全文获取类型
收费全文 | 40088篇 |
免费 | 2073篇 |
国内免费 | 4979篇 |
专业分类
化学 | 29113篇 |
晶体学 | 1219篇 |
力学 | 558篇 |
综合类 | 404篇 |
数学 | 7955篇 |
物理学 | 7891篇 |
出版年
2023年 | 291篇 |
2022年 | 820篇 |
2021年 | 921篇 |
2020年 | 853篇 |
2019年 | 876篇 |
2018年 | 714篇 |
2017年 | 904篇 |
2016年 | 937篇 |
2015年 | 857篇 |
2014年 | 1283篇 |
2013年 | 2746篇 |
2012年 | 1965篇 |
2011年 | 2193篇 |
2010年 | 2044篇 |
2009年 | 2474篇 |
2008年 | 2443篇 |
2007年 | 2535篇 |
2006年 | 2336篇 |
2005年 | 2157篇 |
2004年 | 2185篇 |
2003年 | 1802篇 |
2002年 | 1573篇 |
2001年 | 1229篇 |
2000年 | 1974篇 |
1999年 | 1469篇 |
1998年 | 1352篇 |
1997年 | 741篇 |
1996年 | 729篇 |
1995年 | 646篇 |
1994年 | 615篇 |
1993年 | 530篇 |
1992年 | 511篇 |
1991年 | 353篇 |
1990年 | 232篇 |
1989年 | 242篇 |
1988年 | 211篇 |
1987年 | 164篇 |
1986年 | 118篇 |
1985年 | 134篇 |
1984年 | 138篇 |
1983年 | 47篇 |
1982年 | 96篇 |
1981年 | 128篇 |
1980年 | 109篇 |
1979年 | 114篇 |
1978年 | 90篇 |
1977年 | 77篇 |
1976年 | 57篇 |
1974年 | 25篇 |
1973年 | 32篇 |
排序方式: 共有10000条查询结果,搜索用时 855 毫秒
991.
R. D. Sinisterra R. Najjar O. L. Alves P. S. Santos C. A. Alves De Carvalho A. L. Conde Da Silva 《Journal of inclusion phenomena and macrocyclic chemistry》1995,22(2):91-98
The preparation and characterization of the 1:1 inclusion compound of rhodium(II) -methyl cinnamate in -cyclodextrin is reported. Evidence of inclusion was obtained from X-ray powder diffraction results, Raman, IR and UV-Vis spectroscopic studies and thermal analysis. Given the potential antitumor activity of the rhodium(II) carboxylate and its virtual insolubility in water, its inclusion in -cyclodextrin opens the possibility for its transference to the aqueous phase. 相似文献
992.
The regio- and stereoselectivity of the reactions of carbanions, generated from alkanals, carboxylates of the type XYCHCOOEt (X = EtOOC, CN, Ac; Y = H, Br), or derivatives of 3-methyl-4-phosphono-2-butenoic acid using PTC techniques, with aldehydes of various types (alkanals, ,-enals, cross-conjugated enedials, benzaldehydes,etc.) are reviewed. The factors affecting the outcome of these reactions are discussed. The carbanion analogs, triphenylphosphorus ylides, are shown to attack selectively at one of the aldehyde groups of aromatic dialdehydes. The regularities found for the title reactions were used in the syntheses of some biologically active isoprenoids.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1867–1885, October, 1995. 相似文献
993.
A. R. Burilov D. V. Cherepachkin I. L. Nikolaeva M. A. Pudovik 《Russian Chemical Bulletin》1995,44(2):345-349
Some newS-phosphorylated,S-silylated, andS-stannylated derivatives of -mercaptoketones were obtained. The reactions of some of these compounds induced by the temperature and by molecular oxygen as well as the phosphorylation of the Si- and Sn-containing derivatives were studied.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 353–357, February, 1995. 相似文献
994.
Highly efficient kinetic resolution of racemic secondary alkyl diazoacetates in intramolecular carbon-hydrogen insertion reactions has been achieved using chiral dirhodium(ii) carboxamidates. Products formed from catalytic diazo decomposition of racemic 2-octyl diazoacetate and, separately, its (2R)- and (2S)-enantiomeric forms, as well as bothcis- andtrans-2-methylcyclohexyl diazoacetates, have been systematically evaluated. Enantioselectivities up to 99 %ee have been obtained for -lactone formation. -Lactone production has been observed and, although minor with cyclohexyl diazoacetates, is the major insertion pathway for diazo decomposition of 2-octyl diazoacetate.Dedicated to Academician of the RAS N. S. Zefirov (on his 60th birthday).Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1798–1803, September, 1995.Financial support for this research from the National Institutes of Health (GM 46503) and the National Science Foundation of the United States is gratefully acknowledged. We thank D. A. Pierson for her preparation of 2-methylcyclohexyl diazoacetates and preliminary studies of their diazo decomposition and A. Melekhov from the Higher College of Chemistry for his preparation and catalytic studies of rac-2-octyl diazoacetate. 相似文献
995.
M. W. Evans 《Foundations of Physics Letters》1995,8(3):253-259
By using an 0(3) gauge group, a non-Abelian theory of vacuum electrodynamics is developed in which the newly discovered longitudinal vacuum fieldsB
(3) andi
E
(3) appear self-consistently with the usual plane wavesB
(1),B
(2),E
(1), andE
(2) in the circular basis (1), (2), (3), a complex representation of space. Using the charge quantization condition the vacuum Maxwell equations are given in the non-Abelian representation. 相似文献
996.
M. Daszewski Z. Janas W. Kurcewicz B. Szweryn 《Zeitschrift für Physik A Hadrons and Nuclei》1995,351(2):225-228
The internal bremsstrahlung spectrum of55Fe was studied using HPGe detector in low background and reduced pileup conditions. The data show that the conclusion on the presence of a heavy mass neutrino strongly depends from the experimental decay energy value taken in the analysis. The decay energy was found to beQ
EC
=231.37 ± 0.10 keV. The obtained results also show the need for the higher accuracyQ
EC
used in the analysis of the existence of a 17-keV neutrino in the55Fe decay.The authors would like to thank A. Plochocki and J. ylicz for helpful discussion and assistance. 相似文献
997.
We report the first experimental observation of the excitation of the 4p
2
P
3/2, 1/2 resonance states of Ca II (located at 74 720.4 and 74 497.5 cm–1 above the ground state of Ca I) following pulsed-laser pumping of the 4s
2
1
S
O–4s4p
3P1 intercombination transition of Ca I (E
ex = 15 210 cm–1). Large scale collisional transfer of energy between the laser-excited atoms is believed to be responsible for this. This is possibly because sufficient time is available (rad of the 4s4p
3
P
1 state is approximately 350 µs) for collisions to build such a high level of excitation. Some interesting additional features of the fluorescence spectra of the laser-pumped Ca vapor, such as temperature dependence of the fluorescence intensities and evolution in time of some selected states, are also presented. 相似文献
998.
G. Köhler H. Martinek W. Parasuk K. Rechthaler P. Wolschann 《Monatshefte für Chemie / Chemical Monthly》1995,126(3):299-301
Summary Piperidinomethyl-2-naphthol forms inclusion complexes with -cyclodextrin with an equilibrium constant of 265M
–1 in aqueous solution. The proton transfer equilibrium between the neutral and the zwitterionic form is strongly influenced by the association.
Der Einfluß der Komplexierung mit -Cyclodextrin auf das Protontransfer-Gleichgewicht in Piperidino-2-naphthol (Kurze Mitt.)
Zusammenfassung Piperidinomethyl-2-naphthol bildet Einschlußkomplexe mit -Cyclodextrin mit einer Gleichgewichtskonstante von 265M –1. Das Protontransfer-Gleichgewicht zwischen neutraler Form und zwitterionischer Struktur wird durch diese Assoziation stark beeinflußt.相似文献
999.
Sérgio L. C. Ferreira Neyla M. L. Araújo Adriana B. Santos Alailson F. Dantas A. C. Spinola Costa 《Mikrochimica acta》1995,118(1-2):123-129
TAN reacts with zinc(II) forming a red complex with composition 1:2 Zn(II)-TAN and absorption maximum at 582 nm. Zinc can be determined with this reagent in the presence of Triton X-100, in the pH range 6.20-8.00 with a molar absorptivity of 4.5×104 l/mol/cm Beer's Law was obeyed up to least 1.55 g/ml. Copper interference was eliminated with a mixture of thiosulfate and ascorbic acid and nickel separated by precipitation with dimethylglyoxime. The proposed method was used for zinc determination in several copper-base alloys and the results of analysis in comparison with certified values indicated that the procedure was accurate and precise. A derivative procedure is also proposed, allowing zinc determination with high sensitivity (5-400 ng/ml). 相似文献
1000.
A. Zielenkiewicz K. Busserolles G. Roux-Desgranges A. H. Roux J-P. E. Grolier W. Zielenkiewicz 《Journal of solution chemistry》1995,24(7):623-632
Densities and specific heat capacities of ternary aqueous systems containing dipeptides (glycyl-glycine or L--alanyl-L--alanine) and nucleic acid bases (cytosine or thymine) or their alkyl derivatives (1,3-diethylthymine or caffeine) were determined at 25°C by flow calorimetry and flow densimetry. The partial molar volumes and heat capacities of transfer at infinite dilution of the different nucleic acid bases from water to water+dipeptide solutions were obtained therefrom. Except for the case of the transfer of cytosine to aqueous glycyl-glycine solutions where a small positive dependence of the transfer quantities was observed with the dipeptide concentration, the values of the heat capacities of transfer were in general low, positive or negative, depending on the compensation of hydrophobic-hydrophilic interactions between the dipeptide and the base. The volumes of transfer of most of the bases are very small, within the limit of the experimental error. 相似文献