全文获取类型
收费全文 | 124151篇 |
免费 | 6019篇 |
国内免费 | 12259篇 |
专业分类
化学 | 76918篇 |
晶体学 | 1489篇 |
力学 | 3157篇 |
综合类 | 911篇 |
数学 | 31542篇 |
物理学 | 28412篇 |
出版年
2024年 | 130篇 |
2023年 | 804篇 |
2022年 | 2112篇 |
2021年 | 2021篇 |
2020年 | 2433篇 |
2019年 | 2979篇 |
2018年 | 2534篇 |
2017年 | 3214篇 |
2016年 | 3152篇 |
2015年 | 2697篇 |
2014年 | 3936篇 |
2013年 | 8347篇 |
2012年 | 6987篇 |
2011年 | 6510篇 |
2010年 | 5314篇 |
2009年 | 7204篇 |
2008年 | 7797篇 |
2007年 | 8261篇 |
2006年 | 7484篇 |
2005年 | 6042篇 |
2004年 | 6000篇 |
2003年 | 5150篇 |
2002年 | 6576篇 |
2001年 | 4355篇 |
2000年 | 4038篇 |
1999年 | 3911篇 |
1998年 | 3439篇 |
1997年 | 2579篇 |
1996年 | 2135篇 |
1995年 | 1883篇 |
1994年 | 1677篇 |
1993年 | 1370篇 |
1992年 | 1272篇 |
1991年 | 826篇 |
1990年 | 723篇 |
1989年 | 690篇 |
1988年 | 530篇 |
1987年 | 473篇 |
1986年 | 432篇 |
1985年 | 525篇 |
1984年 | 461篇 |
1983年 | 298篇 |
1982年 | 431篇 |
1981年 | 503篇 |
1980年 | 471篇 |
1979年 | 311篇 |
1978年 | 359篇 |
1977年 | 303篇 |
1976年 | 264篇 |
1974年 | 135篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
991.
通过筛选水稻开花后48~50h的原胚和120~122h的分化胚的cDNA文库,得到一个在胚胎发育过程中表达有差异的克隆,命名为OsEES,测序结果显示OsEES含有一个预测的亚精氨合成酶结构域,编码一个大小约38×103(pI6.5)的蛋白.同时RNA原位杂交的结果显示开花48~50h的原胚中的信号强度明显大于开花120~122h的分化胚,表明OsEES可能在水稻胚胎发生过程中起到一定的调控作用. 相似文献
992.
在分子拓扑理论的基础上,构建了新的结构信息价连接性指数mχY和取代基染色指数I,并用它们研究了3 乙氧基 6 取代苯氧基哒嗪的除草活性pI50与其结构之间的定量关系,给出了相关方程,相关性良好,复相关系数分别为R1=0.9807、R2=0.9926、R3=0.9881,并预测了几个化合物的pI50值,预测值pI50(cal.)与测定值pI50(exp.)相当吻合.新方法计算方便、结果可靠. 相似文献
993.
Susumu Ariki 《Advances in Mathematics》2004,181(1):134-159
This paper determines the representation type of the Iwahori-Hecke algebras of type B when q≠±1. In particular, we show that a single parameter non-semisimple Iwahori-Hecke algebra of type B has finite representation type if and only if q is a simple root of the Poincaré polynomial, confirming a conjecture of Uno's (J. Algebra 149 (1992) 287). 相似文献
994.
聚丙烯酸高碳醇酯(PBA)及聚丙烯酸十八醇酯(POA)是具有长烷基侧链的梳状聚合物,在溶剂苯中的Huggins常数(k′)随其分子量(M)的变化而变化.在PBA-苯体系中发现,当M低于某一临界分子量(MLC)时,k′随分子量的降低显著增大;当M大于某临界分子量(MHC)时,k′随分子量的升高而增大;当M在MLC~MHC时,k′基本上保持不变.而在POA-苯体系中发现,当M低于某一临界分子量(MC)时,k′随分子量的降低显著增大;当M大于该临界分子量(MC)时,k′在0.33~0.43变化.文中同时给出了精确算法用来计算PBA-苯体系及POA-苯体系中PBA及POA的特性粘度.当k′>0.758时,用稀释外推法计算;当0.758>k′>0.426时,用一点法公式[η]=ηsp/C(√)ηr计算;当0.426>k′>0.334时,用另一一点法公式[η]=(√)2(ηsp-lnηr)/C计算. 相似文献
995.
Using the full-potential linearized augmented plane wave (FP-LAPW) method, we have studied the effect of chemistry on the average intercalation voltage (AIV) caused by the Na ions intercalating into transition metal oxides. The effect of transition metal was systematically studied by varying M=Co, Ni and Mn in NaMO2 and fixing the α-NaFeO2 layered structure. The effect of the guest atoms into the host material is discussed in terms of the structural and electronic properties. Comparatively to Li intercalation, a significant electron transfer towards transition metal was found. This observation suggests that the transition metal contribute to the AIV determination and confirms the common assumption that intercalated electron reduces M4+ to M3+. 相似文献
996.
从4~10周龄药物流产胚胎的生殖嵴和肠系膜组织中分离原始生殖细胞(primordial germ cells,PGCs),培养在添加人重组白血病抑制因子(rh LIF)、人重组碱性成纤维细胞生长因子(rh bFGF)和Forskolin的小鼠饲养层细胞上.经过4~7 d培养,PGCs形成典型的鸟巢状集落.集落在传代过程中保持碱性磷酸酶活性,且胚胎阶段性特异抗原1(SSEA-1)、胚胎阶段性特异抗原3(SSEA-3)免疫荧光染色呈阳性.具有分化潜能的PGCs能在体外连续传代培养12代.结果表明从药物流产胚胎中分离的人类PGCs可以在体外培养成为具有分化潜能的多能性干细胞. 相似文献
997.
Xicheng Zhang 《Bulletin des Sciences Mathématiques》2004,128(5):333-340
In this paper we give a representation formula for the heat semigroup on adapted vector fields by the horizontal lift of Ornstein-Uhlenbeck process over Riemannian path space. 相似文献
998.
E. N. Dancer 《Journal of Fixed Point Theory and Applications》2007,1(1):47-60
We discuss the calculation of homotopy indices on closed convex sets in a Banach space and then use these ideas to prove the
existence of multiple solutions of nonlinear elliptic equations. We obtain more information on the solutions than in earlier
work. A key idea is to calculate the homotopy index of the stable and mountain pass solutions and the connections joining
them.
Dedicated to the memory of Jean Leray 相似文献
999.
Huseyin Bekir Yildiz Jaime Castillo Dmitrii A. Guschin Levent Toppare Wolfgang Schuhmann 《Mikrochimica acta》2007,159(1-2):27-34
An amperometric biosensor for the detection of phenolic compounds was developed based on the immobilization of tyrosinase
within an Os-complex functionalized electrodeposition polymer. Integration of tyrosinase within the redox polymer assures
efficient catechol recycling between the enzyme and the polymer bound redox sites. The non-manual immobilization procedure
improves the reproducibility of fabrication process, greatly reduces the desorption of the enzyme from the immobilization
layer, and, most importantly prevents fast inactivation of the enzyme by its substrate due to fast redox cycling.
A two-layer sensor architecture was developed involving ascorbic acid oxidase entrapped within an electrodeposition polymer
in a second layer on top of the redox polymer/tyrosinase layer. Using this sensor architecture it was possible to eliminate
the current interference arising from direct ascorbate oxidation up to a concentration of 630 μM ascorbic acid. The effects
of the polymer thickness, the enzyme/polymer ratio, and the applied potential were evaluated with respect to optimal sensor
properties. The sensitivity of the optimized sensors for catechol was 6.1 nA μM−1 with a detection limit of 10 nM, and for phenol 0.15 nA μM−1 with a detection limit of 100 nM. 相似文献
1000.
Michelina Soccio Lara Finelli Nadia Lotti Valentina Siracusa Tiberio A. Ezquerra Andrea Munari 《Journal of Polymer Science.Polymer Physics》2007,45(13):1694-1703
Poly(butylene naphthalate) (PBN), poly(diethylene naphthalate) (PDEN), and poly(thiodiethylene naphthalate) (PTDEN) were synthesized and characterized in terms of chemical structure and molecular weight. The polyesters were examined by TGA, DSC, and DMTA. All the polymers showed a good thermal stability, even though depending on chemical structure. At room temperature they appeared as semicrystalline materials; the effect of the introduction along the PBN polymer chain of ether oxygen atoms or sulfur ones was a lowering in the Tg value, a decrement of Tm, and a decrease of the crystallization rate. Changing in chemical structure also affects the main α absorption associated with the glass transition which moves to lower temperature and whose energetic requirements decrease. The results were explained as due to the presence of highly flexible C? S? C or C? O? C bonds in the polymeric chain. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 1694–1703, 2007 相似文献