硅异质结太阳电池的物理机制和优化设计

硅异质结太阳电池是一种由非晶硅薄膜层沉积于晶硅吸收层构成的高效低成本的光伏器件,是一种具有大面积规模化生产潜力的光伏产品.异质结界面钝化品质、发射极的掺杂浓度和厚度以及透明导电层的功函数是影响硅异质结太阳电池性能的主要因素.针对这些影响因素已经有大量的研究工作在全世界范围内展开,并且有诸多研究小组提出了器件效率限制因素背后的物理机制.洞悉物理机制可为今后优化设计高性能的器件提供准则.因此及时总结硅异质结太阳电池的物理机制和优化设计非常必要.本文主要讨论了晶硅表面钝化、发射极掺杂层和透明导电层之间的功函数失配以及由此形成的肖特基势垒;讨论了屏蔽由功函数失配引起的能带弯曲所需的特征长度,即屏蔽长度;介绍了硅异质结太阳电池优化设计的数值模拟和实践;总结了硅异质结太阳电池的研究现状和发展前景.     

A Class of Perfect Ternary Constant-Weight Codes

We construct a class of perfect ternary constant-weight codes of length 2 ^r , weight 2 ^r -1 and minimum distance 3. The codes have codewords. The construction is based on combining cosets of binary Hamming codes. As a special case, for r=2 the construction gives the subcode of the tetracode consisting of its nonzero codewords. By shortening the perfect codes, we get further optimal codes.     

线性流形上对称自正交相似矩阵最佳逼近

讨论了线性流形上对称自正交相似矩阵的最小二乘解,得到了解的一般表达式,对于任意给定的矩阵A*,在最小二乘解集中得到了的A的最佳逼近解.     

Optimal Bounded Control for Minimizing the Response of Quasi Non-Integrable Hamiltonian Systems

A strategy for designing optimal bounded control to minimize theresponse of quasi non-integrable Hamiltonian systems is proposed basedon the stochastic averaging method for quasi non-integrable Hamiltoniansystems and the stochastic dynamical programming principle. Theequations of motion of a controlled quasi non-integrable Hamiltoniansystem are first reduced to an one-dimensional averaged Itô stochasticdifferential equation for the Hamiltonian by using the stochasticaveraging method for quasi non-integrable Hamiltonian systems. Then, thedynamical programming equation for the control problem of minimizing theresponse of the averaged system is formulated based on the dynamicalprogramming principle. The optimal control law is derived from thedynamical programming equation and control constraints without solvingthe equation. The response of optimally controlled systems is predictedthrough solving the Fokker–Planck–Kolmogrov (FPK) equation associatedwith completely averaged Itô equation. Finally, two examples are workedout in detail to illustrate the application and effectiveness of theproposed control strategy.     

具有内生人口规模的城市经济增长模型

本文研究了城市经济增长与人口规模的相互关系.通过引入含消费与舒适度的双变量效用函数,提出了城市居民效用最大化问题.利用动态优化与动力系统,得出描述模型的二维动力系统,具有唯一双曲型平衡点和优化问题存在唯一最优增长路径.因而,对城市经济增长存在最优的人口规模.     

城市交通管理中的出租车规划

根据城市的发展情况以及类比其他城市的发展状况,对城市交通出行情况建立模型,对城市出租车的数量及乘坐人口做出预测;并针对目前的油价上涨给出租车行业带来的收入问题做出分析;建立最优化问题对驾驶员和顾客的满意进行描述,最终给出合理的价格调整方案.     

毛细管电泳分离过程的不可逆热力学模型及优化控制仿真

以非平衡热力学分离理论为框架,建立了毛细管电泳分离大系统的分离模型。以分离过程的操作电压U为控制量,以溶质体系的净分离熵S~S作为目标函数,通过对分离大系统的优化设计,得到了最优操作电压控制轨线U^*(t)。通过仿真,证明了分离大系统在此最优控制规律作用下,分离效果最好。     

基于最优滤波器的强混沌背景中谐波信号检测方法研究

强混沌背景中的微弱谐波信号检测有重要的工程研究意义. 目前的检测方法主要是基于Takens理论的混沌相空间重构方法, 然而这些方法往往对信干噪比要求高, 且对高斯白噪声敏感等. 本文注意到混沌信号的二阶统计特性是不变的, 根据这个特点提出了一种基于最优滤波器的强混沌背景中的微弱谐波信号检测方法. 该方法首先构建一个数据矩阵, 在频域上对每个频率通道分别检测谐波信号, 从而将信号检测问题转化为最优化问题, 然后利用最优化理论设计滤波器, 使待检测频率通道的信号增益保持不变, 而尽量抑制其他频率通道的信号, 最后通过判断每一频率通道的输出信干噪比来检测谐波信号. 与传统方法相比, 本文方法有如下优点: 1)可以检测更低信干噪比下的微弱谐波信号; 2)可检测的信号幅度范围更大; 3)抗白噪声性能更强. 仿真结果证明了本文方法的有效性.     

RMSD and Symmetry

A common approach for comparing the structures of biomolecules or solid bodies is to translate and rotate one structure with respect to the other to minimize the pointwise root-mean-square deviation (RMSD). We present a new, robust numerical algorithm that computes the RMSD between two molecules or all the mutual RMSDs of a list of molecules and, if desired, the corresponding rotation matrix in a minimal number of operations as compared to previous algorithms. The RMSD gradient can also be computed. We address the problem of symmetry, both in alignment (possible alternative alignments due to indistinguishable atoms) as well as geometry. In the latter case, it is possible to have degenerate superposition. A necessary condition is optimal superimposability to one's mirror image. Double (respectively, triple) degeneracy results in a one- (respectively, two)-parameter family of rotations leaving the superposition invariant. The software, frmsd , is freely available at http://www.ams.stonybrook.edu/~coutsias/codes/frmsd.tgz . © 2019 Wiley Periodicals, Inc.     

Influence of PtMo Structure and Composition on the Adsorption Energies, Adsorption Site and Vibrational Frequency of Carbon Monoxide

Density functional theory periodic slab calculations were carried out for CO adsorption on a series of Mo modified Pt(111) surfaces to provide an insight into the interaction between CO and doped metal surface, an important issue in CO oxidation as well as in promotion and poisoning effects of catalysis. The modification of adsorption properties with respect to those of adsorption on the pure Mo(110) and Pt(111) is described in terms of changes in the adsorption energies, adsorption sites and vibrational properties occurring upon alloying. We believe that the present DFT calculations can provide important information into optimal alloy composition for CO-tolerance, which is not easily obtained by experimental methods.