氢原子钟壁移的测量和消除

指出了克服氢原子钟壁移问题的必要性. 给出了一种测量氢钟壁移的简易方法,讨论了减小壁移的技术. 该文的方法和技术有助于进一步改善氢原子钟的长期稳定度.     

Fourier transform spectroscopy of CH3OH: rotation-torsion-vibration structure for the CH3-rocking and OH-bending modes

High-resolution Fourier transform spectra of CH₃OH have been investigated in the infrared region from 930 to 1450 cm⁻¹ in order to map the torsion-rotation energy manifolds associated with the ν₇ in-plane CH₃ rock, the ν₁₁ out-of-plane CH₃ rock, and the ν₆ OH bend. Upper-state term values have been determined from the assigned spectral subbands, and have been fitted to power-series expansions to obtain substate origins and effective B-values for the three modes. The substate origins have been grouped into related families according to systematic trends observed in the torsion-vibration energy map, but there are substantial differences from the traditional torsional patterns. There appears to be significant torsion-mediated spectral mixing, and a variety of “forbidden” torsional combination subbands with |Δυ_t|>1 have been observed, where υ_t denotes the torsional quantum number (equivalent to υ₁₂). For example, coupling of the (υ₆,υ_t)=(1,0) OH bend to nearby torsionally excited (υ₇,υ_t)=(1,1) CH₃-rock and (υ₈,υ_t)=(1,1) CO-stretch states introduces (υ₆,υ_t)=(1,0)←(0,1) subbands into the spectrum and makes the ν₇+ν₁₂−ν₁₂ torsional hot band stronger than the ν₇ fundamental. The results suggest a picture of strong coupling among the OH-bending, CH₃-rocking, and CO-stretching modes that significantly modifies the traditional energy structure and raises interesting and provocative questions about the torsion-vibration identity of a number of the observed states.     

Standing waves, clustering, and phase waves in 1D simulations of kinetic relaxation oscillations in NO+NH3 on Pt(1 0 0) coupled by diffusion

The Lombardo–Imbihl–Fink (LFI) ODE model of the NO+NH₃ reaction on a Pt(1 0 0) surface shows stable relaxation oscillations with very sharp transitions for temperatures T between 404 and 433 K. Here we study numerically the effect of linear diffusive coupling of these oscillators in one spatial dimension. Depending on the parameters and initial conditions we find a rich variety of spatio-temporal patterns which we group into four main regimes: bulk oscillations (BOs), standing waves (SW), phase clusters (PC), and phase waves (PW). Two key ingredients for SW and PC are identified, namely the relaxation type of the ODE oscillations and a nonlocal (and nonglobal) coupling due to relatively fast diffusion of the kinetically slaved variables NH₃ and H. In particular, the latter replaces the global coupling through the gas phase used to obtain SW and PC in models of related surface reactions. The PW exist only under the assumption of (relatively) slow diffusion of NH₃ and H.     

Scattering problem with nonlocal separable potential of rank-two: Application to statistical mechanics

In this paper, we present a formulation of statistical mechanics of a thermodynamic system consisting of free particles and independent correlated pairs interacting via nonlocal potential in terms of the scattering properties. Some quantum statistical properties such as energy, heat capacity, second virial coefficient, virial pressure and quantum correction of kinetic energy are described analytically. The difference between the resolvents of the interacting and free Hamiltonians, represented as , that is associated with particle correlations is used for the evaluation of the properties. The statistical properties are related to correlated states, when making a pole expansion of the analytically continued momentum matrix element of . The present work illustrates these relations for a three-dimensional nonlocal separable potential of rank-two.     

平板混合层流动中两相脉动关联矩的大涡模拟

在气粒两相平板混合层流动中,对气相流动采用大涡模拟,对颗粒相流动采用轨道模拟,研究了两相脉动关联矩。由两相各自瞬时速度出发可以直接获得两相脉动关联矩的统计结果。模拟获得的颗粒相一阶矩、二阶矩以及两相脉动关联矩与实验结果定量符合,表明基于细观模拟是不通过模型获得和研究两相脉动关联矩的可行途径。     

氢气扩散火焰中辐射源项湍流脉动特征的PDF模拟

采用κ-ε湍流模型、标量联合的概率密度函数(PDF)输运方程和层流火焰面模型相结合,模拟氢气自由扩散火焰中辐射源项湍流脉动特征.给出了主燃区内辐射源项湍流脉动的频率图.辐射源项的样本点分布集中,大约95%以上的样本落在其系综的±3倍方差以内,频谱图为单峰.     

An interplay between static potential and Reggeon trajectory for QCD string

I consider two cases where QCD string is described by an effective theory of long strings: the static potential and meson scattering amplitudes in the Regge regime. I show how they can be solved in the mean-field approximation, justified by the large number of space–time dimensions, and argue that it turns out to be exact. I compare contributions from QCD string and perturbative QCD and discuss experimental consequences for the scattering amplitudes.     

Wave propagation in viscoelastic single-walled carbon nanotubes with surface effect under magnetic field based on nonlocal strain gradient theory

The governing equation of wave motion of viscoelastic SWCNTs (single-walled carbon nanotubes) with surface effect under magnetic field is formulated on the basis of the nonlocal strain gradient theory. Based on the formulated equation of wave motion, the closed-form dispersion relation between the wave frequency (or phase velocity) and the wave number is derived. It is found that the size-dependent effects on the phase velocity may be ignored at low wave numbers, however, is significant at high wave numbers. Phase velocity can increase by decreasing damping or increasing the intensity of magnetic field. The damping ratio considering surface effect is larger than that without considering surface effect. Damping ratio can increase by increasing damping, increasing wave number, or decreasing the intensity of magnetic field.