全文获取类型
收费全文 | 13446篇 |
免费 | 2320篇 |
国内免费 | 1222篇 |
专业分类
化学 | 3319篇 |
晶体学 | 226篇 |
力学 | 3548篇 |
综合类 | 160篇 |
数学 | 2355篇 |
物理学 | 7380篇 |
出版年
2024年 | 26篇 |
2023年 | 119篇 |
2022年 | 307篇 |
2021年 | 394篇 |
2020年 | 382篇 |
2019年 | 339篇 |
2018年 | 324篇 |
2017年 | 442篇 |
2016年 | 579篇 |
2015年 | 529篇 |
2014年 | 762篇 |
2013年 | 1239篇 |
2012年 | 838篇 |
2011年 | 1002篇 |
2010年 | 820篇 |
2009年 | 963篇 |
2008年 | 990篇 |
2007年 | 965篇 |
2006年 | 827篇 |
2005年 | 703篇 |
2004年 | 590篇 |
2003年 | 569篇 |
2002年 | 472篇 |
2001年 | 406篇 |
2000年 | 367篇 |
1999年 | 321篇 |
1998年 | 357篇 |
1997年 | 215篇 |
1996年 | 176篇 |
1995年 | 132篇 |
1994年 | 149篇 |
1993年 | 125篇 |
1992年 | 89篇 |
1991年 | 82篇 |
1990年 | 62篇 |
1989年 | 43篇 |
1988年 | 43篇 |
1987年 | 39篇 |
1986年 | 33篇 |
1985年 | 48篇 |
1984年 | 25篇 |
1983年 | 18篇 |
1982年 | 18篇 |
1981年 | 8篇 |
1980年 | 8篇 |
1979年 | 10篇 |
1978年 | 6篇 |
1976年 | 5篇 |
1973年 | 3篇 |
1957年 | 6篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
181.
扩散限制聚集与粘性指化图案的模拟研究顾健德,田安民,鄢国森(四川大学化学系,成都,610064)关键词DLA,粘性指化,计算机模拟大自然经常以非常奇妙的方式向人们展示其魅力,吸引人们不断去思考和探索.四川大学图书馆文献阅览室的玻璃顶棚上出现的粘性指化... 相似文献
182.
The percolation transition of geometric clusters in the three-dimensional, simple cubic, nearest neighbor Ising lattice gas model is investigated in the temperature and concentration region inside the coexistence curve. We consider quenching experiments, where the system starts from an initially completely random configuration (corresponding to equilibrium at infinite temperature), letting the system evolve at the considered temperature according to the Kawasaki spinexchange dynamics. Analyzing the distributionn
l(t) of clusters of sizel at timet, we find that after a time of the order of about 100 Monte Carlo steps per site a percolation transition occurs at a concentration distinctly lower than the percolation concentration of the initial random state. This dynamic percolation transition is analyzed with finite-size scaling methods. While at zero temperature, where the system settles down at a frozen-in cluster distribution and further phase separation stops, the critical exponents associated with this percolation transition are consistent with the universality class of random percolation, the critical behavior of the transient time-dependent percolation occurring at nonzero temperature possibly belongs to a different, new universality class. 相似文献
183.
Ludwik Adamowicz Rodney J. Bartlett Józef S. Kwiatkowski Willis B. Person 《Theoretical chemistry accounts》1988,73(2-3):135-145
The diatomic systems, PO and PO– are studied, using numerical Hartree-Fock (NHF) and coupled-cluster calculations. The latter employs a hybrid NHF and Slater orbital basis set. Highly accurate CCSD methods predict bond lengths accurate to <0.004 Å and frequencies to 60 cm–1. In addition the electron affinity of PO is computed to be 0.89 eV compared to an experimental value of 1.09±0.01. Comparisons are made with SCF and MBPT(2) results for PO+ using conventional basis sets.Dedicated to Professor J. Koutecký on the occasion of his 65th birthdayGuggenheim Fellow 相似文献
184.
《Electroanalysis》2004,16(16):1359-1365
Electrochemical oxidation of catechols has been studied in the presence of cyanide ion as nucleophile in aqueous solution, by means of cyclic voltammetry and controlled‐potential coulometry. The results indicate that the participation of catechols in the Michael reaction with cyanide ion to form the corresponding o‐dihydroxybenzonitrile. Based on an EC mechanism, the homogeneous rate constants were estimated by comparing the experimental cyclic voltammetric responses with the digital simulated results. 相似文献
185.
从共聚单体的竞聚率、油相水相分布系数出发,通过动力学模拟计算了丙烯酸丁酯与醋酸乙烯酯乳液共聚物的链结构,并用Johnson公式对其玻璃化转变温度(T_g)进行了理论计算,给出了共聚物T_g及其对应聚合物的重量分布图。发现半连续共聚物有1个T_g,其值随共聚物组成而变化;但一步法共聚物有两个T_g:低温区T_g代表富丙烯酸丁酯共聚物,高温区T_g则代表PVA均聚物。计算结果与实验十分吻合。 相似文献
186.
应用分子动力学模拟了25 ℃和50 ℃时新型室温熔盐二(三氟甲基磺酸酰)亚胺锂[LiN(SO2CF3)2, LiTFSI]与尿素(摩尔比为1:3.6)体系的结构与动力学性质. 在两个温度下体系的微观结构基本相同, Li+的配位数约为5, 且都是与溶剂和阴离子中的氧原子发生配位. 对TFSI-的研究表明, 每个TFSI-只提供四个氧中的一个与Li+配位; 而且在Li+的配位层中, TFSI-具有顺、反和gauche 等不同的构象, 并且不同构象出现的几率会随着温度的改变而改变. 相似文献
187.
José A. Delgado María A. Uguina José L. Sotelo Beatriz Ruíz José M. Gómez 《Adsorption》2006,12(1):5-18
The adsorption of carbon dioxide and methane on silicalite pellets packed on a fixed bed has been studied. Equilibrium and
kinetic measurements of the adsorption of carbon dioxide and methane have been performed, and a binary adsorption isotherm
for carbon dioxide/methane mixtures has been obtained. A model based on the LDF approximation for the mass transfer has been
used to describe the breakthrough curves obtained experimentally. A PSA cycle has been proposed for obtaining methane with
purity higher than 98% from carbon dioxide/methane mixtures containing 38% and 50% methane, and its performance has been simulated
using the proposed model. The simulation results show that silicalite can be a suitable adsorbent for employment in a PSA
separation process for carbon dioxide removal from coalseam and landfill gases. 相似文献
188.
The molecular orientation distribution function of a stable radical 4-hydroxy-2,2,6,6-tetramethylpiperidine-1-oxyl in magnetic-field oriented 4-cyano-4’-n-pentylbiphenyl was determined from the angular dependence of the ESR spectra. The preferred molecular orientation of radical species in the liquid crystal matrix was determined. The temperature evolution of the orientation distribution function was studied.__________Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 190–195, January, 2005. 相似文献
189.
受限于纳米碳管中的乙醇分子的结构和扩散的分子模拟研究 总被引:1,自引:0,他引:1
利用分子模拟研究了常温常压下受限于(8,8) (管径1.081 nm)和(15,15) (管径 2.035 nm)单壁纳米碳管中的乙醇分子. 对受限分子的径向密度分布和氢键等静态性质以及扩散性质进行了分析. 结果显示在管内乙醇分子的平均氢键数目和主体相一致. 乙醇分子在(8,8)碳管内具有高度有序的结构, 而在(15,15)碳管内由于空间的增大导致结构有序度的降低, 其中分子取向已呈随机分布. 进一步对扩散系数的分析发现, 在管内乙醇分子的轴向扩散系数低于主体相, 特别在(8,8)碳管内乙醇分子几乎丧失了轴向扩散能力. 相似文献
190.
Barthez J.M. Molino F. Marignan J. Ayral A. Guizard C. Jullien R. 《Journal of Sol-Gel Science and Technology》1997,8(1-3):83-88
We present here an experimental and numerical study of the chemical and aggregative mechanisms for titanium alkoxide in a
reverse micellar medium. NMR experiments were done to study the first step of the sol-gel process: hydrolysis of titanium
isopropoxide. Light and X-ray scattering experiments were then conducted to characterize the clustering of aggregates and
aggregation kinetics. Fractal dimension, measured by U.S.A.X.S., varies with the hydrolysis ratio and the hydration of the
surfactant. This evolution was explained by polydispersity of the hydrolysis which depends on the surfactant concentration.
This hypothesis was tested through a numerical simulation of irreversible aggregation using a chemically limited aggregation
model. The hydrolyzed sites are distributed among the monomers by a random procedure governed by a polydispersity parameterp, varying from 0 to 1. The total number of hydrolyzed sites is governed by a parameterq belonging to the interval [0, 1]. Thep-q evolution of the fractal dimension coincides rather well with the experimental data in all the region of the two dimensional
phase space. 相似文献