热重分析技术及其在高分子表征中的应用

热重分析技术(TGA)是在程序控制温度和设定气氛下表征材料受热过程中的质量随温度或时间变化的高精度研究工具,具有重复性好、灵敏度高和热过程控制精准等优点.近年来,TGA技术在高分子材料领域得到了广泛应用,促进了高分子材料热稳定性、组成分析以及热分解机理等材料细观热响应特性的深入研究.本文分别从热重分析基本原理、仪器校准...     

两性霉素B与鞘磷脂单分子层的相互作用

选取哺乳动物生物膜中的重要脂质分子鞘磷脂(SM)作为单分子膜的基本组分, 采用Langmuir-Blodgett(LB)膜技术研究了不同比例的两性霉素B/鞘磷脂单层膜的表面压力-平均分子面积(π-A)曲线以及基于π-A曲线的混合性分析, 同时通过原子力显微镜(AFM)研究了其表面形态的变化. 结果表明, 组分间的摩尔比和表面压力对混合单层膜稳定性、混合性以及分子间相互作用具有重要影响.     

含磷有机硅杂化环氧树脂固化体系性能研究

通过磷酸与γ-环氧丙氧基三甲氧基硅烷反应得到含磷有机硅氧烷,并加入到环氧树脂/4,4'-二氨基二苯基甲烷体系中混合,通过溶胶-凝胶的方法制备了含磷有机硅杂化环氧树脂固化物.对固化体系进行了玻璃化转变温度、热失重、阻燃、拉伸强度、冲击强度测试分析.结果表明,该固化体系的阻燃性得到提高,极限氧指数在25.8～29.3,玻璃化转变温度得到提高,在161～179℃;虽然初始分解温度比纯环氧树脂固化物低,但800℃残炭率可以达到26.5%,提高了36%;拉伸强度得到提高,在71～94 MPa,冲击强度可以达到14.36 kJ/m2,提高了14%.该固化体系具有较好的阻燃性能和热性能,同时具有较好的力学性能.     

SYNTHESIS, CHARACTERIZATION AND PROPERTIES OF ORGANOCLAY-MODIFIED POLYSULFONE/EPOXY INTERPENETRATING POLYMER NETWORK NANOCOMPOSITES

Organoclay-modified hydroxylterminated polysulfone (PSF)/epoxy interpenetrating network nanocomposites (oM-PSF/EP nanocomposites) were prepared by adding organophilic montmorillonite (oMMT) to interpenetrating polymer networks (IPNs) of polysulfone and epoxy resin (PSF/EP) using diaminodiphenylmethane (DDM) as curing agent.The mechanical properties like tensile strength,tensile modulus,flexural strength,flexural modulus and impact properties of the nanocomposites were studied as per ASTM standards.Differ...     

基于小波神经网络的中国能源需求预测模型

通过分析影响我国能源需求的主要因素,建立了基于小波神经网络的需求预测模型.采用定性与定量相结合的方式,分析了影响我国能源需求的主要因素,通过将人口总数、GDP、产业结构变化以及能源消费量的一阶滞后作为输入变量,建立基于小波神经网络的我国能源需求非线性预测模型.实验结果表明,该非线性预测模型与多元回归模型相比更加合理,具有更高的预测精度.     

Identification and Characterization of 4-Hydroxy-2H-1,2-benzothiazine-3-carboxylic Acid 1,1-Dioxide Derivatives by Mass Spectroscopy

Electron impact mass spectral fragmentation of certain esters and amides derived from 4-hydroxy-2H-1,2-benzothiazine-3-carboxylic acid 1,1-dioxide is described. Common ions to both series may be observed, as well as others allowing them to be differentiated. The method is promissory for identification and analysis of these compounds.     

内积在溶液浓度测定中的应用

提出内积的溶液浓度测定方法。该方法计算已知浓度溶液透光率曲线与0号溶液（浓度最低的溶液）透光率曲线的内积ρ,确定溶液的ρ-C曲线,然后测定未知溶液的透光率曲线,计算其与0号溶液透光率曲线的内积,并利用已建立好的ρ-C曲线进行插值以估计溶液浓度。由于该方法利用了透光率曲线的全部信息,因此对溶液浓度的估计精度较高。对K2Cr2O7溶液浓度的测定实验结果表明,该方法对溶液浓度的估计相对误差小于1.00%。     

Off-center impact of an elastic column by a rigid mass

Based on the Timoshenko beam model the equations of motion are obtained for large deflection of off-center impact of a column by a rigid mass via Hamilton's principle. These are a set of coupled nonlinear partial differential equations. The Newmark time integration scheme and differential quadrature method are employed to convert the equations into a set of nonlinear algebraic equations for displacement components. The equations are solved numerically and the effects of weight and velocity of the rigid mass and also off-center distance on deformation of the column are studied.