中英化学教材中“化合价—氧化态”表述方法及思考

《化学故事情节AS》是英国索尔特高级化学课程的教材之一, 将该教材中有关"氧化态"这一概念的表述与我国中学化学教材中"化合价" 的表述进行比较, 从知识概念学习的一致性角度论述了我国中学化学教材中使用"氧化态"代替"化合价"的合理性及其优点, 建议我国中学化学教材编写时进行调整。     

溶胶-凝胶法制备ZnO薄膜及其微结构特性研究

采用溶胶-凝胶法(Sol-Gel)制备氧化锌(ZnO)薄膜,研究镀膜层数和退火温度对ZnO薄膜晶体结构、光谱性质及表面形貌的影响.X射线衍射谱测试表明,退火温度为600℃、镀膜层数为10层时制备样品的晶粒尺寸最大,结晶度最好.紫外-可见透过谱发现,样品退火后其透过率曲线变得陡直,光学带隙随退火温度升高而逐渐减小.光致发光谱测试显示,ZnO薄膜的发光谱包含388 nm和394 nm附近的两个主要发光峰,分别对应于本征发射和缺陷发射,其强度随退火温度升高呈现相反的变化.原子力显微照片则显示了随退火温度的升高制备样品表面晶粒的分布趋于均匀而致密.     

磁场微重力效应的研究

将导电的液体置于磁场中,使导电液体中浮力驱动的自然对流减弱甚至消失,在导电液体中制造出了二级微重力效应,将这种情况称为磁场微重力效应.通过研究导电液体自然对流驱动力的无量纲Grashof数的变化,发现微重力效应的水平可以用公式g_m＝（β₀/β_m）（ν₀ /ν_m）²g₀ 计算,如果略去一次项,则可用g_m＝（ν₀ /ν_m）²g₀来估算.测量研究了不同磁场条件下硅熔体的磁黏度,估算不同磁场强度对应的磁场微重力水平后,发现估算结果与实验结果基本符合. 关键词： 磁场 二级微重力效应 Grashof数 微重力水平     

Fractal dimension of scattering equivalent section of aerosol and its calibration mechanism

The correct calibration of coefficients in the inversion model for aerosol mass concentration is the precondition of obtaining highly precise results. The concept of the fractal dimension of scattering equivalent section is presented, and the calibration mechanism of the fractal dimension is discussed. Based on the calibration mechanism, the stability of the fractal dimension is analyzed. Theoretical analysis and experimental results indicate that the fractal dimension obtained by the intersection point calibration method is stable, while that calibrated by the Gauss-Newton method is instable, which only describes the shape characteristic of a small sample. The study of the calibration mechanism for the fractal dimension markedly enhances the present model for aerosol mass concentration.     

Mei conserved quantity of Nielsen equation for anon-Chetaev-type non-holonomic system

<正>The Mei symmetry and Mei conserved quantity of the Nielsen equation for a non-Chetaev-type non-holonomic non-conservative system are studied.The differential equations of motion of the Nielsen equation for the system,the definition and the criterion of Mei symmetry and the condition and the form of Mei conserved quantities deduced directly from the Mei symmetry for the system are obtained.Finally,an example is given to illustrate the application of the results.     

幂幺矩阵的充要条件

研究幂幺矩阵的充要条件,利用矩阵的秩和齐次线性方程组解空间的维数.将m=2时幂幺矩阵的充要条件推广到一般幂幺矩阵的充要条件,得出了幂幺矩阵可对角化的结果,并将幂幺矩阵的充要条件平行地推广到幂幺线性变换.     

二维可压缩流体Kelvin-Helmholtz不稳定性

利用高精度数值格式,研究了二维可压缩流体中的Kelvin-Helmholtz不稳定性,主要研究了可压缩性对Kelvin-Helmholtz稳定性增长率的影响.模拟定量的给出低Mach和高Mach数两种情况下,初始静压和对流Mach数以及Kelvin-Helmholtz不稳定性线性增长率的关系.模拟结果和自由剪切层以及混合层的实验结果以及理论分析一致.模拟表明,对流Mach数是描述流体可压缩性的合适参数,对流Mach数越小流体越不可压,Kelvin-Helmholtz不稳定性的线性增长率随对流Mach数的增加而减小. 关键词： Kelvin-Helmholtz不稳定性 可压缩流体 Mach数 超音速流体     

InGaN/GaN laser diode characterization and quantum well number effect

The effect of quantum well number on the quantum efficiency and temperature characteristics of In- GaN/GaN laser diodes （LDs） is determined and investigated. The 3-nm-thick In0.13Ca0.87N wells and two 6-am-thick GaN barriers are selected as an active region for Fabry-Perot （FP） cavity waveguide edge emitting LD. The internal quantum efficiency and internal optical loss coefficient are extracted through the simulation software for single, double, and triple InGaN/GaN quantum wells. The effects of device temperature on the laser threshold current, external differential quantum efficiency （DQE）, and output wavelength are also investigated. The external quantum efficiency and characteristic temperature are improved significantly when the quantum well number is two. It is indicated that the laser structures with many quantum wells will suffer from the inhomogeneity of the carrier density within the quantum well itself which affects the LD performance.     

金纳米薄膜导电和导热性质的实验研究

由于尺寸效应和晶界效应的影响,纳米薄膜在导电和导热方面呈现出与体材料不同的性质.本文实验研究了不同厚度(20～54 nm)金薄膜在不同温度(100～340 K)的导电、导热性质.测量结果显示,薄膜的电导率和热导率比体材料小,洛伦兹数比体材料大,Wiedemann-Franz定律不再成立.随着厚度增加,薄膜的电导率,热导率和电阻温度系数都增加.薄膜热导率随温度变化趋势与体材料相反,随着温度升高而升高.电导率随温度变化趋势与体材料相同,随着温度升高而降低;但薄膜没有体材料对温度变化敏感,导致电阻温度系数下降.     

60位的回归数

60位的回归数并不存在,从而将回归数的位数n≤60改进为n≤59。