全文获取类型
收费全文 | 4557篇 |
免费 | 415篇 |
国内免费 | 406篇 |
专业分类
化学 | 514篇 |
晶体学 | 12篇 |
力学 | 670篇 |
综合类 | 107篇 |
数学 | 3349篇 |
物理学 | 726篇 |
出版年
2024年 | 7篇 |
2023年 | 59篇 |
2022年 | 73篇 |
2021年 | 66篇 |
2020年 | 105篇 |
2019年 | 127篇 |
2018年 | 142篇 |
2017年 | 149篇 |
2016年 | 165篇 |
2015年 | 149篇 |
2014年 | 225篇 |
2013年 | 374篇 |
2012年 | 206篇 |
2011年 | 268篇 |
2010年 | 200篇 |
2009年 | 275篇 |
2008年 | 307篇 |
2007年 | 297篇 |
2006年 | 263篇 |
2005年 | 245篇 |
2004年 | 221篇 |
2003年 | 212篇 |
2002年 | 186篇 |
2001年 | 140篇 |
2000年 | 151篇 |
1999年 | 132篇 |
1998年 | 112篇 |
1997年 | 85篇 |
1996年 | 81篇 |
1995年 | 49篇 |
1994年 | 62篇 |
1993年 | 33篇 |
1992年 | 38篇 |
1991年 | 28篇 |
1990年 | 22篇 |
1989年 | 20篇 |
1988年 | 13篇 |
1987年 | 13篇 |
1986年 | 10篇 |
1985年 | 10篇 |
1984年 | 16篇 |
1983年 | 4篇 |
1982年 | 12篇 |
1981年 | 6篇 |
1980年 | 5篇 |
1979年 | 3篇 |
1978年 | 7篇 |
1977年 | 3篇 |
1976年 | 1篇 |
1957年 | 1篇 |
排序方式: 共有5378条查询结果,搜索用时 15 毫秒
91.
复相系平衡条件及平衡稳定性条件的分析曾丹苓(重庆大学热力工程系重庆630044)关键词复相系,平衡条件,平衡稳定性条件1引言汽液相变是工程上常见的现象,它是一个复杂的物理过程,涉及到传热传质、相转变、表面现象、流体流动及工质热物性等领域,但从热力学的... 相似文献
92.
The radiation directivity of a complicated conformal array of underwater acoustic transducers is presented based on the boundary "element method. It includes the element directivity of each transducer, the natural beam pattern and the controlled beam pattern of the transducer array. At first, the boundary element model of the conformal array is built up, and then the boundary condition is exerted on the model according to the design and environment in which the transducer array is used, and the radiation directivity of the conformal array is calculated. An experiment has been done to measure the directivity in an anechoic water tank. The calculated and the experimental results are compared and analyzed. They are consistent to each other. It is shown that the boundary element method together with the detailed calculations is successful to simulate and predict the radiation directivity of an underwater acoustic transducer array. 相似文献
93.
94.
外尔于1918年引入的规范变换实际上是相位变换而非真正的尺度变换,但规范不变性、规范理论等概念都沿袭了下来。我们发现,针对由量子化条件[x, p]=iℏ而来的量子体系之本征值问题存在规范变换,或者说尺度变换,x → x/α,p → αp,该变换保体系的能量谱不变。量子谐振子、氢原子问题及一类多体问题的精确解析解证实了这一点。量子化条件 [x, p]=iℏ看来是个对量子力学很强的约束,不止于能量的量子化。这个规范变换提醒我们相空间的体积及其量子化才是物理的关键,这也是量子力学和统计物理在潜意识里一直沿用却未予关注的思路。有趣的是,从量子谐振子体系的相空间表述似乎不能导向这个结论。如同规范理论所断言的电磁学量在给定坐标系下的数值表征与标度无关,我们认为量子体系的物理量,如能量谱等,在给定坐标系下的数值表征亦应与标度无关。此尺度变换与德布罗意关系相恰。 相似文献
95.
Titania (TiO2) photocatalysts, each embedded with one of six metals (Ag, Ce, Co, Fe, Mg, and Mn), were prepared using a simplified ultrasonic process. The characteristics of the prepared metal-embedded TiO2 (metal–TiO2) were determined using transmission electron microscopy, energy-dispersive X-ray spectroscopy, X-ray diffraction spectroscopy, photoluminescence emission spectroscopy, UV–visible spectroscopy, and nitrogen adsorption–desorption. Except for Co–TiO2, the metal–TiO2 photocatalysts showed improved performance for the decomposition of gaseous benzene and toluene, which are two of the most problematic indoor air pollutants that can cause a variety of adverse health symptoms, under daylight lamp irradiation. Photocatalytic activity was greatest for the Mg–TiO2 sample, followed by, in order, the Ag–TiO2, Ce–TiO2, Fe–TiO2, Mn–TiO2, unmodified TiO2, and Co–TiO2 samples. Although Mg–TiO2 showed the least redshift in its light absorption and the highest electron–hole recombination rate among the metal–TiO2 photocatalysts, it yielded the highest photocatalytic activity, likely because of its increased adsorption capacity and anatase composition. The degradation of benzene and toluene over Mg–TiO2 improved as ultrasound treatment amplitude increased from 20 to 37 μm, then decreased gradually as amplitude was further increased to 49 μm. Degradation efficiency also improved as ultrasound operation time increased from 30 to 60 min, then decreased gradually as amplitude was further increased to 90 min. Overall, this process could be utilized to prepare metal–TiO2 photocatalysts with improved performance for the decomposition of gas phase pollutants under daylight lamp irradiation. 相似文献
96.
J. Pouget 《Phase Transitions》2013,86(1-4):251-260
On the basis of a lattice model the domain structure for ferroelastic transformations is examined. The model accounts for both strongly nonlinear and competing interactions which allow for, in some situations, the propagation of nonlinear excitations. The model can be mostly applied to proper ferroelastic transformations of which In-Tl, Ti-Ni, etc.… are good prototypes. The phonon dispersion of the transverse acoustic waves obtained in the linearized case is discussed and the results show first a phonon softening at nonzero wave-number and next an upwards convexity of the phonon branch near the long-wavelength limit. This can be seen as pre-transitional effects. In a fully nonlinear case we consider vanishing dilatation transformations and the continuum approximation is applied to the one-dimensional version. Then, we investigate nonlinear excitations; three main classes of solution are found: i) quasi-harmonic solutions corresponding to periodically modulated structures in space which is a precursor effect of the elastic transformation, ii) an array of solitons made of periodic arrangements of parent-elastic domains and iii) a moving strain soliton. All the significant results are numerically illustrated by means of the microscopic model. Finally, the similarity to martensitic transformations and some extensions of the model are outlined. 相似文献
97.
Guangwen Yang Wentao Wu Zhixiang Li Naiwu Chen Jian Qin Guoping Hu Yang Zhang Jian Li Shuhui Chen 《Tetrahedron letters》2018,59(6):532-536
hNav1.7 had received great interest in the past decade owing to its attractive mechanism of actions in pain processing pathway. More recently, we developed a series of efficacious hNav1.7 inhibitors for analgesic, which were characterized with a novel aminocyclohexene as pharmacophore. Herein, we reported our synthetic efforts to construct the unique scaffold, which can be rapidly accessed from readily available 7-azanorbornenes via an unexpected catalyst-free, LiAlH4 mediated tandem double bond migration-ring opening sequence. A probable mechanism was proposed to illuminate the good regio- and stereoselectivity. 相似文献
98.
《应用有机金属化学》2017,31(6)
{Fe3O4@SiO2@(CH2)3‐thiourea dioxide‐SO3H/HCl}, a newly reported nanomagnetic core–shell supported solid acid catalyst, was successfully employed in the preparation of 4,4′‐(arylmethylene)bis(1H –pyrazol‐5‐ol) and pyrano[3,2‐c ]pyrazole derivatives. The presented methods are very efficient and high‐yielding. Also, the catalyst exhibited powerful potential for reusability in both types of reactions. 相似文献
99.
By taking the coupling effect into consideration, we study the resonance condition of a photonic wire microring resonator (PWRR) sensor and compare our results with the previous work. Simulation results show that the resonant wavelength and sensitivity strongly depend on the coupling strength. The difference caused by the coupling effect can be up to tens of nanometers for the resonant peak position and tens of nm/RIU for the sensitivity in a silicon-on-insulator (SOI) PWRR. Such a giant influence from coupling effect cannot be disregarded and should be considered seriously for the design and application of PWRRs. It also shows an alternative tuning technique by controlling the coupling strength. 相似文献
100.
Synergetic catalytic effect of rGO,Pd, Fe3O4 and PPy as a magnetically separable and recyclable nanocomposite for coupling reactions in green media 下载免费PDF全文
In this paper, rGO/Pd–Fe3O4@PPy as an efficient stable nanocomposite was synthesized. To understand the synergetic effects of rGO, Pd, Fe3O4 and PolyPyrrole, the performance of rGO/Pd–Fe3O4@PPy as a heterogeneous recyclable nanocatalyst in the green synthesis of C‐C and C‐O coupling products, as well as different conditions are studied. Synthesized rGO/Pd–Fe3O4@PPy was characterized by FT‐IR, XRD, FE‐SEM, EDS, TGA and AFM analysis. Best results are obtained under sonication in H2O for C‐C coupling and by ball‐milling for C‐O coupling. The benefits of this method include: green solvents and conditions, absence of external base, low reaction times with high yield and easy work‐up method. 相似文献