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51.
We have studied the characteristic features of carbazole phosphorescence quenching by benzophenone in toluene at 77 K. We
have shown that the decrease in the relative phosphorescence intensity for carbazole (energy donor) by a greater factor than
we see for the relative change in its decay time is due to the fact that a change in the phosphorescence decay time occurs
only for carbazole molecules participating in triplet-triplet energy transfer, while the substantial decrease in the phosphorescence
intensity for carbazole with no change in the phosphorescence decay time is connected with quenching of its singlet states.
__________
Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 73, No. 4, pp. 554–556, July–August, 2006. 相似文献
53.
Sonya V. Roberson Albert J. Fahey Amit Sehgal Alamgir Karim 《Applied Surface Science》2002,200(1-4):150-164
We present a simple method for chemical modification of chlorosilane self-assembled monolayers (SAMs) on Si surfaces by exposure to a gradient of UV-ozone radiation to create stable substrates with a range of contact angles (θH2O≈5–95°) and surface energies on a single substrate. These gradient energy substrates are developed to potentially generate libraries for combinatorial studies of thin film phenomenology, where a systematic variation of interfacial surface energy represents one of the significant parameters along one axis. The graded oxidation process presents a systematic variation of surface chemical composition. We have utilized contact angle measurements and time-of-flight secondary ion mass spectrometry (ToF-SIMS) to investigate this variation for a series of ions, among which are SiCH3+, SiOH+ and COOH−. We show that the macroscopic measurements of surface free energy/contact angle correlate with the detailed analysis of surface chemistry (as assessed by ToF-SIMS) on these test substrates. 相似文献
54.
低温太阳热能与化学链燃烧相结合控制CO2分离动力系统 总被引:3,自引:1,他引:2
本文探索并提出控制CO2分离的低温太阳热能与清洁合成燃料甲醇-三氧化二铁化学链燃烧相结合的新颖能源动力系统。基于图象(?)分析方法,明确地指出甲醇化学链燃烧能量释放过程燃烧堋损失减小和低温太阳热能品位提升的机理。从能源有效利用和环境相容出发,研究和揭示化学链燃烧与太阳能有机整合共同减小CO2分离能耗的特性规律。相比不分离常规联合循环,新系统(?)效率提高约6.2个百分点;与分离CO2的联合循环相比,新系统媚效率提高约14.2个百分点。同时,低温太阳热能热转功效率可达到22.5%。 相似文献
55.
Hui-Ling Li De-Jiang Qi Qing-Quan Jiang Shu-Zheng Yang 《International Journal of Theoretical Physics》2006,45(12):2428-2436
An extension of the Parikh-Wilczek's semi-classical quantum tunneling method, the tunneling radiation of the charged particle from a torus-like black hole is investigated. Difference from the uncharged mass-less particle, the geodesics of the charged massive particle tunneling from the black hole is not light-like, but determined by the phase velocity. The derived result shows that the tunneling rate depends on the emitted particle's energy and electric charge, and takes the same functional form as uncharged particle. It proves also that the exact emission spectrum is not strictly pure thermal, but is consistent with the underlying unitary theory.
PACS Numbers: 04.70.Dy, 97.60.Lf, 05.30.Ch. 相似文献
56.
Chen-Cheng Sun Shih-Chin Lee Yaw-Shyan Fu Yu-Hwe Lee 《Applied Surface Science》2006,252(23):8295-8300
CrNx thin films have attracted much attention for semiconductor IC packaging molding dies and forming tools due to their excellent hardness, thermal stability and non-sticking properties (low surface free energy). However, few data has been published on the surface free energy (SFE) of CrNx films at temperatures in the range 20-170 °C. In this study CrNx thin films with CrN, Cr(N), Cr2N (and mixture of these phases) were prepared using closed field unbalanced magnetron sputtering at a wide range of Cr+2 emission intensity. The contact angles of water, di-iodomethane and ethylene glycol on the coated surfaces were measured at temperatures in the range 20-170 °C using a Dataphysics OCA-20 contact angle analyzer. The surface free energy of the CrNx films and their components (e.g., dispersion, polar) were calculated using the Owens-Wendt geometric mean approach. The influences of CrNx film surface roughness and microstructure on the surface free energy were investigated by atomic force microscopy (AFM) and X-ray diffraction (XRD), respectively. The experimental results showed that the lowest total SFE was obtained corresponding to CrN at temperature in 20 °C. This is lower than that of Cr(N), Cr2N (and mixture of these phases). The total SFE, dispersive SFE and polar SFE of CrNx films decreased with increasing surface temperature. The film roughness has an obvious effect on the SFE and there is tendency for the SFE to increase with increasing film surface roughness. 相似文献
57.
David E. Griffiths 《应用有机金属化学》1994,8(2):149-161
Dibutyltin-3-hydroxyflavone, Bu2Sn(of), is a new fluorescence probe inhibitor of F1F0-ATPase and oxidative phosphorylation which inhibits by titration of an unidentified component of F0. Its site of action is closely related to that of the trialkyltins and of venturicidin. This F0 component is part of a pool of this component which is present in the heart mitochondrial inner membrane at levels of 5–7 nmol (mg protein)?1 [18 ± 3 Bu2Sn(of) sites per mol F1F0-ATPase]. However, ATPase activity in submitochondrial particles is near maximally inhibited by titration of approx. three Bu2Sn(of) sites per mol F1F0-ATPase. Over 60% (60–80%) of the Bu2Sn(of) interaction sites can be lost during the purification of F1F0-ATPase from submitochondrial particles. The number of Bu2Sn(of) interaction sites in various F1F0-ATPase preparations is variable. The high numbers of Bu2Sn(of) sites per mol F1F0-ATPase for heart mitochondria (18–21) and submitochondrial particles (15–19.5) decline in ATP synthase (11–15) to the low values obtained in Complex V (7–10.5) and the minimal values observed in highly purified F1F0?ATPase (3.5–5.6), thus indicating a variable dissociable component or cofactor of ATP synthase. The Bu2Sn(of) interaction site, a component of ATP synthase, is responsive to the redox status of the respiratory chain and the interaction with Bu2Sn(of) is with the reduced form of this component. Fluorescence titration studies show that this component is in redox equilibrium with the ubiquinone pool of the respiratory chain. It is proposed that this redox component serves as an inhibitor titratable cofactor pool which cycles through an F0 interaction site (or sites) via a system which serves as an energy-transfer link between the respiratory chain and ATP synthase. 相似文献
58.
For classical solutions of the incompressible Navier-Stokes equations (NSE) the energybalance between kinetic energy, work done by external forces, and viscous dissipation holds rigorously true. It is shown in this paper that standard Galerkin approximations violate energy balance in the case of plane Couette flow, whereas Poiseuille flow turns out to be energy consistent at any cutoff. The main reason for this discrepancy is seen in the different boundary conditions between the stationary linear shear flow and its disturbances. In our analysis, essentially, we introduce an auxiliary external force field which enforces the finite dimensional Galerkin approximation to fulfil the NSE. It is exemplarily demonstrated how the energy discrepancy decreases when the number of disturbed modes is increased which couple to the stationary shear flow. 相似文献
59.
Gamma ray bursts (GRBs) have been proposed as one possible class of sources of the ultrahigh energy cosmic ray (UHECR) events
observed up to energies ≳ 1020 eV. The synchrotron radiation of the highest energy protons accelerated within the GRB source should produce gamma rays up
to TeV energies. Here we briefly discuss the implications on the energetics of the GRB from the point of view of the detectability
of the prompt TeV γ-rays of proton-synchrotron origin in GRBs in the up-coming ICECUBE muon detector in the south pole. 相似文献
60.