全文获取类型
收费全文 | 6671篇 |
免费 | 610篇 |
国内免费 | 430篇 |
专业分类
化学 | 491篇 |
晶体学 | 17篇 |
力学 | 142篇 |
综合类 | 146篇 |
数学 | 6206篇 |
物理学 | 709篇 |
出版年
2024年 | 31篇 |
2023年 | 120篇 |
2022年 | 200篇 |
2021年 | 161篇 |
2020年 | 229篇 |
2019年 | 262篇 |
2018年 | 253篇 |
2017年 | 239篇 |
2016年 | 158篇 |
2015年 | 136篇 |
2014年 | 240篇 |
2013年 | 615篇 |
2012年 | 261篇 |
2011年 | 371篇 |
2010年 | 378篇 |
2009年 | 545篇 |
2008年 | 495篇 |
2007年 | 374篇 |
2006年 | 387篇 |
2005年 | 294篇 |
2004年 | 252篇 |
2003年 | 244篇 |
2002年 | 210篇 |
2001年 | 186篇 |
2000年 | 178篇 |
1999年 | 180篇 |
1998年 | 160篇 |
1997年 | 115篇 |
1996年 | 64篇 |
1995年 | 68篇 |
1994年 | 57篇 |
1993年 | 42篇 |
1992年 | 36篇 |
1991年 | 25篇 |
1990年 | 17篇 |
1989年 | 19篇 |
1988年 | 17篇 |
1987年 | 11篇 |
1986年 | 9篇 |
1985年 | 18篇 |
1984年 | 15篇 |
1983年 | 3篇 |
1982年 | 13篇 |
1981年 | 7篇 |
1980年 | 4篇 |
1977年 | 2篇 |
1976年 | 2篇 |
1975年 | 4篇 |
1974年 | 2篇 |
1973年 | 1篇 |
排序方式: 共有7711条查询结果,搜索用时 31 毫秒
151.
152.
R. B. King 《Russian Chemical Bulletin》1993,42(8):1283-1291
Methods derived from topology and graph theory indicate that the deltahedral boranes B
n
H
n
2– and the corresponding carboranes C2Bn–2H
n
(6 n 12) may be regarded as three-dimensional delocalized aromatic systems in which surface bonding and core bonding correspond to -bonding and -bonding, respectively, in planar polygonal two-dimensional hydrocarbons CinnH
n
(n–6)+ (n=5/7). The two extreme types of topologies which may be used to model core bonding in deltahedral boranes and carboranes are the deltahedral (D
n
) topology based on the skeleton of the underlying deltahedron and the complete (K
n
) topology based on the corresponding complete graph. Analyses of the Hoffmann-Lipscomb LCAO extended Hückel computations, the Armstrong—Perkins—Stewart self-consistent molecular orbital computations, and SCF MOab initio GAUSSIAN-82 computations on B6H6
2– indicate that the approximation of the atomic orbitals by the sum of the molecular orbitals, as is typical in modernab initio computations, leads to significantly weaker apparent core bonding approximated more closely by deltahedral (D
n
) topology than by complete (K
n
) topology.This work was presented at the Workshop The Modern Problems of Heteroorganic Chemistry sponsored by the A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences (May 8–13, 1993).Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1353–1360, August, 1993. 相似文献
153.
154.
Rui M. Almeida Ana C. Marques Maurizio Ferrari 《Journal of Sol-Gel Science and Technology》2003,26(1-3):891-896
The present paper is focused on multilayer Er3+-doped silica-titania planar waveguides, co-doped with silver, which were prepared by spin-coating on silica glass, or buffered single crystal silicon substrates. The single layer thickness (0.4 m) and refractive index (1.60–1.63) were measured by spectroscopic ellipsometry at 715 nm. The thickness of the waveguides (measured by mechanical profilometry) was 1 m and their optical propagation losses were measured at different laser wavelengths (488 nm, 514 nm and 633 nm), exhibiting an approximately Rayleigh-like behavior. The thermal precipitation of silver nanocrystallites was achieved, both in air and under a controlled atmosphere (dry nitrogen) and these were characterized by visible absorption spectroscopy, which clearly showed the development of a plasmon absorption band near 415 nm, by X-ray diffraction (XRD) and Transmission Electron Microscopy (TEM). The Er3+ metastable level lifetimes for the emission at ca. 1.54 m were found to be ca. 4–6 ms, for Er3+ concentrations varying between 0.2–2.0 mol% (or (0.4–4.4) × 1020 ions/cm3), but no significant variation was observed with the Ag concentration added (up to 2.5 mol%). 相似文献
155.
The new sequential centrifugal layer chromatography extends the possibilities for preparative separation of furocoumarin isomers. In the present work, isobergapten, pimpinellin, bergapten, isopimpinellin, and sphondin were isolated from a prepurified extract of Heracleum sphondylium roots using two different techniques, namely, centrifugal layer chromatography (CLC) and sequential centrifugal layer chromatography (SCLC). The former technique was carried out with four plates, whereas the latter method required only one plate, using the same mobile phase in each case. A further advantage of the SCLC method was that all completely separated compounds could be quickly and efficiently eluted in small volumes of mehtanol. 相似文献
156.
Horst Elmar Winkelnkemper 《Annals of Global Analysis and Geometry》1992,10(3):209-218
Let
t
be the flow (parametrized with respect to arc length) of a smooth unit vector field v on a closed Riemannian manifold M
n
, whose orbits are geodesics. Then the (n-1)-plane field normal to v, v, is invariant under d
t
and, for each x M, we define a smooth real function
x
(t) : (1 +
i
(t)), where the i(t) are the eigenvalues of AA
T, A being the matrix (with respect to orthonormal bases) of the non-singular linear map d2t
, restricted to v at the point x
-t M
n.Among other things, we prove the
Theorem (Theorem II, below). Assume v is also volume preserving and that
x
'
(t) 0 for all x M and real t; then, if
x
t
: M M is weakly missng for some t, it is necessary that vx 0 at all x M. 相似文献
157.
In this paper, we study the algebraic connectivity of a Hamiltonian graph, and determine all Hamiltonian graphs whose algebraic connectivity attain the minimum among all Hamiltonian graphs on n vertices. 相似文献
158.
159.
Treewidth is a graph parameter of fundamental importance to algorithmic and structural graph theory. This article surveys several graph parameters tied to treewidth, including separation number, tangle number, well‐linked number, and Cartesian tree product number. We review many results in the literature showing these parameters are tied to treewidth. In a number of cases we also improve known bounds, provide simpler proofs, and show that the inequalities presented are tight. 相似文献
160.