Sonochemically synthesized core-shell structured Au–Pd nanoparticles supported on γ-Fe2O3 particles

A sample of Au–Pd bimetallic nanoparticles supported on γ-Fe₂O₃ was synthesized in a sonochemically one-pot process. The structural analyses of the synthesized sample were performed by the techniques of X-ray Absorption Fine Structure (XAFS), X-ray Diffraction (XRD), Transmission Electron Microscopy (TEM) and UV–vis spectrometry. Results indicated that the synthesized sample formed a core-shell structure in which a gold core was surrounded by a thin palladium shell. The reaction rate constant for the hydrogenation of cyclohexene of the present sample showed higher value than that of Pd nanoparticles supported on γ-Fe₂O₃ and core-shell structured Au–Pd nanoparticles supported on SiO₂. The present sample is a promising catalyst material which has a high catalytic activity.     

微型同轴脉管制冷机最低制冷温度影响因素的实验研究

本文对微型同轴脉管制冷机最低制冷温度的影响因素进行了实验研究。试验结果表明:在其他运行参数不变的情况下,随着氢浓度的逐渐减少,最低制冷温度也逐渐降低,当氢的摩尔浓度小于20％时,其最低制冷温度和纯氦相差不大。不同的氢氦配比下,该脉管制冷机的最佳运转频率为16.7 Hz。随着系统平均压力的提高,最低制冷温度也随之下降,但变化幅度越来越小。     

SryBa1－yFCl0.5Br0.5:Sm2+在光谱

本文对无机光谱烧孔系列材料SryBa1－yFCl0.5Br0.5:Sm2+中不同组份的样品(y=0,0.25.0.5,0.75.1.00)4f5d能带的激发光谱、不同温度下5D2、5D1、5D0→7F0跃迁的荧光衰减进行了测量,研究了组份的变化对4f5d能带的位置,5D2、5D1、5D0→7F0跃迁的几率和烧孔效率的影响,并得出结论:在该系列材料中,随组份y的增加,4f5d带与5DJ能级更加接近,5D0→7F0的电子跃迁几率增大,烧孔效率提高。     

Occurrence, Repetition and Matching of Patterns in the Low-temperature Ising Model

We continue our study of the exponential law for occurrences and returns of patterns in the context of Gibbsian random fields. For the low-temperature plus-phase of the Ising model, we prove exponential laws with error bounds for occurrence, return, waiting and matching times. Moreover we obtain a Poisson law for the number of occurrences of large cylindrical events and a Gumbel law for the maximal overlap between two independent copies. As a by-product, we derive precise fluctuation results for the logarithm of waiting and return times. The main technical tool we use, in order to control mixing, is disagreement percolation     

Dynamic Properties of Two-Dimensional Polydisperse Granular Gases

We propose a two-dimensional model of polydisperse granular mixtures with a power-law size distribution in the presence of stochastic driving. A fractal dimension D is introduced as a measurement of the inhomogeneity of the size distribution of particles. We define the global and partial granular temperatures of the multi-component mixture. By direct simulation Monte Carlo, we investigate how the inhomogeneity of the size distribution influences the dynamic properties of the mixture, focusing on the granular temperature, dissipated energy, velocity distribution, spatial clusterization, and collision time. We get the following results: a single granular temperature does not characterize a multi-component mixture and each species attains its own "granular temperature"; The velocity deviation from Gaussian distribution becomes more and more pronounced and the partial density of the assembly is more inhomogeneous with the increasing value of the fractal dimension D; The global granular temperature decreases and average dissipated energy per particle increases as the value of D augments.     

R410A在水平内螺纹管中沸腾换热实验研究

对于非共沸混合制冷剂R410A在外径9.52mm、5mm的两种不同的几何参数的内螺纹的流动沸腾换热进行了实验研究,分析讨论了制冷剂质量流速、管外水流量变化、强化管的参数、强化管的压降对换热系数影响以及其机理。试验的结果表明:换热系数随着流量的增大而增大,管径的大小对换热系数的影响较大,在相同的流量下,9.52mm的换热系数比5mm的大到110%~230%,5mm管的压降比9.52mm的大200%~300%。     

单级自动复叠混合工质制冷循环的实验研究

由于压缩机压比的局限,制约着单一制冷剂的压缩回热循环发展,本系统采用单一压缩机和混合工质的自复叠制冷循环系统取得了较好的制冷效果。文中对单级自动复叠制冷系统进行了理论模拟,并设计和搭建了实验台进行分析。通过理论和实验数据的分析得出混合工质组合R600a/R23,并初步得到最优配比。     

直喷式柴油机燃烧系统均匀优化设计的多维仿真研究

以直喷式柴油机的动力性和经济性为优化目标,对柴油机燃烧系统进行了基于均匀设计的多维仿真研究。通过回归分析的方法,综合考虑了柴油机的进气系统、喷油系统和燃烧室形状等参数,得到了燃烧系统参数的最优组合。结果表明:均匀设计法能以较少的仿真计算次数得到优化结果;通过回归分析和回归方程的分析得出,涡流比、油束夹角,以及涡流比和油束夹角的交互作用对柴油机的动力性和经济性影响最大;均匀设计的优化结果准确可靠,因此均匀设计法可以用于柴油机的多维仿真研究;涡流比和油束夹角的交互作用对油气混合有较大的影响。     

Regular Binary Thermal Lattice-Gases

We analyze the power spectrum of a regular binary thermal lattice gas in two dimensions and derive a Landau–Placzek formula, describing the power spectrum in the long-wavelength, low frequency domain, for both the full mixture and a single component in the binary mixture. The theoretical results are compared with simulations performed on this model and show a perfect agreement. The power spectrums are found to be similar in structure as the ones obtained for the continuous theory, in which the central peak is a complicated superposition of entropy and concentration contributions, due to the coupling of the fluctuations in these quantities. Spectra based on the relative difference between both components have in general additional Brillouin peaks as a consequence of the equipartition failure.     

WZW–Poisson manifolds

We observe that a term of the WZW-type can be added to the Lagrangian of the Poisson σ-model in such a way that the algebra of the first class constraints remains closed. This leads to a natural generalization of the concept of Poisson geometry. The resulting “WZW–Poisson” manifold M is characterized by a bivector Π and by a closed three-form H such that 1/2[Π,Π]_Schouten=H,ΠΠΠ.