首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   6938篇
  免费   655篇
  国内免费   631篇
化学   3844篇
晶体学   36篇
力学   226篇
综合类   73篇
数学   2942篇
物理学   1103篇
  2024年   6篇
  2023年   51篇
  2022年   72篇
  2021年   105篇
  2020年   171篇
  2019年   179篇
  2018年   174篇
  2017年   224篇
  2016年   189篇
  2015年   208篇
  2014年   308篇
  2013年   1055篇
  2012年   288篇
  2011年   342篇
  2010年   296篇
  2009年   392篇
  2008年   401篇
  2007年   407篇
  2006年   386篇
  2005年   308篇
  2004年   297篇
  2003年   269篇
  2002年   860篇
  2001年   183篇
  2000年   190篇
  1999年   131篇
  1998年   157篇
  1997年   98篇
  1996年   101篇
  1995年   90篇
  1994年   66篇
  1993年   44篇
  1992年   30篇
  1991年   18篇
  1990年   22篇
  1989年   15篇
  1988年   16篇
  1987年   14篇
  1986年   7篇
  1985年   8篇
  1984年   13篇
  1983年   3篇
  1982年   5篇
  1981年   5篇
  1980年   3篇
  1979年   6篇
  1978年   3篇
  1973年   2篇
  1968年   1篇
  1936年   1篇
排序方式: 共有8224条查询结果,搜索用时 859 毫秒
31.
The cyclomercurated ferrocenylimines containing heterocyclic ring were prepared by the condensation of cyclomercuration of acylferrocene with the appropriate heterocyclic amine.This procedure provides an efficient method for the synthesis of cyclomerucurated ferrocenylimines containing heterocyclic ring which are difficultly synthesized by the conventional method.The reaction mechanism is proposed.  相似文献   
32.
本文介绍了迈克耳逊干涉仪的彩色光环的产生机理、快速调节与拍摄方法。  相似文献   
33.
Let E\subset \Bbb R s be compact and let d n E denote the dimension of the space of polynomials of degree at most n in s variables restricted to E . We introduce the notion of an asymptotic interpolation measure (AIM). Such a measure, if it exists , describes the asymptotic behavior of any scheme τ n ={ \bf x k,n } k=1 dnE , n=1,2,\ldots , of nodes for multivariate polynomial interpolation for which the norms of the corresponding interpolation operators do not grow geometrically large with n . We demonstrate the existence of AIMs for the finite union of compact subsets of certain algebraic curves in R 2 . It turns out that the theory of logarithmic potentials with external fields plays a useful role in the investigation. Furthermore, for the sets mentioned above, we give a computationally simple construction for ``good' interpolation schemes. November 9, 2000. Date revised: August 4, 2001. Date accepted: September 14, 2001.  相似文献   
34.
研究了无限的NF-环及有限的NF-环,并且给出了有限NF-环的构造.  相似文献   
35.
We study factorisation in the ring of exponential polynomials and provide a proof of Ritt's factorisation theorem in modern notation and so generalised as to deal with polynomial coefficients as well as with several variables. We do this in the more general context of a group ring of a divisible torsion-free ordered abelian group over a unique factorisation domain.

  相似文献   

36.
Supersemiprime Rings and Supersemiprime Radical   总被引:4,自引:1,他引:3  
张宪君  靳庭良 《数学季刊》1998,13(2):107-110
§1. IntroductionInthisrecentyears,theprimeringswithspecialpropertieshavebeenstudiedsomeau-thors,forexample,N.T.Groenewaldintroducedthecompletelyprimeringsandthecompletelyrimeradicalin[1].D.HandelmanandJ.Lawrencediscussedthestronglyprimeringsandthestronglyprimeradicalin[2].S.Veldsmanstudiedthesuperprimeringsandthesuperprimeradicalin[3].ZhangXianjunintroducedtheAbsolutelysemiprimeringsandtheabsolutelysemiprimeradicalandsoon.Theaimofthispaperistostudythesemiprimeringswithspecialpropertiesan…  相似文献   
37.
研究了用频域法实现圆环形目标物计数的方法。对空域中含有圆环形目标物的二值图像,经傅里叶变换后在频域内进行滤波,再经傅里叶反变换后取一阈值进行处理,则对应于圆环形目标物即变为一个实心体,然后对实心体进行计数即可实现对圆环形目标物的计数。对该方法进行了数学描述,并分别用模拟图像和实际图像进行了实验。结果表明,该方法消除噪声的效果好,对部分封闭圆的检测同样有效,且可用于目标物有粘连的情况。该方法对圆环形目标物的尺寸相差不大的情况更为有效。  相似文献   
38.
黎奇升  佟文廷 《数学进展》2004,33(2):236-242
本文证明了:(1)Exchange环R的K0群的正向凸子群格同构于R的稳定余有限半本原理想格;(2)稳定有限、半本原的exchange环R是单的当且仅当它是K0-单的并且满足逼近弱s^*—可比性,推广了Goodearl,Ara等人的结果。  相似文献   
39.
Amphiphilic diblock copolymer polycaprolactone‐block‐poly(glycidyl methacrylate) (PCL‐b‐PGMA) was synthesized via enzymatic ring‐opening polymerization (eROP) and atom transfer radical polymerization (ATRP). Methanol first initiated eROP of ?‐caprolactone (?‐CL) in the presence of biocatalyst Novozyme‐435 under anhydrous conditions. The resulting monohydroxyl‐terminated polycaprolactone (PCL–OH) was subsequently converted to a bromine‐ended macroinitiator (PCL–Br) for ATRP by esterification with α‐bromopropionyl bromide. PCL‐b‐PGMA diblock copolymers were synthesized in a subsequent ATRP of glycidyl methacrylate (GMA). A kinetic analysis of ATRP indicated a living/controlled radical process. The macromolecular structures were characterized for PCL–OH, PCL–Br, and the block copolymers by means of nuclear magnetic resonance, gel permeation chromatography, and infrared spectroscopy. Differential scanning calorimetry and wide‐angle X‐ray diffraction analyses indicated that the copolymer composition (?‐CL/GMA) had a great influence on the thermal properties. The well‐defined, amphiphilic diblock copolymer PCL‐b‐PGMA self‐assembled into nanoscale micelles in aqueous solutions, as investigated by dynamic light scattering and transmission electron microscopy. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 5037–5049, 2007  相似文献   
40.
A dendritic macroinitiator having 16 TEMPO‐based alkoxyamines, Star‐16 , was prepared by the reaction of a dendritic macroinitiator having eight TEMPO‐based alkoxyamines, [G‐3]‐OH , with 4,4′‐bis(chlorocarbonyl)biphenyl. The nitroxide‐mediated radical polymerization (NMRP) of styrene (St) from Star‐16 gave 16‐arm star polymers with PDI of 1.19–1.47, and NMPR of 4‐vinylpyridine from the 16‐arm star polymer gave 16‐arm star diblock copolymers with PDI of 1.30–1.43. The ring‐opening polymerization of ε‐caprolactone from [G‐3]‐OH and the subsequent NMRP of St gave AB8 9‐miktoarm star copolymers with PDI of 1.30–1.38. The benzyl ether linkages of the 16‐arm star polymers and the AB8 9‐miktoarm star copolymers were cleaved by treating with Me3SiI, and the resultant poly(St) arms were investigated by size exclusion chromatography (SEC). The SEC results showed PDIs of 1.23–1.28 and 1.18–1.22 for the star polymers and miktoarm stars copolymers, respectively, showing that they have well‐controlled poly(St) arms. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 1159–1169, 2007.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号