全文获取类型
收费全文 | 705篇 |
免费 | 16篇 |
国内免费 | 28篇 |
专业分类
化学 | 131篇 |
晶体学 | 14篇 |
力学 | 47篇 |
数学 | 399篇 |
物理学 | 158篇 |
出版年
2024年 | 1篇 |
2023年 | 13篇 |
2022年 | 26篇 |
2021年 | 10篇 |
2020年 | 23篇 |
2019年 | 26篇 |
2018年 | 25篇 |
2017年 | 8篇 |
2016年 | 6篇 |
2015年 | 20篇 |
2014年 | 21篇 |
2013年 | 51篇 |
2012年 | 20篇 |
2011年 | 54篇 |
2010年 | 42篇 |
2009年 | 74篇 |
2008年 | 51篇 |
2007年 | 57篇 |
2006年 | 58篇 |
2005年 | 26篇 |
2004年 | 20篇 |
2003年 | 13篇 |
2002年 | 16篇 |
2001年 | 15篇 |
2000年 | 9篇 |
1999年 | 8篇 |
1998年 | 11篇 |
1997年 | 7篇 |
1996年 | 11篇 |
1995年 | 4篇 |
1994年 | 2篇 |
1993年 | 4篇 |
1992年 | 3篇 |
1991年 | 4篇 |
1990年 | 3篇 |
1989年 | 2篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1985年 | 1篇 |
1981年 | 1篇 |
1979年 | 1篇 |
排序方式: 共有749条查询结果,搜索用时 15 毫秒
111.
Developments in planar electrochromatography in open (PEC) and closed (PPEC) systems are reviewed. The discussion focuses
on progress in chamber construction for planar electrochromatography, separating system performance, equilibration of the
PPEC process, separation time and selectivity, and the general advantages, disadvantages and prospects of this separation
mode.
Presented at the 11th International Conference on Chemistry and the Environment, 9–12 September 2007, Torum, Poland. 相似文献
112.
Erich Kleinpeter Andreas Koch Bagrat A. Shainyan 《Journal of Molecular Structure》2008,863(1-3):117-122
The spatial magnetic properties (Through Space NMR Shieldings – TSNMRS) of two cyclobutadiene derivatives (2 and 5) and of a number of cyclobutadiene dianion derivatives (3, 4 and 6–8) have been calculated by the GIAO perturbation method employing the Nucleus-Independent Chemical Shift (NICS) concept of P. v. Ragué Schleyer, and visualized as Iso-Chemical-Shielding Surfaces (ICSS) of various size and direction. TSNMRS values can be successfully employed to quantify and visualize the (anti)aromaticity of the compounds studied and to discuss the influence of Li+ complexation to cyclobutadiene dianion (4a, 7 and 8) on planar 4c,6e or three-dimensional 6c,6e aromaticity. 相似文献
113.
Coulter–Matthews (CM) bent functions are from to defined by , where and (α,2n)=1. It is not known if these bent functions are weakly regular in general. In this paper, we show that when n is even and α=n+1 (or n−1), the CM bent function is weakly regular. Moreover, we explicitly determine the dual of the CM bent function in this case. The dual is a bent function not reported previously. 相似文献
114.
On stable cutsets in claw-free graphs and planar graphs 总被引:4,自引:0,他引:4
A stable cutset in a connected graph is a stable set whose deletion disconnects the graph. Let and (claw) denote the complete (bipartite) graph on 4 and vertices. It is NP-complete to decide whether a line graph (hence a claw-free graph) with maximum degree five or a -free graph admits a stable cutset. Here we describe algorithms deciding in polynomial time whether a claw-free graph with maximum degree at most four or whether a (claw, )-free graph admits a stable cutset. As a by-product we obtain that the stable cutset problem is polynomially solvable for claw-free planar graphs, and also for planar line graphs.Thus, the computational complexity of the stable cutset problem is completely determined for claw-free graphs with respect to degree constraint, and for claw-free planar graphs. Moreover, we prove that the stable cutset problem remains NP-complete for -free planar graphs with maximum degree five. 相似文献
115.
116.
Orozco J Fernández-Sánchez C Mendoza E Baeza M Céspedes F Jiménez-Jorquera C 《Analytica chimica acta》2008,607(2):176-182
This work reports on the development of a graphite-polystyrene composite electrode of planar configuration, containing silver(II) oxide and copper(II) oxide catalysts (AgO-CuO), for the measurement of electrochemical oxygen demand (EOD). Optimisation studies of the composite composition as well as conditions for its processing on planar substrates and generation of an appropriate electrochemical active area resulted in the scalable fabrication of robust composite electrodes. These were evaluated with glucose as target analyte. They showed competitive low limits of detection in a linear concentration range from 5 mg L−1 to 1400 mg L−1 of O2. Besides, they were stable for at least one year. The determination of EOD in wastewater samples coming from production lines of parenteral food and winemaking was successfully carried out. 相似文献
117.
Model biological membranes are becoming increasingly important for studying fundamental biophysical phenomena and developing membrane-based devices. To address the anticipated problem of non-physiological interactions between membrane proteins and substrates seen in “solid-supported lipid bilayers” that are formed directly on hydrophilic substrates, we have developed a polymer-tethered lipid bilayer system based on a random copolymer with multiple lipid analogue anchors and a glyco-acrylate backbone. This system is targeted at applications that, most importantly, require stability and robustness since each copolymer has multiple lipid analogues that insert into the bilayer. We have combined this copolymer with a flexible photochemical coupling scheme that covalently attaches the copolymer to the substrate. The Langmuir isotherms of mixed copolymer/free lipid monolayers measured at the air–water interface indicate that the alkyl chains of the copolymer lipid analogues and the free lipids dominate the film behavior. In addition, no significant phase transitions are seen in the isotherms, while hysteresis experiments confirm that no irreversible states are formed during the monolayer compression. Isobaric creep experiments at the air–water interface and AFM experiments of the transferred monolayer are used to guide processing parameters for creating a fluid, homogeneous bilayer. Bilayer homogeneity and fluidity are monitored using fluorescence microscopy. Continuous bilayers with lateral diffusion coefficients of 0.6 μm2/s for both leaflets of the bilayer are observed for a 5% copolymer system. 相似文献
118.
119.
The aim of this study was to obtain time-resolved images of the electrical breakdown of a planar microelectrode gap along the surface of a glass substrate in atmospheric air. The obtained images revealed details of the events leading to the breakdown. First, a point light emission appeared at the cathode, indicating breakdown initiated by the field emission of electrons from the cathode under extremely high electric fields. Then, a flare-like broad light emission was generated at the anode. Finally, breakdown occurred over the entire gap by the expansion and merger of the two emissions. 相似文献
120.
搭建了常压水超汽化实验回路(HVL-Ⅰ),采用平面激光诱导荧光(PLIF)、高速摄影、微距摄影、粒子成像测速(PIV)等先进测量技术,开展聚变堆面对等离子体部件(第一壁、偏滤器)在高热流过冷沸腾工况下强化换热特性实验研究。选择三角形和矩形翅片的铬锆铜超汽化样件,实验工况为常压室温(296K),若丹明B 水溶液流速 0.3~0.5m•s−1 连续可调,热流密度~5MW•m−2。实验结果表明同等工况下,矩形翅片比三角形翅片换热效果显著增强,性能提升约30%~50%。微距摄影显示翅根涡流形态保持时间越短,越有利于小汽泡充分扩散,从而使换热得到强化。 相似文献