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11.
Dmitry S. Zimnitsky Tatiana L. Yurkshtovich Pavel M. Bychkovsky 《Journal of polymer science. Part A, Polymer chemistry》2004,42(19):4785-4791
Samples of oxidized cellulose (OC) with various carboxyl contents and degrees of crystallinity were obtained by the oxidation of native and mercerized cellulose with a solution of nitrogen(IV) oxide in CCl4. A detailed characterization of these OC samples was performed. The effect of oxidation conditions (concentration of N2O4 in the solution and oxidation time) and starting cellulose material on OC characteristics (carboxyl, carbonyl and nitrogen content, degree of crystallinity and polymerization, surface area and swelling, and acidic properties) was investigated. Reactivity in the oxidation process was higher in mercerized cellulose than in native cellulose. The action of dilute solutions (10–15%) of N2O4 did not affect the degree of crystallinity of cellulose samples. Under these conditions, the oxidation took place mainly in amorphous regions and on the surface of crystallites. Oxidation in a concentrated (40%) N2O4 solution led to the destruction of crystallites, which increased the surface area and swelling of cellulose in water. The surface area and the swelling of OC samples increased with a decrease in the index of crystallinity. The acidic properties of OC were shown to increase with an increase of swelling in water. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 4785–4791, 2004 相似文献
12.
An analytic and numerical study of the behavior of the linear nonhomogeneous wave equation of the form ε2utt = Δu + tf with high wave speed (ε 1) is carried out. This study was initially motivated by meteorological observations which have indicated the presence of large spatial scale gravity waves in the neighborhood of a number of summer and winter storms, mainly from visible images of ripples in clouds in satellite photos. There is a question as to whether the presence of these waves is caused by the nearby storms. Since the linear wave equation is an approximation to the full system describing pressure waves in the atmosphere, yet is considerably more tractable, we have chosen to analyze the behavior of the linear nonhomogeneous wave equation with high wave speed. The analysis is shown to be valid in one, two, and three space dimensions. Partly because of the high wave speed, the solution is known to consist of behavior which changes on two different time scales, one rapid and one slow. Additionally, because of the presence of the nonhomogeneous forcing term tf, we show that there is a component of the solution which will vary only on a very large spatial scale. Since even the linearized wave equation can give rise to persistent large spatial scale waves under the right conditions, the implication is that certain storms could be responsible for the generation of large-scale waves. Numerical simulations in one and two dimensions confirm analytic results. 相似文献
13.
本文以fp 同伦方法为工具,借助于一些适当的变换,研究有序的(B)空间中的集值映象方程的多正解问题;在文中的有关工作中,还使用了集值映象的拟导数的某些性质. 相似文献
14.
Augustine O. Esogbue Qiang Song Donovan Young 《Mathematical Methods of Operations Research》2006,63(3):525-542
In this paper the problem of verifying the Pareto-optimality of a given solution to a dynamic multiple-criterion decision (DMCD) problem is investigated. For this purpose, some new conditions are derived for Pareto-optimality of DMCD problems. In the literature, Pareto-optimality is characterized by means of Euler-Lagrangian differential equations. There exist problems in production and inventory control to which these conditions cannot be applied directly (Song 1997). Thus, it is necessary to explore new conditions for Pareto-optimality of DMCD problems. With some mild assumptions on the objective functionals, we develop necessary and/or sufficient conditions for Pareto-optimality in the sprit of optimization theory. Both linear and non-linear cases are considered. 相似文献
15.
A nanoscale
multivalent platinum drug based on a poly(amidoamine) [PAMAM] dendrimer (generation
4.5, carboxylate surface) has been synthesized and fully characterized using
a variety of spectroscopic, chromatographic and thermal methods. Treatment
of the dendrimer with an aqueous solution containing an excess diaquo(cis-1,2-diaminocyclohexane)platinum(II) produces
a conjugate containing approximately forty (diaminocyclohexane)platinum(II)
moieties at the surface of the dendrimer. This material undergoes smooth two-stage
thermal decomposition to provide residual platinum oxide reflecting the platinum
loading in the drug. 相似文献
16.
具有时滞的非自治的捕食-食饵系统的全局吸引 总被引:1,自引:0,他引:1
考虑一个具有离散时滞的非自治的捕食—食饵系统。系统是由3种群组成的,其中一个为捕食者,另两个为食饵种群。本文的目的是给出时滞对系统的持续生存是无害的,从而确定了系统的周期解全局吸引的条件。 相似文献
17.
Xian Xu 《Journal of Mathematical Analysis and Applications》2004,291(2):673-689
In this paper, some multiplicity results for positive solutions of some singular semi-positone three-point boundary value problem be obtained by using the fixed point index method. 相似文献
18.
Bounds are given on the size of the parameter-space decomposition induced by multiple sequence alignment problems where phylogenetic information may be given or inferred. It is shown that many of the usual formulations of these problems fall within the same integer parametric framework, implying that the number of distinct optima obtained as the parameters are varied across their ranges is polynomially bounded in the length and number of sequences. 相似文献
19.
20.
GLOBAL EXISTENCE FOR A CLASS OF SYSTEMSOF NONLINEAR WAVE EQUATIONS INTHREE SPACE DIMENSIONS
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S. KATAYAMA 《数学年刊B辑(英文版)》2004,25(4):463-482
Consider a system of nonlinear wave equationsfor i = 1, … , m, where F, (i = 1, … , m) are smooth functions of degree 2 near the origin of their arguments, and u = (u1, … ,um), while u and x u represent the first and second derivatives of u, respectively. In this paper, the author presents a new class of nonlineaxity for which the global existence of small solutions is ensured. For example, global existence of small solutions for arbitrary cubic terms,arbitrary cubic termswill be established, provided that c12 ≠ c22. 相似文献