光热材料在太阳能海水脱盐中应用的研究进展

用于海水脱盐的太阳能界面蒸发装置因其绿色环保、简单高效以及适用范围广等优点,受到了广泛关注。与传统的体积式蒸发装置不同,太阳能界面蒸发装置将太阳光的收集和蒸汽的产生锁定在空气-水的界面,无需从底部加热整体水来产生蒸汽,极大提高了能源利用效率。本文详细介绍了太阳能界面水蒸发装置的重要组成部分——光热材料的光热转换机理、材料种类以及材料的性能;探讨了高效海水净化太阳能蒸发装置的设计策略(增强光吸收、充足水供应、耐盐排盐等)。在此基础上,总结了基于界面蒸发中的太阳能蒸发装置的研究进展,展望了新型太阳能蒸发装置在海水净化领域的发展前景。     

精密及缺陷信息条件下的结构可靠性设计

概率方法一直以来被认为是处理不确定现象的最有效的方法.传统的概率可靠性模型建立在随机变量的分布函数基础上,需要较完整的数据信息.在结构设计问题中,有关载荷、抗力等影响因素的统计数据一般是稀少的或缺乏的,信息往往以非完整的形式出现.此外,结构的安全设计还需考虑结构和环境的相互作用,结构设计、分析、评价以及制作过程中可能存在的误差等,有些不确定因素不能归于随机性.因此,需要发展新的结构可靠性设计模型和方法,以克服传统的概率可靠性方法的局限和不足.本文对精密及缺陷信息条件下的可靠性设计模型和方法进行综述,内容包括随机可靠性设计模型与方法、非完整信息下的可靠性分析和设计、模型误差和主观不确定的影响、复杂系统优化求解策略、以及今后的研究展望.      

制造战略与企业绩效关系研究

通过文献研究和实践调查分析,构造企业制造战略检测量表,用偏最小二乘回归法来确定影响企业绩效的制造战略可观测项目,进一步分析制造战略与企业绩效的正相关关系,为企业制造战略竞争重点要素的识别和管理提供定量依据.     

可用于环境修复的半导体光催化剂及其改性策略研究进展

多相光催化技术作为一种直接利用太阳光降解多种污染物的先进氧化工艺在环境修复领域的研究中引起了广泛关注.在多相光催化过程中,半导体材料在太阳光的激发下,其强大的氧化/还原能力可快速高效降解各种污染物.研究者通常根据环境中污染物的状态和种类选择合适的半导体材料及修饰策略,构建高效多相光催化体系,探究光催化材料在环境修复中的...     

新时代中国国际战略研究与反思

随着国家实力和国际影响力增强,中国国家战略利益向全球延伸,作为国家实力与世界地位之间的桥梁,国际战略谋划的重要性愈发突出,加强国际战略研究恰逢其时。在新时代,推动构建新型国际关系和人类命运共同体是中国国际战略思想的核心表达,中国国际战略要密切关注中美关系、“一带一路”建设、全球伙伴关系网络等核心要素。目前,中国国际战略研究初成体系,正在向成熟的学科建设迈进。国际战略研究与教学相辅相成,应积极为战略思维强化和战略人才培养服务。强化国际战略教学与人才培养,加强战略思维的全民教育与精英培育,事关国本、事关中国的未来。     

单原子催化的关键进展与未来挑战

单原子催化剂(SACs)兼具均相与多相催化剂的双重优势, 表现出最大化的原子利用率、 超高的本征活性与选择性以及易与产物分离的特点, 受到人们的广泛关注. 然而, 由于单个原子较高的表面能以及不稳定性, 设计与制备单原子催化剂仍是一大挑战. 本文综合评述了近年来单原子催化剂的稳定化策略、 高载量催化剂的制备方法以及批量制备技术等方面的关键研究进展, 并简要分析了单原子催化剂未来发展所面临的问题与挑战, 最后对单原子催化的发展方向进行了展望.     

Assessing the Europe 2020 Strategy Implementation Using Interval Entropy and Cluster Analysis for Interrelation between Two Groups of Headline Indicators

The research analyzes the progress of Member States in the implementation of Europe 2020 strategy targets and goals in 2016–2018. Multiple criteria decision-making approaches applied for this task. The set of headline indicators was divided into two logically explained groups. Interval entropy is proposed as an effective tool to make prioritization of headline indicators in separate groups. The sensitivity of the interval entropy is its advantage over classical entropy. Indicator weights were calculated by applying the WEBIRA (weight-balancing indicator ranks accordance) method. The WEBIRA method allows the best harmonization of ranking results according to different criteria groups—this is its advantage over other multiple-criteria methods. Final assessing and ranking of the 28 European Union countries (EU-28) was implemented through the α-cut approach. A k-means clustering procedure was applied to the EU-28 countries by summarizing the ranking results in 2016–2018. Investigation revealed the countries–leaders and countries–outsiders of the Europe 2020 strategy implementation process. It turned out that Sweden, Finland, Denmark, and Austria during the three-year period were the countries that exhibited the greatest progress according to two headline indicator groups’ interrelation. Cluster analysis results are mainly consistent with the EU-28 countries’ categorizations set by other authors.     

Line positions,intensities, and Einstein A coefficients for 3-0 band of 12C16O: A spectroscopy learning method

Based on the model- and data-driven strategy, a spectroscopy learning method that can extract the novel and hidden information from the line list databases has been applied to the R branch emission spectra of 3-0 band of the ground electronic state of ¹²C¹⁶O. The labeled line lists such as line intensities and Einstein A coefficients quoted in HITRAN2020 are collected to enhance the dataset. The quantified spectroscopy-learned spectroscopic constants is beneficial for improving the extrapolative accuracy beyond the measurements. Explicit comparisons are made for line positions, line intensities, Einstein A coefficients, which demonstrate that the model- and data-driven spectroscopy learning approach is a promising and an easy-to-implement strategy.     

CoOx@Co-NC Catalyst with Dual Active Centers for Enhanced Oxygen Evolution: Breaking Trade-Off of Particle Size and Metal Loading

Increasing the metal loading and downsizing the metal particle size are two effective ways to boost the electrochemical performance of catalysts. However, it is difficult to simultaneously increase the metal loading and reduce the particle size since isolated individual atoms are easy to aggregate into nanoparticles when increasing the metal loading. To tackle this contradiction, we report a bottom-up ligand-mediated strategy to facilely prepare ultrafine CoO_x nanoclusters anchored on a Co-N-containing carbon matrix (CoO_x@Co-NC). The co-exist of N and O atoms prevent Co atoms agglomerating into large particles and allowing the formation of ultrafine dispersed Co species with large Co loading (up to 20 wt.%). Since the relationship between ultrasmall size and large metal loading is well balanced, the CoO_x nanoclusters have no inhibitory effect, but facilitate the catalytic performance of Co-N₄ sites during OER process. Consequently, due to the synergistic effect of ultrafine CoO_x nanoclusters and Co-N₄ macrocycles, the as-synthesized CoO_x@Co-NC exhibit promising OER activity (η₁₀=370 mV, Tafel plot=40 mV/dec), bettering than that of benchmark RuO₂ (η₁₀=411 mV, Tafel plot=72 mV/dec). This ligand-mediated strategy to synthesize carbonaceous materials containing dual active centers with large metal loading is promising for developing active and stable catalysts for electrocatalytic applications.     

The Emergence of Palladium-Catalyzed C(sp3)−H Functionalization of Free Carboxylic Acids

Palladium-catalyzed directing group assisted C−H bond activation has emerged as a powerful tool in synthetic organic chemistry. However, only recently, among various directing groups, widely available carboxylate moiety is recognized as a versatile candidate for the regioselective transformations. Notably, palladium-catalyzed carboxylate directed C(sp³)−H bond activation and diverse functionalization is highly challenging and has gained huge attention for its versatile applications. Mono- and bidentate ligands have proven to be useful for accelerating the C(sp³)−H bond activation step, which helps to control reactivity and selectivity (including enantioselectivity). In this Minireview, we discuss the recent progress made in palladium-catalyzed C(sp³)−H bond functionalization reactions for the construction of C−C and C−Heteroatom bonds with the direction of free carboxylic acid.