全文获取类型
收费全文 | 2000篇 |
免费 | 170篇 |
国内免费 | 237篇 |
专业分类
化学 | 208篇 |
晶体学 | 3篇 |
力学 | 55篇 |
综合类 | 34篇 |
数学 | 1601篇 |
物理学 | 506篇 |
出版年
2024年 | 2篇 |
2023年 | 25篇 |
2022年 | 38篇 |
2021年 | 37篇 |
2020年 | 55篇 |
2019年 | 51篇 |
2018年 | 56篇 |
2017年 | 56篇 |
2016年 | 69篇 |
2015年 | 63篇 |
2014年 | 109篇 |
2013年 | 154篇 |
2012年 | 93篇 |
2011年 | 125篇 |
2010年 | 93篇 |
2009年 | 132篇 |
2008年 | 131篇 |
2007年 | 137篇 |
2006年 | 130篇 |
2005年 | 107篇 |
2004年 | 103篇 |
2003年 | 93篇 |
2002年 | 88篇 |
2001年 | 64篇 |
2000年 | 78篇 |
1999年 | 61篇 |
1998年 | 45篇 |
1997年 | 39篇 |
1996年 | 35篇 |
1995年 | 25篇 |
1994年 | 20篇 |
1993年 | 10篇 |
1992年 | 9篇 |
1991年 | 9篇 |
1990年 | 4篇 |
1989年 | 8篇 |
1987年 | 4篇 |
1986年 | 4篇 |
1985年 | 8篇 |
1984年 | 6篇 |
1983年 | 2篇 |
1982年 | 6篇 |
1981年 | 5篇 |
1980年 | 4篇 |
1979年 | 2篇 |
1976年 | 3篇 |
1974年 | 3篇 |
1972年 | 1篇 |
1969年 | 1篇 |
1936年 | 1篇 |
排序方式: 共有2407条查询结果,搜索用时 328 毫秒
61.
考虑立体活性孤对电子附近次级键配位原子的贡献,对文献报道的三十个氨基多羧酸锑(III)螯合物的晶体结构中配位多面体描述进行了全面的修正.配位多面体的几何构型指定采用了单位球内截多面体的两面角判据及其相关的ANVPDA程序.所有配位多面体几何构型的修正均得到了键价计算的有力支持. 相似文献
62.
63.
64.
微波-气相-热压法分解高纯铂的研究 总被引:1,自引:0,他引:1
本文研究了微波气相热压法新技术分解高纯铂在密闭的聚四氟乙烯高压罐中,以微波瞬间加热混合酸产生的高压、纯净蒸气分解金属铂,此法避免了酸中杂质的沾污以制备供高纯铂分析的试液,提高了痕量杂质分析的准确度和降低检测限 相似文献
65.
Mariana Ramos-Estrada Gustavo A. Iglesias-Silva Kenneth R. Hall F. Kohler 《Fluid Phase Equilibria》2006,240(2):179-185
We use the Clausius–Clapeyron equation to calculate third virial coefficients at low reduced temperatures. This procedure gives an alternative to predict third virial coefficients in a region where the third virial coefficient is difficult to measure. We compare the results of this method with published third virial coefficient data. Calculated third virial coefficients have average percentage deviations within 5% of the experimental values at reduced temperatures between 0.8 and 1.0. 相似文献
66.
J. Ghazouani 《Thermochimica Acta》2005,432(1):10-19
Volumetric properties of several low acentric factor fluids (Ar, CH4, C2H6, Kr, N2, Ne, O2, Xe) as well as CO2 are modeled using the Bender equation of state. This equation is a linear function of 19 adjustable parameters, which are evaluated from properties data, using a linear numerical procedure. The validity of the EOS is tested by calculating the Joule-Thomson inversion curve. A simple model is in particular used to correlate the inversion properties predicted by the Bender equation, expressed in term of reduced pressure as a function of reduced temperatures ranging from 0.8 to 6. The simple correlation reproduces accurately the used data. We employ data on state behaviour ρ(P,T) of homogeneous fluid phases, vapour-liquid equilibrium, second virial coefficient and the coordinates of the critical point. 相似文献
67.
《Arabian Journal of Chemistry》2020,13(9):7115-7131
The impregnation of magnetite (Mt) nanoparticle (NPs) onto Musa acuminata peel (MApe), to form a novel magnetic combo (MApe-Mt) for the adsorption of anionic bromophenol blue (BPB) was studied. The SEM, EDX, BET, XRD, FTIR and TGA were used to characterize the adsorbents. The FTIR showed that the OH and CO groups were the major sites for BPB uptake onto the adsorbent materials. The average Mt crystalline size on MApe-Mt was 21.13 nm. SEM analysis revealed that Mt NPs were agglomerated on the surface of the MApe biosorbent, with an average Mt diameter of 25.97 nm. After Mt impregnation, a decrease in BET surface area (14.89 to 3.80 m2/g) and an increase in pore diameter (2.25–3.11 nm), pore volume (0.0052–0.01418 cm3/g) and pH point of zero charge (6.4–7.2) was obtained. The presence of Pb(II) ions in solution significantly decreased the uptake of BPB onto both MApe (66.1–43.8%) and MApe-Mt (80.3–59.1%), compared to other competing ions (Zn(II), Cd(II), Ni(II)) in the solution. Isotherm modeling showed that the Freundlich model best fitted the adsorption data (R2 > 0.994 and SSE < 0.0013). In addition, maximum monolayer uptake was enhanced from 6.04 to 8.12 mg/g after Mt impregnation. Kinetics were well described by the pseudo-first order and liquid film diffusion models. Thermodynamics revealed a physical, endothermic adsorption of BPB onto the adsorbents, with ΔHo values of 15.87–16.49 kJ/mol, corroborated by high desorption (over 90%) of BPB from the loaded materials. The viability of the prepared adsorbents was also revealed in its reusability for BPB uptake. 相似文献
68.
The spatial distribution function and second moments of circular freely jointed chain are derived based on an analytical method. The circular Gauss chain, which is simple for long chains, is compared with the circular freely jointed chain, which is exact for short chains. It is shown that the Gauss chain model predicts a more compact configurational distribution than the exact freely jointed chain. The two chain models, however, become closer to each other when the chain length increases. It is found that the difference of the mean square radius of gyration calculated with these two chain models is a constant, independent of the chain length. 相似文献
69.
A. J. B. Ward F. Gerrish 《International Journal of Mathematical Education in Science & Technology》2013,44(3):425-429
W. E. Roth gave necessary and sufficient conditions for the existence of solution(s) of certain types of linear matrix equations. Proofs were based on invariant factors and were long and complicated. Other shorter but non-constructive proofs have since been provided by later authors. We present here very brief constructive proofs based on the simplest of mathematical techniques, namely row- and column-reduction of a matrix. 相似文献
70.
Sliced Latin hypercube designs are very useful for running a computer model in batches, ensembles of multiple computer models, computer experiments with qualitative and quantitative factors, cross-validation and data pooling. However, the presence of highly correlated columns makes the data analysis intractable. In this paper, a construction method for sliced (nearly) orthogonal Latin hypercube designs is developed. The resulting designs have flexible sizes and most are new. With the orthogonality or near orthogonality being guaranteed, the space-filling property of the resulting designs is also improved. Examples are provided for illustrating the proposed method. 相似文献