硝酸酯热分解的机理分析

使用加速量热仪研究硝酸正丙酯（NPN）、硝酸异丙酯（IPN）和硝酸异辛酯（EHN）的热分解过程。分析了在绝热条件下热分解反应动力学, 根据实验数据计算出表观活化能、指前因子和反应热等参数。根据NPN、IPN和EHN热分解的起始温度和反应热数据,给出了三种硝酸酯在75℃时的反应风险指数,分析得到三种物质的热失稳风险度。分别在B3LYP/6-31+G(2df,2p)和B3P86/6-31+G(2df,2p)的理论水平下,计算得到NPN、IPN和EHN的O-NO2键离解能(BDE)。由NPN、IPN和EHN的O-NO2键离解能在很大程度上符合由加速量热仪测试得到的活化能,推知三种硝酸酯的热分解反应只是单分子O-NO2键的均裂反应。     

Ti(SO_4)_2水解-水热法制备锐钛型纳米TiO_2及其光催化性能

以Ti(SO4)2水溶液为原料,在水热条件下直接水解合成了锐钛型纳米TiO2颗粒。利用透射电镜(TEM)、X射线衍射(XRD)、BET低温吸附和紫外-可见光谱(UV-Vis)等方法对产物进行了表征,并研究了样品光催化降解甲基橙(MO)的性能。结果表明所制得纳米TiO2颗粒为锐钛矿型,晶型良好,平均粒径为24 nm,BET比表面积约为56.20 m2.g-1。光催化活性与商品纳米TiO2(P25)相近,具有良好的工业应用前景。     

Variational iteration method for solving compressible Euler equations

This paper applies the variational iteration method to obtain approximate analytic solutions of compressible Euler equations in gas dynamics.This method is based on the use of Lagrange multiplier for identification of optimal values of parameters in a functional.Using this method,a rapid convergent sequence is produced which converges to the exact solutions of the problem.Numerical results and comparison with other two numerical solutions verify that this method is very convenient and efficient.     

LAMOST光纤单元定位参数研究

大天区多目标光纤光谱天文望远镜LAMOST是世界上光谱获取量最大的望远镜,4000个双回转光纤单元的精确定位是关键因素之一。根据对星像观测的要求以及单元的定位方式,确立了所需的7个定位参数,研究了在复杂现场环境下获取定位参数的具体流程和可行性算法,包括光重心法、摄像机快速标定算法、基于最小二乘拟合圆算法、空间坐标旋转算法等。通过模拟星像观测仿真测试和现场星像试观测证明,定位参数精度能很好地满足观测需求。目前LAMOST望远镜观测光谱获取率已达到90%以上。     

基于有限元法确立碳化钨顶锤的破裂判据

以有限元法为理论基础,通过运行大型有限元软件,成功构建了铰链式六面顶压机配套顶锤的有限元理论模型,并确立了碳化钨顶锤的破裂判据。模拟结果表明:以小斜边末尾处为应力参考点,依据第四强度理论,能够对碳化钨顶锤的性能进行更加合理的数值分析。依据此判据可知:在顶锤锤面及小斜边附近,裂纹高发区分布在小斜边附近;在顶锤轴向上,裂纹高发区分布在距离顶锤锤面30 mm处。铰链式六面顶压机配套碳化钨顶锤的有限元模型以及碳化钨顶锤破裂判据的成功构建,为实现新型碳化钨顶锤的设计与研究奠定了基础,对促进实现铰链式六面顶压机腔体大型化具有现实意义。     

Nonlinear flutter analysis of stiffened composite panels in super-sonic flow

The flutter instability of stiffened composite panels subjected to aerodynamic forces in the supersonic flow is investigated. Based on Hamilton's principle,the aeroelastic model of the composite panel is established by using the von Karman large deflection plate theory,piston theory aerodynamics and the quasi-steady thermal stress theory. Then,using the finite element method along with Bogner-Fox-Schmit elements and three-dimensional beam elements,the nonlinear equations of motion are derived. The effect of...     

利用积分方程法的各向异性地层频率测深三维模拟

应用一种新的积分方程算法对各向异性地层频率域电磁测深三维问题进行正演模拟.利用范数小于或等于1的修正Green算子得到各向异性地层中的新积分方程,由于满足压缩映射条件,该积分方程在任意参数条件下总是迭代收敛的.提出一种应用迭代法求解新积分方程的迭代初值优化选择方法,并通过具体算例对比说明该方法可使频率域电磁测深三维模拟的计算效率得到有效提高.最后应用所述算法对层状各向异性大地轴向频率测深视电阻率响应进行三维数值模拟,考察分析地层的各向异性对视电阻率响应特征的影响,得到一些重要结论.     

Symmetry reduction and exact solutions of the (3+1)-dimensional Zakharovben Kuznetsov equation

By means of the classical method, we investigate the (3+1)-dimensional Zakharov-Kuznetsov equation. The symmetry group of the (3+1)-dimensional Zakharov-Kuznetsov equation is studied first and the theorem of group invariant solutions is constructed. Then using the associated vector fields of the obtained symmetry, we give the one-, two-, and three-parameter optimal systems of group-invariant solutions. Based on the optimal system, we derive the reductions and some new solutions of the (3+1)-dimensional Zakharov-Kuznetsov equation.     

广义Birkhoff方程的积分方法

场方法和最终乘子法是求解运动微分方程的基本方法.本文将这两种方法应用于广义Birkhoff系统,求出了场方法的基本偏微分方程和该方程的完全积分;根据Jacobi最终乘子定理求出了广义Birkhoff方程的解.并举例说明结果的应用.     

Particle-number-conserving analysis of multiquasiparticle bands in ~(177)Lu

The experimental one-, three-, and five-quasiparticle bands in ~(177)Lu are analyzed by the particle-number conserving (PNC) method for treating the cranked shell model with pairing interaction, in which the blocking effects are taken into account exactly. The experimental moments of inertia are reproduced very well by PNC calculations with us free parameter.