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991.
A new 8 ‐pulse P hase M odulated binomial‐like selective inversion pulse sequence, dubbed ‘8PM’, was developed by optimizing the nutation and phase angles of the constituent radio‐frequency pulses so that the inversion profile resembled a target profile. Suppression profiles were obtained for both the 8PM and W5 based excitation sculpting sequences with equal inter‐pulse delays. Significant distortions were observed in both profiles because of the offset effect of the radio frequency pulses. These distortions were successfully reduced by adjusting the inter‐pulse delays. With adjusted inter‐pulse delays, the 8PM and W5 based excitation sculpting sequences were tested on an aqueous lysozyme solution. The 8 PM based sequence provided higher suppression selectivity than the W5 based sequence. Two‐dimensional nuclear Overhauser effect spectroscopy experiments were also performed on the lysozyme sample with 8PM and W5 based water signal suppression. The 8PM based suppression provided a spectrum with significantly increased (~ doubled) cross‐peak intensity around the suppressed water resonance compared to the W5 based suppression. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
992.
《Journal of Raman spectroscopy : JRS》2017,48(3):494-500
A nondestructive and sensitive method is developed to determine mixed pesticides of acetamiprid, chlorpyrifos and carbendazim in apple samples by surface‐enhanced Raman spectroscopy (SERS). Self‐modeling mixture analysis (SMA) was used to identify and extract the Raman signals of each pesticide from the spectra of apples contaminated with mixed pesticides. Results indicate that the obtained SERS signal intensities of each pesticide in their mixture have no obvious difference to the signal intensities of the corresponding pure pesticide at a low concentration. The lowest detectable level of acetamiprid, chlorpyrifos and carbendazim in apple are 0.0054 mg/kg, 0.064 mg/kg and 0.014 mg/kg, respectively, which are sensitive enough for identifying apple contaminated with pesticides above the maximum residue limit. The predicted values of each pesticide in their mixture are obtained using the prediction model based on the Raman signal of the single pesticide. The correlation coefficients of predicted values and actual values are 0.893 for acetamiprid, 0.926 for chlorpyrifos and 0.938 for carbendazim, respectively. The method presents the ultrasensitive SERS performance for quantifying residual pesticides in apple samples without sample pre‐treatment, showing great potential to serve as a useful means for monitoring pesticide residues used in mixed state. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
993.
The direct transmission of digital baseband signals has practical significance in the field of Ethernet terminal connection, high-speed digital communication, data transmission of various types of information peripherals. The signal amplitude gradually decays while the transmission distance increases. Also the attenuation is proportional to the signal frequency, resulting in signal distortion and receiving error. It is a common method for digital baseband signal transmission to use pre-emphasis chip and equalizer chip to improve the transmission quality with a wide range of mature applications. This paper describes a new type of digital signal transmission method, as the receiver using analog-to-digital converter, instead of equalizer chip, to achieve the multi-level quantization of receiving time-domain data waveform. The waveform of the transmitted digital high and low level signal is sampled into multi-bit values. Then, the paper realizes adaptive frequency domain equalization based on soft threshold and makes use of multi-level quantization soft information for error correction. Error correcting code is mainly used to correct the error caused by the channel bandwidth limit, external noise or interference in the process of data transmission, so as to improve the stability and reliability of the transmission. The paper uses the two-stage error correcting codec system based on both Turbo and BCH coding, to achieve the high performance of Turbo code, and good characters of respond time and complexity. The transmitter outputs 12.5 MHz pseudo-random sequence through a 199.93 meter unshielded balanced twisted pair transmission medium. And the receiver circuit using a 62.5MSPS analog-to-digital converter over-samples the waveform to 8-level quantity. The output error of a 65536 bit pseudo-random sequence is less than 8 bits, and the error correction can be further improved by 8b-10b codec. Compared with the traditional pre-emphasis and balanced interface ICs connection, the method described in this article has the advantages of longer transmission distance, better flexibility and wider scope of use. 相似文献
994.
《化学:亚洲杂志》2017,12(21):2780-2789
As a newly developed technique, photoelectrochemical (PEC) immunoassays have attracted great attention in recent years because of their low cost and desirable sensitivity. Because the detection signal originates from the photoelectric conversion of photoelectric materials, the appearance and application of quantum dots (QDs), which possess unique photophysical properties and regulated optoelectronic characteristics, has taken the development of PEC immunoassays to new heights. This review concisely introduces the general mechanism of QDs‐based photoelectric conversion for immunoassays and summarizes the current advances in QD applications in immunoassays. Given that signal strategies and photoactive materials are the key elements in PEC biosensor systems, we comprehensively highlight the state‐of‐the‐art signaling strategies and various applications of QDs in PEC immunoassays to introduce advances in QDs‐based PEC immunoassays. Finally, challenges and future developmental trends are briefly discussed 相似文献
995.
Simone Fiori 《Mathematical Methods in the Applied Sciences》2017,40(16):5893-5905
The present contribution focuses on the estimation of the geometric acceleration and of the geometric jolt (namely, the derivative of the acceleration) of a multidimensional, structured gyroscopic signal. A gyroscopic signal encodes the instantaneous orientation of a rigid body during a full three‐dimensional rotation that is regarded as a trajectory in the curved space SO(3) of the special orthogonal matrices. The geometric acceleration and jolt associated to a gyroscopic signal are evaluated through the rules of calculus prescribed by differential geometry. Such an endeavor is motivated by recent studies on the smoothness of human body movement in biomechanical engineering, sports science, and rehabilitation neuroengineering. Two indexes of smoothness are compared, namely, a normalized proper geometric acceleration index and a normalized proper geometric jolt index. Our investigation concludes that, in the considered experiments with measured signals, for relatively low values of the acceleration and of the jolt indexes, such indexes are strongly positively correlated. Copyright © 2017 John Wiley & Sons, Ltd. 相似文献
996.
The chirp heterodyne technique allows a directional discrimination of laser Doppler velocity measurements without the use of additional frequency shift elements. This paper presents, for the first time, the use of a chirp frequency-modulated solid-state laser, emitting in the green spectral range. Experimental results of a fluid flow measurement verify the function of the realised chirp heterodyne laser Doppler velocimeter. 相似文献
997.
两种高速CMOS图像传感器的应用与测试 总被引:2,自引:0,他引:2
采用MI-MV13和LUPA-1300-2两种不同厂家型号的高速CMOS图像传感器,设计了分辨率为1 280×1 024的300~500 frame/s高速数字工业相机,并在实验室条件下对设计相机进行了关键性能指标对比测试,得到了光谱响应及量子效率、增益、动态范围、暗电流、读出噪声、光电响应非均匀性等测试结果。测试分析显示,LUPA-1300-2的峰值量子效率为50%,比MI-MV13的峰值量子效率高12%,与厂家的参考指标基本一致。测试结果证明:该测试方法正确,对两种高速CMOS图像传感器的关键性能指标的测试客观可信,所设计的高速CMOS摄像机的性能基本满足高帧频摄像的要求。 相似文献
998.
999.
基于双数字信号处理器(DSP)的实时相关图像处理系统的设计 总被引:2,自引:0,他引:2
以两片由TI公司生产的数字信号处理器TMS320C6203B为核心,用可编程逻辑阵列CPLD进行逻辑控制,采用现场可编程门阵列FPGA作图像的预处理和进行双数字信号处理器(DSP)之间的通讯,实现了实时相关的图像处理。此系统实时性好,可直接利用数字图像的灰度特征,在低信噪比的情况下目标跟踪点漂移小,目标跟踪能够较好地适应不同灰度分布的背景。 相似文献
1000.