睾酮、乙酸炔诺酮、左炔诺酮、甲睾酮6种激素的液相色谱-串联质谱法(LC-MS/MS)。试样经酶解后用乙酸乙酯提取,提取液氮吹至近干,用2mL乙腈-水(体积比1∶1)溶解,冷冻离心脱脂净化。用SB-C18色谱柱(50×2.1mm,1.8μm)分离,以乙腈-水为流动相,梯度洗脱,在电喷雾正离子模式下进行多反应监测(MRM)的定性定量分析,外标法定量。6种目标物检出限为0.25~1.0μg/kg,定量限为0.5~2.0μg/kg,6种目标物在0.5~100μg/kg范围内线性相关系数r均大于0.99,在6个加标水平下的平均回收率为70.5%~107.2%,相对标准偏差(RSD)为3.9%~9.5%。该方法的样品前处理简单快速,灵敏度高,适用于黄鳝等蛋白脂肪含量高的动物组织中激素类药物多残留的同时测定。     

养老金预测相关模型及替代率、收支平衡的分析

企业职工养老基金的收支平衡,关系到社会稳定和向老龄化社会的顺利过渡．利用微分方程、高阶函数建立了预测远期社会平均工资及职工在职时的工资模型,并经分析对比,选用与实际吻合较好的模型,以3种年龄段为例,计算分析了它们的养老金、替代率、收支等情况．结果表明：职工年平均工资高、退休年龄迟于60岁、缴费年数多于20年,则替代率高,能接近目标值;若基础养老金按现收现付方式管理,且按目前法定年龄退休,则缺口较大．因此,要从政策与管理等多方面采取有效措施,保障养老金保险制度顺利实施．     

超短脉冲谐波截止区量子效应研究

采用Lewenstein路径积分模型和准经典三步模型,计算了不同脉宽的超短脉冲高次谐波波谱。通过比较模型截止频率随载波包络相位的变化关系的差异,对辐射过程中的量子效应进行了研究。结果显示,随脉宽的减小,以上两种模型计算结果出现的偏离增加,谐波辐射中的量子效应愈加明显。当脉宽减小至0.5 T(T为光学周期)时,准经典三步模型已不能用以解释Lewenstein模型的计算结果。     

Self-marking phase-stepping electronic speckle pattern interferometry (ESPI) for determining a phase map with least residues

Different from most of the electronic speckle pattern interferometry (ESPI) approaches, which involve the correlation fringe formulation followed by speckle noise elimination (or filtering), to develop a wrapped phase map, this study adopts the approach proposed by Creath in 1985 instead. However, Creath's approach is so critical of its applying interferograms, the influence of which is dependent on the robustness of the applied phase-shifting algorithm and the accuracy of the phase shifter. The self-marking technique proposed by Huang and Chou in 2000 is adopted herein to help overcome any unfavorable conditioning, including hysteresis, nonlinearity or plane tilting, of the pieozo-electrical transducer (PZT), to enable the successful implementation of the Creath's method. With its help, the whole phase stepping history of a practical work (i.e., an ESPI experiment for the present study) can be fully recorded and monitored. Thus, the required phase stepping frames can be accordingly decided and their further calculation will yield a phase map with least number of residues.     

4-氨基二苯甲酮晶体的定向生长及光学性能研究

采用过冷熔体定向约束生长法生长了尺寸约为30 mm×14 mm×7 mm的块状4-氨基二苯甲酮晶体,并对生长晶体的光学均匀性、光学透过率、二次谐波转换效率以及激光损伤阈值等性能进行了测试.结果表明:定向生长的4-氨基二苯甲酮晶体在650~1200 nm波段内具有90;以上的光学透过率;最高二次谐波转换效率达到64.9;;单点激光脉冲损伤阈值分别为205.4 GW/cm2(输入光波为1064 nm)和267.2 GW/cm2(输入光波为532 nm).采用过冷熔体定向约束生长的4-氨基二苯甲酮晶体适合于用作Nd: YAG激光的二次倍频器件,也适合于用作650~1200 nm波段的光学调制器件.     

具有三体作用的玻色-爱因斯坦凝聚暗孤子的演化

运用变分法研究了具有三体作用的玻色-爱因斯坦凝聚暗孤子的演化特性,分析了调谐囚禁电势对暗孤子运动的影响.结果表明,囚禁在调谐势阱中的暗孤子将振动,势阱强度和三体作用的符号影响了暗孤子的演化,并改变了BEC系统的振动特性.     

Effects of transverse profile of pump field on second harmonic generation in periodic nonlinear materials

We report on a theoreticalanalysis of the effects of a converging pump field of Gaussian transverse profile on second harmonic generation in a periodic nonlinear material with quasi-phase-matching. The outputs of the centre intensity and the intensity flux for second harmonic generation are derived by simulation, based on the parameters of quasi-phase-mismatch, the waist and focus positions of the input pump beam. The results show that when the transverse profile of the pump field is taken into account, the quasi-phase-match value and focus position of input beam for maximal second harmonic generation flollow new criteria.     

About the entropic structure of detailed balanced multi-species cross-diffusion equations

This paper links at the formal level the entropy structure of a multi-species cross-diffusion system of Shigesada–Kawasaki–Teramoto (SKT) type (cf. [1]) satisfying the detailed balance condition with the entropy structure of a reversible microscopic many-particle Markov process on a discretised space. The link is established by first performing a mean-field limit to a master equation over discretised space. Then the spatial discretisation limit is performed in a completely rigorous way. This by itself provides a novel strategy for proving global existence of weak solutions to a class of cross-diffusion systems.