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141.
Zoia V. Voitenko Oleksandr I. Halaev Sergey V. Kolotilov Christine Lepetit Bruno Donnadieu Remi Chauvin 《Tetrahedron》2010,66(41):8214-8222
Base- and acid-catalyzed nucleophilic addition of 11H-isoindolo[2,1-a]quinazoline-5-one to aromatic aldehydes and maleimides was investigated. The aldol adducts and condensation products were obtained stereoselectively. Main diastereomers of the Michael adducts were isolated in 74-89% yield, and converted by N-methylation to new stable α-substituted isoindole derivatives, for which 6-methylisoindolo[2,1-a]]quinazoline-5-one stands as the unsubstituted reference. The stability of the latter was monitored in moist aerated CDCl3 solution, and one of the oxidative hydrolysis product was characterized by X-ray diffraction analysis as the corresponding N-arylphthalimide. The reactivity of the unsubstituted 6-methylisoindolo[2,1-a]]quinazoline-5-one was also investigated with acetylenic Michael acceptors. Fully conjugated isoindole derivatives possessing an original pull-push-pull structure were obtained. The conformations and molecular orbitals of the dibenzoylacetylene adduct were studied at the DFT level of theory. Its static quadratic hyperpolarizabilty β0 was also calculated at the ZINDO level. 相似文献
142.
143.
The absorption spectrum of water vapor has been investigated by Intracavity Laser Absorption Spectroscopy (ICLAS) between 13 540 and 14 070 cm−1. This spectrum is dominated by relatively strong transitions of the 4δ polyad of vibrational states. The achieved sensitivity - on the order of αmin ∼ 10−9 cm−1 - has allowed one to newly measure 222 very weak transitions with intensities down to 5 × 10−28 cm/molecule at 296 K. Fifty new or corrected H216O energy levels belonging to a total of 13 vibrational states could be determined from the rovibrational analysis based on variational calculations by Schwenke and Partridge. The previous investigations in the region by Fourier Transform Spectroscopy were critically evaluated and used to construct the best to date set of energy levels accessed by transitions in the considered region. All the rovibrational transitions reaching these upper energy levels and having intensities larger than 4.0 × 10−28 cm/mol were calculated. In the resulting line list, the positions at the level of experimental accuracy were augmented with variational intensities leading to the most complete line list for water in normal isotopic abundance in the 13 500-14 100 cm−1 region. 相似文献
144.
Separate spatial soliton pairs in a biased series centrosymmetric photorefractive crystal circuit 总被引:1,自引:0,他引:1
It is shown theoretically that three types of separate soliton pairs: bright-bright, bright-dark, and dark-dark, can be established in a biased series circuit consisting of two centrosymmetric photorefractive crystals and the two solitons in a separate soliton pair can affect each other by the light-induced current. The effects of the intensities of soliton beams and background lights on the normalized profiles of solitons are discussed. 相似文献
145.
Two-dimensional modulation instability (2DMI) is experimentally demonstrated in a classical second harmonic generation setup. The spatial spectrum is measured and reveals typical 2DMI bands, in agreement with the analytical MI model. These observations are confirmed by (2 + 1)D numerical simulations. 相似文献
146.
In this paper dynamic routing and wavelength assignment strategies have been proposed for multiclass WDM optical networks. Multiclass optical networks provide multiple classes of services to the subscriber according to the requirement, which in turn increase operational profitability. Each class of service could be characterized by parameters like number of wavelengths, expected call holding time and average arrival rate of request. The proposed strategies have been analyzed and compared with existing strategies on the basis of blocking probabilities for multiclass traffic scenarios. Simulation results on different network topologies demonstrate that the performance of proposed strategies “Fixed shortest/alternate shortest path routing with wavelength reservation (FSASWR)” and “Fixed alternate shortest path routing with least priority wavelength assignment (FASPL)” are much better as compared to existing strategies. Proposed strategies minimize blocking probability of the multiclass network using limited number of wavelengths. 相似文献
147.
The mixed integer quadratic programming (MIQP) reformulation by Zheng, Sun, Li, and Cui (2012) for probabilistically constrained quadratic programs (PCQP) recently published in EJOR significantly dominates the standard MIQP formulation ( and ) which has been widely adopted in the literature. Stimulated by the dimensionality problem which Zheng et al. (2012) acknowledge themselves for their reformulations, we study further the characteristics of PCQP and develop new MIQP reformulations for PCQP with fewer variables and constraints. The results from numerical tests demonstrate that our reformulations clearly outperform the state-of-the-art MIQP in Zheng et al. (2012). 相似文献
148.
Motivated by the AIG bailout case in the financial crisis of 2007–2008, we consider an insurer who wants to maximize his/her expected utility of terminal wealth by selecting optimal investment and risk control strategies. The insurer’s risk process is modeled by a jump-diffusion process and is negatively correlated with the capital gains in the financial market. We obtain explicit solutions of optimal strategies for various utility functions. 相似文献
149.
150.
引入差异度指标描述碎纸片图像边缘的匹配程度,以差异度最小为目标建立TSP问题的数学模型,并按照指派模型求解。设计“按行聚类-行内排序”算法,以降低算法的时间复杂度;同时,对字符进行聚类分析,并利用模式识别技术降低拼接的错误率,减少人工干预;通过纵切、纵横切、双面的中英文碎纸片的复原,验证了拼接模型和算法的准确性和有效性。 相似文献