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991.
992.
We study shear-thickening phenomena observed in thermoreversible gels of telechelic associating polymers on the basis of the transient network theory. We introduce nonlinear models for the elongational properties of the middle chain; the tension along middle chains contains a nonlinear term with an amplitude A that diverges if the chain is fully stretched. Models for the dissociation rate of end chains from network junctions are also introduced; the dissociation rate is coupled to the middle-chain tension by a coupling constant g. The balance between the nonlinearity strength and coupling intensity determines the necessary condition for thickening. A strong nonlinearity in the tension caused by a large A leads to thickening if the dissociation rate of the end chains is weakly coupled to the middle-chain tension. In contrast, if it is strongly coupled, the end chains easily dissociate upon a small nonlinear elongation of the middle chains, thus leading to thinning. We present theoretical phase diagrams showing the boundary of the thickening/thinning transition in the A–g plane, and we show the existence of a critical point for thickening in these diagrams. 相似文献
993.
Y. Ootao R. Kawamura Y. Tanigawa T. Nakamura 《Archive of Applied Mechanics (Ingenieur Archiv)》1998,68(10):662-676
Summary A neural network model is applied to optimization problems of material compositions for a functionally graded material plate
with arbitrarily distributed and continuously varied material properties in the thickness direction. Unsteady temperature
distribution is evaluated by taking into account the bounds of the number of the layers. Thermal stress components for an
infinite functionally graded material plate are formulated under traction-free mechanical conditions. As a numerical example,
a plate composed of zirconium oxide and titanium alloy is considered. In the optimization problem of minimizing the thermal
stress distribution, the numerical calculations are carried out making use of the neural network. The optimum material composition
is determined by taking into account the effect of temperature-dependence of material properties. The results obtained by
neural network and ordinary nonlinear programming method are compared.
Received 3 March 1998; accepted for publication 22 May 1998 相似文献
994.
G. G. Pereira W. V. Pinczewski D. Y. C. Chan L. Paterson P. E. Øren 《Transport in Porous Media》1996,24(2):167-201
Drainage displacements in three-phase flow under strongly wetting conditions are completely described by a simple generalisation of well understood two-phase drainage mechanisms. As in two-phase flow, the sequence of throat invasions in three-phase flow is determined by fluid connectivity and threshold capillary pressure for the invading interface. Flow through wetting and intermediate spreading films is important in determining fluid recoveries and the progress of the displacement in three-phase flow. Viscous pressure drops associated with flow through films give rise to multiple filling and emptying of pores. A three-phase, two-dimensional network model based on the pore-scale fluid distributions and displacement mechanisms reported by Øren et al. and which accounts for flow through both wetting and intermediate fluid films is shown to correctly predict all the important characteristics of three-phase flow observed in glass micromodel experiments. 相似文献
995.
This paper describes the formulation of a quasi-1-D network model, referred to as the ‘bubble model’, and its application
for simulating particle transport and filtration through a granular filter bed. The model comprises a series of homogeneous
sites linked through bundles of cylindrical bonds that represent flow pathways through distributions of pores and pore throats.
This model incorporates pore scale processes of particle sieving and infiltration are based on numerical simulations described
in a companion paper. The modeling of infiltration is further refined based on detailed experimental observations and measurements
of the filtration of a dilute suspension of acrylic particles through a column of glass beads reported by Yoon et al. (2005 Water Resour. Res., to appear). Their data distinguish (a) between the collection of particles on grain surfaces and at grain-to-grain contact
points, and (b) between particles that are fully entrapped and those that are hindered (temporarily collected) and can later
become detached. These effects are represented by two parameters that characterize the probability of attachment and are linked
to the surface roughness of the grains; one that describes the minimum particle size that can be fully entrapped, and one
that describes the detachment rate. These parameters can be readily calibrated from conventional measurements of effluent
concentration and effluent particle size distribution. Detailed comparisons with the data reported by Yoon et al. show that the proposed bubble model is able to achieve reliable predictions of the spatial distribution of particles within
the filter bed following phases of particle injection and washing. 相似文献
996.
997.
为解决在同一个工作区域多个无线通信网络容易彼此干扰无法协同工作的问题,以移动机械工程车辆为控制对象,设计JRCJ500无线遥控系统,由用户手持终端接收用户操作指令,现场控制器驱动远程设备动作,实现对车辆的远程操作控制与状态信息反馈;采用STM32L低功耗处理器设计无线通信模块,选择公用通信频段,基于跳频扩频通信技术,约定无线通信数据格式与跳频频点,通过简单高效的跳频图案生成算法,在每一帧数据中添加同步字头,实现了无线通信网络的快速同步组网,保证了通信的稳定性,实现了在限定工作区域多台无线通信设备同时工作的应用需求。由于采用模块化设计,系统具有良好的通用性和可移植性,能够在多种复杂恶劣工作场合实现远程控制功能。 相似文献
998.
Hamacher K 《Journal of computational chemistry》2011,32(5):810-815
Understanding the stability of the native state and the dynamics of a protein is of great importance for all areas of biomolecular design. The efficient estimation of the influence of individual contacts between amino acids in a protein structure is a first step in the reengineering of a particular protein for technological or pharmacological purposes. At the same time, the functional annotation of molecular evolution can be facilitated by such insight. Here, we use a recently suggested, information theoretical measure in biomolecular design - the Kullback-Leibler-divergence - to quantify and therefore rank residue-residue contacts within proteins according to their overall contribution to the molecular mechanics. We implement this protocol on the basis of a reduced molecular model, which allows us to use a well-known lemma of linear algebra to speed up the computation. The increase in computational performance is around 10(1)- to 10(4)-fold. We applied the method to two proteins to illustrate the protocol and its results. We found that our method can reliably identify key residues in the molecular mechanics and the protein fold in comparison to well-known properties in the serine protease inhibitor. We found significant correlations to experimental results, e.g., dissociation constants and Φ values. 相似文献
999.
1000.
This study analyzed variations of tribological behaviors that depend on the injection molding techniques during the blending of short glass fiber (SGF) and polytetrafluoroethylene (PTFE) reinforced polycarbonate (PC) composites. The proposed planning of blending experiments is to use a D‐optimal mixture design (DMD). The tribological behaviors of friction coefficient and wear mass loss were selected for discussion. Nine experimental runs, based on a DMD method, utilized to train the back‐propagation neural network (BPNN) and then the simulated annealing algorithm (SAA) approach is applied to search for an optimal mixture ratio setting. In addition, the result of BPNN integrating SAA was also compared with response surface methodology (RSM) approach. The results of confirmation experiment show that DMD, RSM, and BPNN integrating SAA method are effective tools for the optimization of reinforced process. Furthermore, the scanning electron microscope (SEM) images show that the abundant debris are peeled off from the matrix materials and predominant delamination mechanisms and plastic deformation are shown on the worn surface after tribological behavior tests. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献