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131.
《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2017,129(4):992-995
Under high pressure, some materials form electrides, with valence electrons separated from all atoms and occupying interstitial regions. This is often accompanied by semiconducting or insulating behavior. The interstitial quasiatoms (ISQ) that characterize some high pressure electrides have been postulated to show some of the chemical features of atoms, including the potential of forming covalent bonds. It is argued that in the observed high‐pressure semiconducting Li phase (oC40, Aba2), an example of such quasimolecules is realized. The theoretical evaluation of electron density, electron localization function, Wannier orbitals, and bond indices forms the evidence for covalently bonded ISQ pairs in this material. The quasimolecule concept thus provides a simple chemical perspective on the unusual insulating behavior of such materials, complementing the physical picture previously presented where the global crystal symmetry of the system plays the major role. 相似文献
132.
133.
We show that an arbitrary infinite graph G can be compactified by its ends plus its critical vertex sets, where a finite set X of vertices of an infinite graph is critical if its deletion leaves some infinitely many components each with neighbourhood precisely equal to X. We further provide a concrete separation system whose ?0‐tangles are precisely the ends plus critical vertex sets. Our tangle compactification is a quotient of Diestel's (denoted by ), and both use tangles to compactify a graph in much the same way as the ends of a locally finite and connected graph compactify it in its Freudenthal compactification. Finally, generalising both Diestel's construction of and our construction of , we show that G can be compactified by every inverse limit of compactifications of the sets of components obtained by deleting a finite set of vertices. Diestel's is the finest such compactification, and our is the coarsest one. Both coincide if and only if all tangles are ends. This answers two questions of Diestel. 相似文献
134.
Douglas R. Woodall 《Journal of Graph Theory》2019,92(4):488-490
In the article “The average degree of an edge-chromatic critical graph II” by Douglas R. Woodall (J. Graph Theory 56 (2007), 194-218), it was claimed that the average degree of an edge-chromatic critical graph with maximum degree is at least if , at least if , and at least if . Unfortunately there were mistakes in the proof of the last two of these results, which are now proved only if and , respectively. 相似文献
135.
Marién Abreu Jan Goedgebeur Domenico Labbate Giuseppe Mazzuoccolo 《Journal of Graph Theory》2019,92(4):415-444
A -bisection of a bridgeless cubic graph is a -colouring of its vertex set such that the colour classes have the same cardinality and all connected components in the two subgraphs induced by the colour classes ( monochromatic components in what follows) have order at most . Ban and Linial Conjectured that every bridgeless cubic graph admits a -bisection except for the Petersen graph. A similar problem for the edge set of cubic graphs has been studied: Wormald conjectured that every cubic graph with has a -edge colouring such that the two monochromatic subgraphs are isomorphic linear forests (ie, a forest whose components are paths). Finally, Ando conjectured that every cubic graph admits a bisection such that the two induced monochromatic subgraphs are isomorphic. In this paper, we provide evidence of a strong relation of the conjectures of Ban-Linial and Wormald with Ando's Conjecture. Furthermore, we also give computational and theoretical evidence in their support. As a result, we pose some open problems stronger than the above-mentioned conjectures. Moreover, we prove Ban-Linial's Conjecture for cubic-cycle permutation graphs. As a by-product of studying -edge colourings of cubic graphs having linear forests as monochromatic components, we also give a negative answer to a problem posed by Jackson and Wormald about certain decompositions of cubic graphs into linear forests. 相似文献
136.
Let m ≤ n ≤ k. An m × n × k 0‐1 array is a Latin box if it contains exactly m n ones, and has at most one 1 in each line. As a special case, Latin boxes in which m = n = k are equivalent to Latin squares. Let be the distribution on m × n × k 0‐1 arrays where each entry is 1 with probability p, independently of the other entries. The threshold question for Latin squares asks when contains a Latin square with high probability. More generally, when does support a Latin box with high probability? Let ε > 0. We give an asymptotically tight answer to this question in the special cases where n = k and , and where n = m and . In both cases, the threshold probability is . This implies threshold results for Latin rectangles and proper edge‐colorings of Kn,n. 相似文献
137.
《Discrete Mathematics》2019,342(10):2846-2849
138.
In Korchmáros et al. (2018)one-factorizations of the complete graph are constructed for with any odd prime power such that either or . The arithmetic restriction is due to the fact that the vertices of in the construction are the points of a conic in the finite plane of order . Here we work on the Euclidean plane and describe an analogous construction where the role of is taken by a regular -gon. This allows us to remove the above constraints and construct one-factorizations of for every even . 相似文献
139.
140.
A graph with at least vertices is said to be distance -extendable if, for any matching of with edges in which the edges lie at distance at least pairwise, there exists a perfect matching of containing . In this paper we prove that every 5-connected triangulation on the projective plane of even order is distance 3 7-extendable and distance 4 -extendable for any . 相似文献