首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   3581篇
  免费   149篇
  国内免费   141篇
化学   840篇
晶体学   3篇
力学   473篇
综合类   17篇
数学   1522篇
物理学   1016篇
  2024年   6篇
  2023年   63篇
  2022年   64篇
  2021年   56篇
  2020年   59篇
  2019年   73篇
  2018年   66篇
  2017年   88篇
  2016年   94篇
  2015年   97篇
  2014年   213篇
  2013年   255篇
  2012年   150篇
  2011年   219篇
  2010年   192篇
  2009年   234篇
  2008年   242篇
  2007年   237篇
  2006年   183篇
  2005年   149篇
  2004年   132篇
  2003年   114篇
  2002年   86篇
  2001年   68篇
  2000年   92篇
  1999年   83篇
  1998年   67篇
  1997年   67篇
  1996年   66篇
  1995年   42篇
  1994年   39篇
  1993年   37篇
  1992年   30篇
  1991年   26篇
  1990年   17篇
  1989年   21篇
  1988年   21篇
  1987年   14篇
  1986年   9篇
  1985年   12篇
  1984年   13篇
  1983年   9篇
  1982年   8篇
  1981年   13篇
  1980年   12篇
  1979年   9篇
  1978年   6篇
  1977年   8篇
  1976年   4篇
  1957年   2篇
排序方式: 共有3871条查询结果,搜索用时 15 毫秒
91.
《随机分析与应用》2013,31(5):1209-1233
Abstract

In the paper we compute the explicit form of the fractional chaos decomposition of the solution of a fractional stochastic bilinear equation with the drift in the fractional chaos of order one and initial condition in a finite fractional chaos. The large deviations principle is also obtained for the one-dimensional distributions of the solution of the equation perturbed by a small noise.  相似文献   
92.
Two novel triorganotin carboxylate complexes of the biologically active urocanic acid have been synthesized and characterized. Elemental analysis, melting point, spectroscopic techniques – IR, 1H, 13C and 119Sn NMR – mass spectrometry and X‐ray diffraction studies have been used for structural characterization. Crystal structures of the tin(IV) derivatives show that urocanic acid acts as a bridging bidentate ligand through its imidazole nitrogen atom and its carboxylic group, producing a polymeric one‐dimensional chain. The molecular structures of the complexes, catena‐poly‐tri(n‐butyl)tin(IV) 3‐(3H‐imidazol‐4‐yl)prop‐2‐enoate (1) and catena‐poly‐triphenyltin(IV) 3‐(3H‐imidazol‐4‐yl)prop‐2‐enoate (2), present a distorted trigonal–bipyramidal configuration. This is further confirmed by 119Sn NMR in the solid state. The tin(IV) derivatives form double‐stranded ribbons via N―HO―H bonds. Nevertheless, the compounds are essentially monomeric in solution, with a tetrahedral configuration as observed by 119Sn NMR in solution. The cytotoxic activity of the titled compounds has been tested against six human cell lines and the corresponding IC50 values are reported. Both tin(IV) compounds have a high to very high in vitro cytotoxic activity against the tumor cell lines K562, HCT‐15 and MCF‐7. Compound 1 is 86 times more active than cisplatin in the HTC‐15 cell line. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   
93.
A new diamine monomer containing rigid planar fluorenone moiety, 2,7‐bis(4‐aminophenyl)‐9H‐fluoren‐9‐one, was synthesized through Suzuki coupling reaction. Then it was reacted with pyromellitic dianhydride to obtain a polyimide (FOPPI) via a conventional two‐step polymerization process. The prepared FOPPI exhibits excellent barrier properties, with the oxygen transmission rate and water vapor transmission rate low to 3.2 cm3·m?2·day?1 and 2.9 g·m?2·day?1, respectively. The results of wide angle X‐ray diffractograms, positron annihilation lifetime spectroscopy, and molecular dynamics simulations reveal that the excellent barrier properties of FOPPI are mainly ascribed to the crystallinity, high chain rigidity, and low free volume, which are resulted from the rigid planar moiety. FOPPI also shows outstanding thermal stability and mechanical properties with a glass transition temperature up to 420 °C, 5% loss temperature of 607 °C, coefficient of thermal expansion of 1.28 ppm K?1, and tensile strength of 150.8 MPa. The polyimide has an attractive potential application prospect in the flexible electronics encapsulation area. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2017 , 55 , 2373–2382  相似文献   
94.
The paper describes a parameterisation procedure for multiple nonlinear equations with intercepts. These equations may consist of numerous members with few practical limitations on their structure. Examples are given on the application of the procedure to simulation in the areas of chemical technology and hydrology. Advantages of the proposed method are simplicity of the fitting procedure, high accuracy of simulations and more reliable simulations beyond the calibration range  相似文献   
95.
We introduce a new distance measure between two preorders that captures indifference, strict preference, weak preference and incomparability relations. This measure is the first to capture weak preference relations. We illustrate how this distance measure affords decision makers greater modeling power to capture their preferences, or uncertainty and ambiguity around them, by using our proposed distance measure in a multiple criteria aggregation procedure for mixed evaluations.  相似文献   
96.
We study the similarities between the Fano varieties of lines on a cubic fourfold, a hyper-Kähler fourfold studied by Beauville and Donagi, and the hyper-Kähler fourfold constructed by Debarre and Voisin in [3]. We exhibit an analog of the notion of “triangle” for these varieties and prove that the 6-dimensional variety of “triangles” is a Lagrangian subvariety in the cube of the constructed hyper-Kähler fourfold.  相似文献   
97.
Barlow and Gupta (1969) and Alam (1970) studied the monotonicity of two integrals, involving gamma distributions, that arise in certain ranking and selection problems. In this paper, we shall unify their results by studying the monotonicity of two generalized versions of integrals considered by them. We will also provide applications of derived results in study of certain multiple comparison procedures.  相似文献   
98.
99.
This article proposes a global, chaos-based procedure for the discretization of functionals of Brownian motion into functionals of a Poisson process with intensity λ>0. Under this discretization we study the weak convergence, as the intensity of the underlying Poisson process goes to infinity, of Poisson functionals and their corresponding Malliavin-type derivatives to their Wiener counterparts. In addition, we derive a convergence rate of O(λ?14) for the Poisson discretization of Wiener functionals by combining the multivariate Chen–Stein method with the Malliavin calculus. Our proposed sufficient condition for establishing the mentioned convergence rate involves the kernel functions in the Wiener chaos, yet we provide examples, especially the discretization of some common path dependent Wiener functionals, to which our results apply without committing the explicit computations of such kernels. To the best our knowledge, these are the first results in the literature on the universal convergence rate of a global discretization of general Wiener functionals.  相似文献   
100.
A novel method is proposed for calculating the natural frequencies of a multiple cracked beam and detecting unknown number of multiple cracks from the measured natural frequencies. First, an explicit expression of the natural frequencies through crack parameters is derived as a modification of the Rayleigh quotient for the multiple cracked beams that differ from the earlier ones by including nonlinear terms with respect to crack severity. This expression provides a simple tool for calculating the natural frequencies of the beam with arbitrary number of cracks instead of solving the complicated characteristic equation. The obtained nonlinear expression for natural frequencies in combination with the so-called crack scanning method proposed recently by the authors allowed the development of a novel procedure for consistent identification of unknown amount of cracks in the beam with a limited number of measured natural frequencies. The developed theory has been illustrated and validated by both numerical and experimental results.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号