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101.
102.
A novel phenylacetylene derivative containing urea groups was synthesized and polymerized with a Rh catalyst to give the corresponding polymer, poly(1) with moderate number-average molecular weights. The poly(1) was soluble in toluene, CHCI3, CH2C12, THF, DMF, and DMSO, but insoluble in hexane, diethyl ether and MeOH. The specific rotation and circular dichroism (CD) spectroscopic studies revealed that poly(1) took predominantly one-handed helical structures. The presence of intramolecular hydrogen bonding was confirmed by liquid-state IR spectroscopy. The helicity of poly(1) could be tuned by temperature and anion. The helical conformation of the polymer was stable against Br but susceptible to F. 相似文献
103.
104.
Shangwang Liu Tongbo Cai Xiufang Tang Yangyang Zhang Changgeng Wang 《Entropy (Basel, Switzerland)》2022,24(1)
Aiming at recognizing small proportion, blurred and complex traffic sign in natural scenes, a traffic sign detection method based on RetinaNet-NeXt is proposed. First, to ensure the quality of dataset, the data were cleaned and enhanced to denoise. Secondly, a novel backbone network ResNeXt was employed to improve the detection accuracy and effection of RetinaNet. Finally, transfer learning and group normalization were adopted to accelerate our network training. Experimental results show that the precision, recall and mAP of our method, compared with the original RetinaNet, are improved by 9.08%, 9.09% and 7.32%, respectively. Our method can be effectively applied to traffic sign detection. 相似文献
105.
In 1996, we reported that silyl groups of 9,10-disilylanthracenes significantly affect the UV/Vis and fluorescence spectra. Although the results indicate that the silyl groups have strong electronic effects on anthracene, the details of the mechanisms responsible for this have not yet been clarified. This article describes the analysis of the UV/Vis and fluorescence spectra of 9,10-bis(diisopropylsilyl)anthracene by theoretical calculations. This study reveals that π conjugation of anthracene is extended by cooperation of σ–π and σ*–π* conjugation between the silyl groups and anthracene. This effect increases the transition moment of the π–π* transition of anthracene. As a result, the molecular extinction coefficient of the 1La band and the fluorescence quantum yield are increased. 相似文献
106.
107.
The fluorescence properties of a series of rare earth (Re3+ = Eu3+, Tb3+) polymeric complexes (PEK-Re3+-HLs) using three high-Tg novel carboxyl-containing polyaryletherketones (PEK) as macromolecular ligands and small molecules (HL) such as 1,10-phenanthroline (Phen), dibenzoylmethane (DBM) and 8-hydroxyquinoline (HQ) as co-ligands were investigated by means of fluorescence excitation and emission spectroscopy as well as fluorescence lifetime measurement methods. Among them, PEK-1-Re3+-Phens, in which the Re3+ ions were coordinated simultaneously with Phen and PEK-1 containing both carboxyl and bulky isopropyl groups on the polymer backbone, exhibited strong fluorescence intensities, long lifetimes, and good film-formation properties. The smooth films of PEK-1-Eu3+-Phen and PEK-1-Tb3+-Phen, cast from their DMF solutions, could emit bright red and green light under the UV lamp of 365 nm, respectively, which characteristics are of great significance for their potential applications in the large area display material fields. The excellent fluorescence properties of complexes in this study were attributed to the synergistic effects of PEK-1 ligand and Phen co-ligand. Especially, the rigid twisted structure and the bulky isopropyl substituents on PEK-1 backbone forced the coordinated rare earth ion moieties apart, and thus the probability of non-radiative decay rate of Re3+ ions at the excited levels were decreased to a large extent. 相似文献
108.
M. A. Bastrakov A. M. Starosotnikov A. Kh. Shakhnes S. A. Shevelev 《Russian Chemical Bulletin》2008,57(7):1539-1542
Transformation of the amino group in 7-amino-1-methyl-4,6-dinitro-2-phenylindole afforded a number of new 7-R-4,6-dinitroindoles
and a first representative of a novel tricyclic heteroaromatic system of [1,2,5]oxadiazolo[4,3-g]indole.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1508–1511, July, 2008. 相似文献
109.
Yuki Arakawa Hiroki Kuwahara Masatoshi Tokita Gen-ichi Konishi Hideto Tsuji 《Molecular Crystals and Liquid Crystals》2018,662(1):197-207
ABSTRACTWe present a new fabrication approach to achieve a high birefringence film by means of photopolymerization based on an alkylthio-containing rod-like liquid crystalline molecule exhibiting large temperature dependence of birefringence. We designed a new reactive mesogen having alkylthio linkages (BPM–S). It was found that BPM–S had a larger increment of birefringence with decreasing temperature, relative to commercially available alkoxy analog LC242. This result could be thought to be due to enhanced intermolecular attractive interaction for an alkylthio mesogen implied by the proximity of laterally neighboring molecules and cybotactic nematic tendency based on wide-angle X-ray measurement. The uniaxially-aligned photo-polymerized film for BPM–S showed higher birefringence than that for LC 242. 相似文献
110.
设V是3-维不定空间,W是V中某个不可约根系的无限Weyl群,本文在仿射群A(V)中共轭的意义下,给出了点群为W的晶体群的分类。 相似文献