高次非球面的工艺技术研究

 高次非球面在光学系统应用中意义重大,但是一直以来缺乏一套快速、有效的工艺方法。利用VC6.0编制了一款面型计算软件以辅助加工,并提出了一种新的高次非球面补偿检验方法。针对一块巡天光谱仪中口径Φ244 mm的一面平面另一面为高次非球面的改正镜开展工艺方法的设计与研究,从铣磨成形开始,根据高次非球面的特点提出了几种新型磨削工艺,建立相应的数学模型。由于高次非球面的特殊性,试验了数控铣磨直接成型法,很大程度上降低后继工艺难度,在细磨和抛光阶段采用数控小工具和整工具研磨相结合,能够很好地克服面型不平滑等技术难题。总结出了一套高效率、低成本、高精度的高次非球面工艺方法。     

Study of domain structure and magnetization reversal after thermal treatments in Fe40Co38Mo4B18 microwires

We have studied the effect of thermal treatment on the magnetic domain structure and magnetic reversal process of amorphous and nanocrystalline Fe₄₀Co₃₈Mo₄B₁₈ microwires. The domain structure and the magnetization reversal of amorphous FeCoMoB microwires reflect the complex stress distribution introduced by the glass coating. Hence, the thickness of radial domain structure decreases with temperature and the temperature dependence of the switching field presents a discontinuous behavior. After nanocrystallization, the domain structure of FeCoMoB microwire is almost constant within the temperature range 10-400 K and the switching field decreases almost linearly with temperature mostly because of the decrease of saturation magnetization.     

广义特征坐标系计算膨胀波与激波优越性的数值验证

最近提出的以流体速度和声速的线性组合为速度而运动的广义特征坐标系,是-个更为-般的坐标系统,当参数取不同特殊值的时候,就可以得到其他经典的坐标系统.这种坐标系的最大特点是,它能跟随膨胀波(当然也可以跟随激波和接触间断)运动,从而在使用同-计算格式的前提下,使得膨胀波的计算精度更高.对膨胀波和激波进行数值试验,结果显示广义特征坐标系在计算膨胀波和激波时明显优于传统的坐标系.     

Thermodynamical Aspects of Modified Holographic Dark Energy Model

We investigate the unified first law and the generalized second law in a modified holographic dark energy model. The thermodynamical analysis on the apparent horizon can work and the corresponding entropy formula is extracted from the systematic algorithm. The entropy correction term depends on the extra-dimension number of the brane as expected, but the interplay between the correction term and the extra dimensions is more complicated. With the unified first law of thermodynamics well-founded, the generalized second law of thermodynamics is discussed and it is found that the second law can be violated in certain circumstances. Particularly, if the number of the extra dimensions is larger than one, the generalized law of thermodynamics is always satisfied; otherwise, the validity of the second law can only be guaranteed with the Hubble radius greatly smaller than the crossover scale r_c of the 5-dimensional DGP model.     

Phase and shape controlling of MnS nanocrystals in the solvothermal process

MnS nanocrystals with different phases and shapes were prepared through solvothermal synthesis. The products were characterized by X-ray diffraction (XRD), transmission electron microscope (TEM), UV–vis absorption and photoluminescence (PL) spectra. The solvent and reaction time played an important role in controlling the phase and shape of MnS nanocrystals. The possible mechanism of the shape evolution was investigated, which revealed that the crystal growth along the unique c axis of γ-MnS resulted in the rod-like MnS at the primary period, and the tetrahedral crystal seed of β-MnS with zincblende structure resulted in the interlinking of MnS rods, so the zigzag and three-branched and palm-like MnS appeared; with increasing reactive time the thermodynamically stable spherical α-MnS was favored through the Ostwald ripening process. The PL results showed that the intensity of γ-MnS was much weaker than that of α-MnS, and the trap state emissions of γ-MnS at 470 and 482 nm, respectively, disappeared, which might be ascribed to the difference of the shapes between the sphere and the rod or branch.     

石化废水处理过程中荧光有机物变化特征及去除效果

石化废水排放量大、污染物成分复杂,对环境的危害较大。采用三维荧光光谱扫描技术分析了某大型石化企业综合污水处理厂各处理单元(水解酸化+A/O+接触氧化工艺)进出水的荧光光谱特征。污水厂总进水包含四个荧光峰Peak A,Peak B,Peak D,Peak E,分别位于λex/λem=220/300,225/340,270/300,275/340nm附近,荧光物质主要来自工业废水,水解酸化池出水各荧光峰强度有所降低,位置基本不变,厌氧池出水λex/λem=250/425nm附近出现新荧光峰Peak C,好氧池出水荧光峰Peak C处荧光强度有所增强,二沉池出水Peak A消失,二沉池之后水样荧光谱图变化不大;该处理工艺对荧光有机物的总去除率为92.0%,Peak A,Peak B,Peak D,Peak E附近的荧光有机物去除率分别为100.0%,91.2%,80.3%,92.0%;污水厂进水IPeak B/IPeak E值波动较大而出水变化不大,表明该污水处理厂运行稳定,其处理工艺具有较强的抗冲击负荷能力。     

Spherical particle Brownian motion in viscous medium as non-Markovian random process

The Brownian motion of a spherical particle in an infinite medium is described by the conventional methods and integral transforms considering the entrainment of surrounding particles of the medium by the Brownian particle. It is demonstrated that fluctuations of the Brownian particle velocity represent a non-Markovian random process. The features of Brownian motion in short time intervals and in small displacements are considered.     

Emission spectra simulation of calcium plasmas in non-local thermodynamic equilibrium

We use previous high-quality experimental spectra to test the accuracy of atomic data and the validity of the collisional－radiative (CR) model used in this paper. The synthetic spectrum with electron temperature log T_e(K)=6.745 and electron density n_e=6.0×10^{13}cm^{-3}, which almost reproduces the experimental spectra, is presented. Nearly all the features of the experimental spectra were identified. The results of the CR modelling for the emission spectra of calcium plasmas all agree well with the measured spectral line intensities within the experimental error for most of the lines. Furthermore, we make the electron temperature diagnostic through the synthetic spectrum and population fractions of every ionization state as a function of charge state at different electron temperatures, as well as the electron density diagnostic through the intensity ratios of two lines of Be-like calcium and three lines of C-like calcium. A good agreement between the calculated values and the measured ones is found.     

Random Motions at Finite Speed in Higher Dimensions

We present a general method of studying the transport process , t≥0, in the Euclidean space ℝ ^m , m≥2, based on the analysis of the integral transforms of its distributions. We show that the joint characteristic functions of are connected with each other by a convolution-type recurrent relation. This enables us to prove that the characteristic function (Fourier transform) of in any dimension m≥2 satisfies a convolution-type Volterra integral equation of second kind. We give its solution and obtain the characteristic function of in terms of the multiple convolutions of the kernel of the equation with itself. An explicit form of the Laplace transform of the characteristic function in any dimension is given. The complete solution of the problem of finding the initial conditions for the governing partial differential equations, is given. We also show that, under the standard Kac condition on the speed of the motion and on the intensity of the switching Poisson process, the transition density of the isotropic transport process converges to the transition density of the m-dimensional homogeneous Brownian motion with zero drift and diffusion coefficient depending on the dimension m. We give the conditional characteristic functions of the isotropic transport process in terms of the inverse Laplace transform of the powers of the Gauss hypergeometric function. Some important models of the isotropic transport processes in lower dimensions are considered and some known results are derived as the particular cases of our general model by means of the method developed.     

Structural and optical properties of nanocrystalline ZnO thin films synthesized by the citrate precursor route

Nanocrystalline zinc oxide (ZnO) thin films have been deposited by spin-coating polymeric precursors synthesized by the citrate precursor route using ethylene glycol and citric acid as chelating agents. The ZnO thin films were annealed in air at different temperatures for 10 min. The films were characterized by different structural and optical techniques, including X-ray diffraction (XRD), atomic force microscopy (AFM), optical transmission spectroscopy, and photoluminescence (PL). The thermal decomposition of polymeric precursor was studied by thermogravimetric analysis (TGA). XRD analysis with grazing incidence and rocking curves indicate that the ZnO films are polycrystalline with preferential orientation along the c-axis direction with a full-width at half-maximum (FWHM) of 0.31° for 600 °C-annealed samples. On annealing, the texturing in films increased along with a decrease in FWHM. AFM micrographs illustrate that the ZnO films are crack-free with well-dispersed homogeneous and uniformly distributed spherical morphology. The synthesized ZnO thin films have transparency >85% in the visible region exhibiting band edge at 375 nm, which becomes sharper with anneal. Room temperature PL spectra of these films show strong ultraviolet (UV) emission around 392 nm with an increase in intensity with annealing temperature, attributed to grain growth. Deconvolution of the PL spectra reveals that there is coupling of free excitons with higher orders of longitudinal optical (LO) phonon replicas leading to a broad asymmetric near-band-edge peak.