Global dynamics and control of malicious signal transmission in wireless sensor networks

This paper studies the global dynamics of a discontinuous delayed model of malicious signal transmission in wireless sensor networks under the framework of differential inclusion. The local stability of two types of steady states are investigated for the discontinuous system by studying the corresponding characteristic equation. The sufficient conditions for the existence of two types of globally asymptotically stable steady states are obtained for the discontinuous system by using the comparison arguments method. Furthermore, the optimal control of the discontinuous system is investigated by using Pontryagin’s maximum principle. Numerical simulations of two examples are carried out to illustrate the main theoretical results. The obtained results can help us to better control and predict the spread of malicious signal transmission in wireless sensor networks.     

Acceleration of Reverse Intersystem Crossing using Different Types of Charge Transfer States

There is a need to boost the rate constant of reverse intersystem crossing (k_RISC) in thermally activated delayed fluorescence (TADF) materials for applications to organic light-emitting diodes. Recently, energy level matching of the locally excited state (LE) and charge transfer state (CT) has been reported to enhance k_RISC. In this study, we conceptually demonstrate that k_RISC can be improved even between CT states without LE states, through the use of different types of CT states. On the basis of this concept, we design a new compound, named DMAC-bPmT, where two phenyl groups of a well-known TADF material DMAC-TRZ are substituted by pyrimidine groups. Theoretical calculations indicated that the energy levels of the different CT states of DMAC-bPmT are very close and enhanced spin orbit coupling may be expected between them. As predicted, DMAC-bPmT experimentally exhibited a k_RISC three times as high as that of DMAC-TRZ.     

The delayed crosslinking amphiphilic polymer gel system based on multiple emulsion for in-depth profile control

Delayed crosslinking polymer gel systems are widely used in-depth profile control technology for water production control. In this paper, an amphiphilic polymer P(AM-NaA-DDAM) was synthesized by a free radical micellar polymerization method and a delayed crosslinking amphiphilic polymer gel system was prepared based on multiple emulsion of W₁/O/W₂ emulsion which was prepared by a two-step emulsification method. The optimized formulation of amphiphilic polymer gel systems is: 0.15% P(AM-NaA-DDAM), 0.3% methenamine, 0.02% resorcinol, and 0.3% citric acid. The delayed gelation time of the delayed crosslinking amphiphilic polymer gel system is closely related to the stability of the W₁/O emulsion. By using multiple emulsion delayed crosslinking method, the delayed crosslinking amphiphilic polymer gel system with diesel as the oil phase can delay the gelation time up to 168 hours.     

Adaptive estimation for stochastic damping Hamiltonian systems under partial observation

The paper considers a process $Z_t=(X_t,Y_t)$ where $X_t$ is the position of a particle and $Y_t$ its velocity, driven by a hypoelliptic bi-dimensional stochastic differential equation. Under adequate conditions, the process is stationary and geometrically $\beta$-mixing. In this context, we propose an adaptive non-parametric kernel estimator of the stationary density $p$ of $Z$, based on $n$ discrete time observations with time step $\delta$. Two observation schemes are considered: in the first one, $Z$ is the observed process, in the second one, only $X$ is measured. Estimators are proposed in both settings and upper risk bounds of the mean integrated squared error (MISE) are proved and discussed in each case, the second one being more difficult than the first one. We propose a data driven bandwidth selection procedure based on the Goldenshluger and Lespki (2011) method. In both cases of complete and partial observations, we can prove a bound on the MISE asserting the adaptivity of the estimator. In practice, we take advantage of a very recent improvement of the Goldenshluger and Lespki (2011) method provided by Lacour et al. (2016), which is computationally efficient and easy to calibrate. We obtain convincing simulation results in both observation contexts.     

以1,3-茚二酮为电子受体的热激活延迟荧光分子的合成及其在有机发光二极管中的应用

本文设计合成了一种新型电子受体2,2-二甲基-1,3-茚二酮,并将其应用于热激活延迟荧光(TADF)分子的设计中,合成了一系列具有不同发光性能的TADF分子:5-二甲基吖啶基-2,2-二甲基-1,3-茚二酮(IDYD),5-吩噁嗪基-2,2-二甲基-1,3-茚二酮(IDPXZ)和5,6-二吩噁嗪基-2,2-二甲基-1,3-茚二酮(ID2PXZ)。以IDYD为客体掺杂制备得到蓝光OLED器件,其CIE值为(0.27,0.31),最大外量子效率(EQE)为2.13%。以IDPXZ为客体掺杂得到橙光OLED器件,其CIE值为(0.43,0.53),EQE为1.31%。以ID2PXZ为客体掺杂得到黄光OLED器件,其CIE值为(0.41,0.54),EQE为2.55%。上述结果证明了以2,2-二甲基-1,3-茚二酮为电子受体可以得到不同发光颜色的TADF分子,并在全色OLED器件中具有一定应用前景。     

串联式叉型滞后簇发振荡及其动力学机制

簇发振荡是自然界和科学技术中广泛存在的快慢动力学现象,其具有与通常的振荡显著不同的特性.根据不同的动力学机制可将其分为多种模式,例如,点-点型簇发振荡和点-环型簇发振荡等.叉型滞后簇发振荡是由延迟叉型分岔诱发的一类具有简单动力学特性的点-点型簇发振荡.研究以多频参数激励Duffing系统为例,旨在揭示一类与延迟叉型分岔相关的具有复杂动力学特性的簇发振荡,即串联式叉型滞后簇发振荡.考虑了一个参激频率是另一个的整倍数情形,利用频率转换快慢分析法得到了多频参数激励Duffing系统的快子系统和慢变量,分析了快子系统的分岔行为.研究结果表明,快子系统可以产生两个甚至多个叉型分岔点;当慢变量穿越这些叉型分岔点时,形成了两个或多个叉型滞后簇发振荡;这些簇发振荡首尾相接,最终构成了所谓的串联式叉型滞后簇发振荡.此外,分析了参数对串联式叉型滞后簇发振荡的影响.      

Theoretical insights into the absorption and emission properties of blue luminescent copper(I) complexes based on the pyrazolyl‐pyridine ligands

The ground geometrical and electronic structures, charge transfer (CT) behaviors, absorption, and emission properties of the three copper(I) complexes [Cu(pypz)(POP)]⁺ (1) , [Cu(pympz)(POP)]⁺ (2) , and [Cu(pytfmpz)(POP)]⁺ (3) (pypz=1‐(2‐pyridyl)pyrazole, pympz=3‐methyl‐1‐(2‐pyridyl)pyrazole, and pytfmpz=3‐trifluoromethyl‐1‐(2‐pyridyl)pyrazole), have been investigated using density functional theory (DFT) and time‐dependent density functional theory (TD‐DFT). The vertical absorption energies of the all copper(I) complexes are well reproduced by TD‐DFT calculations based on the CT amount calculations. The triplet emission properties of the all copper(I) complexes were correctly evaluated at BMK/LANL2DZ/6‐31G* level of theory. In addition, the thermally activated delayed fluorescence properties of 1–3 were discussed in detail based on the spatial separation of the HOMO and LUMO and vertical excited energies. These theoretical insights should be expected to provide some guides for the design and synthesis of efficient luminescent copper(I) complexes. © 2014 Wiley Periodicals, Inc.     

Relative Controllability in Systems with Pure Delay

A linear control system with pure delay is considered. The integral-form solution of the Cauchy problem is obtained. The relative-controllability problem and the stabilization problem for a pendulum with time delay are solved__________Translated from Prikladnaya Mekhanika, Vol. 41, No. 2, pp. 118–130, February 2005.The study was partially sponsored by the State Committee of Science and Technology of Ukraine (grant No. 01. 07/00081).     

起爆时差对孔间裂缝贯穿影响的动光弹研究

文章用动光弹试验方法研究了相邻两个炮孔被同时起爆和采用不同的起爆时差起爆时炮孔之间应力波的传播及其应力波对裂纹扩展的影响,并重点研究了炮孔之间裂纹的产生、扩展及贯穿过程和机理。研究结果表明:在先起爆的炮孔爆炸产生的动态应力场存在时起爆另一个炮孔,即起爆时差N基本满足t/c(?)Nt/c(?),是在后起爆的炮孔孔壁上产生主导控制裂纹的最有利条件;在先起爆的炮孔旁钻导向孔,并采用合适的起爆时差可以获得炮孔间的最佳贯穿。     

Stochastic adaptive control with small observation noise

Controlled diffusions depending on an unknown parameter and with small system perturbation are considered in this paper. Two parameter identification methods are proposed and error probabilities are estimated in terms of the small perturbation parameter. These methods are then used to choose among competing filters on successive time intervals. Asymptotically optimal controls based on partial observations are found on successive time intervals by using the best filter identified on the previous time intervals.