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91.
92.
通过双醚化反应、氯甲基化反应以及在强碱性条件下进行的脱氯化氢反应制备聚(2-甲氧基-5-丁氧基)对苯乙炔(PMOBOPV)、聚(2-甲氧基-5-己氧基)对苯乙炔(PMOHOPV)、聚(2,5-二丁氧基)对苯乙炔(PDBOPV)和聚(2,5-二己氧基)对苯乙炔(PDHOPV)等四种可溶性聚对苯乙炔(PPV)衍生物,通过紫外-可见吸收光谱对产物分子结构进行表征.结果显示,PMOBOPV、PMOHOPV、PDBOPV和PDHOPV的共轭π电子发生π → π* 跃迁的吸收峰分别位于491 nm、495nm、504nm和510nm处,相应的光学禁带宽度分别为2.23eV、2.18eV、2.12eV和2.07eV.利用简并四波混频技术测量PPV衍生物的三阶非线性光学性能,探讨了分子结构对PPV衍生物三阶非线性极化率(χ(3))的影响.研究发现,激发波长为532 nm时,PMOBOPV、PMOHOPV、PDBOPV和PDHOPV的共振χ(3)值分别为3.45×10-10、5.13×10-10、7.15×10-10和9.61×10-10 esu;激发波长为1064 nm时,它们的非共振χ(3)值分别为1.09×10-11、1.42×10-11、1.62×10-11和2.14×10-11 esu. 相似文献
93.
In this paper, we applied multifractal modeling techniques to analyze the traffic data collected from the Beijing Yuquanying. The results indicated that multifractal characteristics obviously exist in the traffic system; the degree of fractality of these traffic data tends to increase as the traffic system becomes congested; the Hölder exponent that measures the local rate of fractality may be used as indicators to predict the presence of the traffic congestion. 相似文献
94.
In this paper, the nonlinear Boussinesq equations with the conformable time-fractional derivative are solved analytically using the well-established modified Kudryashov method. As a consequence, a number of new exact solutions for this type of equations are formally derived. It is believed that the method is one of the most effective techniques for extracting new exact solutions of nonlinear fractional differential equations. 相似文献
95.
Fern Sassower Sisser 《Mathematical Programming》1981,20(1):110-121
The problem of minimizing a nonlinear objective function ofn variables, with continuous first and second partial derivatives, subject to nonnegativity constraints or upper and lower bounds on the variables is studied. The advisability of solving such a constrained optimization problem by making a suitable transformation of its variables in order to change the problem into one of unconstrained minimization is considered. A set of conditions which guarantees that every local minimum of the new unconstrained problem also satisfies the first-order necessary (Kuhn—Tucker) conditions for a local minimum of the original constrained problem is developed. It is shown that there are certain conditions under which the transformed objective function will maintain the convexity of the original objective function in a neighborhood of the solution. A modification of the method of transformations which moves away from extraneous stationary points is introduced and conditions under which the method generates a sequence of points which converges to the solution at a superlinear rate are given. 相似文献
96.
A mean-field model of nonlinearly coupled oscillators with randomly distributed frequencies and subject to independent external white noises is analyzed in the thermodynamic limit. When the frequency distribution isbimodal, new results include subcritical spontaneous stationary synchronization of the oscillators, supercritical time-periodic synchronization, bistability, and hysteretic phenomena. Bifurcating synchronized states are asymptotically constructed near bifurcation values of the coupling strength, and theirnonlinear stability properties ascertained. 相似文献
97.
讨论了具有有界随机参数的随机Bonhoeffer-Van der Pol系统的随机混沌现象,并利用噪声对其进行控制.首先运用Chebyshev多项式逼近的方法,将随机Bonhoeffer-Van der Pol系统转化为等价的确定性系统,使原系统的随机混沌控制问题转换为等价的确定性系统的确定性混沌控制问题,继而可用Lyapunov指数指标来研究等价确定性系统的确定性混沌现象和控制问题.数值结果表明,随机Bonhoeffer-Van der Pol系统的随机混沌现象与相应的确定性Bonhoeffer-Van der Pol系统极为相似.利用噪声控制法可将混沌控制到周期轨道,但是在随机参数及其强度的影响下也呈现出一些特点. 相似文献
98.
Y. KatoD. Ichii K. OhashiH. Kunugita K. Ema K. TanakaT. Takahashi T. Kondo 《Solid State Communications》2003,128(1):15-18
We have confirmed biexciton formation in an organic-inorganic hybrid quantum-well material (C4H9NH3)2PbBr4 by photoluminescence and two-photon absorption measurements. The biexciton has extremely large binding energy, 60 meV, which to our knowledge is the largest value ever reported for a semiconductor. By analyzing the spectrum of biexciton luminescence, the biexciton gas temperature was found to be much higher than the bath temperature due to a higher local temperature arising from the large biexciton binding energy. 相似文献
99.
We investigate the temporal behavior of low-amplitude dark spatial solitons in biased centrosymmetric crystals with two-photon photorefractive effects. The expressions of time-dependent space-charge field and dynamical evolution equation are derived. The temporal behaviors of the intensity profiles and the intensity full width at half maximum (FWHM) of dark solitons are investigated by numerical method. The results indicate that a broad soliton is generated at the beginning, and as time evolves, the intensity width of solitons decrease monotonously to a minimum value toward steady state. Within the same propagation time, the higher the ratio of soliton peak intensity to the dark irradiation intensity is, the shorter the FWHM of dark solitons is. 相似文献
100.
Single crystals of pure, Ca2+ and Sr2+ doped NH4Sb3F10 are grown by slow evaporation technique. The effect of dopants on the growth and physicochemical properties also have been investigated and reported for the first time. The grown crystals are characterized with the aid of single crystal X-ray diffractometry to confirm the crystal structure. EDAX studies are done to confirm the presence of dopants in the crystal lattice. The vibrational frequencies of various group ligands in the crystals have been derived from the Fourier transform infrared (FT-IR) spectrum. From the optical absorption spectrum the band gap energy was calculated and it was found to be 5.76, 6.29 and 6.35 eV for pure, Ca2+ and Sr2+ doped NH4Sb3F10 crystals respectively. Thermal stability of the sample has been analysed using TG-DTA analysis. The activation energy of pure, Ca2+ and Sr2+ doped NH4Sb3F10 crystals were calculated from the dc conductivity measurements and it is found to be 0.2728, 0.2816 and 0.3622 eV Experimental results shows improved physicochemical properties when the dopant is added to the pure material. 相似文献