全文获取类型
收费全文 | 4146篇 |
免费 | 698篇 |
国内免费 | 468篇 |
专业分类
化学 | 1221篇 |
晶体学 | 68篇 |
力学 | 667篇 |
综合类 | 97篇 |
数学 | 1253篇 |
物理学 | 2006篇 |
出版年
2024年 | 8篇 |
2023年 | 38篇 |
2022年 | 82篇 |
2021年 | 71篇 |
2020年 | 106篇 |
2019年 | 88篇 |
2018年 | 96篇 |
2017年 | 152篇 |
2016年 | 170篇 |
2015年 | 131篇 |
2014年 | 201篇 |
2013年 | 383篇 |
2012年 | 247篇 |
2011年 | 298篇 |
2010年 | 219篇 |
2009年 | 276篇 |
2008年 | 246篇 |
2007年 | 274篇 |
2006年 | 249篇 |
2005年 | 190篇 |
2004年 | 200篇 |
2003年 | 205篇 |
2002年 | 173篇 |
2001年 | 136篇 |
2000年 | 142篇 |
1999年 | 135篇 |
1998年 | 117篇 |
1997年 | 71篇 |
1996年 | 81篇 |
1995年 | 70篇 |
1994年 | 69篇 |
1993年 | 57篇 |
1992年 | 48篇 |
1991年 | 39篇 |
1990年 | 35篇 |
1989年 | 26篇 |
1988年 | 25篇 |
1987年 | 22篇 |
1986年 | 13篇 |
1985年 | 27篇 |
1984年 | 15篇 |
1983年 | 7篇 |
1982年 | 14篇 |
1981年 | 10篇 |
1980年 | 9篇 |
1979年 | 9篇 |
1978年 | 6篇 |
1977年 | 7篇 |
1976年 | 8篇 |
1957年 | 3篇 |
排序方式: 共有5312条查询结果,搜索用时 15 毫秒
101.
102.
利用红外反射光谱研究了蓝宝石衬底上用金属有机物化学气相淀积方法生长的稀磁半导体GaMnN材料的晶格振动特性. 并成功地将改进的遗传算法应用于其红外反射光谱洛伦兹振子模型参数的提取. 通过与GaN薄膜的洛伦兹振子模型参数的对比研究发现,GaN掺入Mn后,ωTO向高频方向移动,γ,ε∞和εs均增加,而ωLO基本保持不变. 文中同时分析和讨论了Mn对晶格振动特性的影响及
关键词:
稀磁半导体GaMnN材料
遗传算法
洛伦兹振子模型
参数提取 相似文献
103.
104.
调制激光作用牙齿组织发生散射形成光子密度波, 而由于光热效应产生热波, 基于一维介质辐射传输漫射近似方程与一维热传导方程建立了调制激光作用牙齿组织半透明混合介质的一维热波数学模型. 利用该模型仿真分析了牙齿龋损特性参数(牙釉质龋损层光吸收系数、散射系数、热扩散系数及龋损深度)对光热辐射动态响应特性的影响与规律. 利用红外探测器(HgCdTe, 2–12 μm)记录808 nm半导体激光激发牙齿组织产生的热波信号, 由锁相放大器计算热波信号的幅值与相位. 通过频率扫描试验获得了牙齿组织的光热动态响应, 利用多参数最佳统计拟合方法得到了牙齿组织特性参数. 结果表明光热辐射测量对牙齿组织不均匀性和龋损特性均具有较高敏感性与特异性. 相似文献
105.
106.
本文介绍了一种测试继电器在动态过程中动态参数测试的方法。采用此方法能直接测量和观察继电器动态过程中的线圈电压、电流 ,同时可测出继电器的动作时间 ,还可了解其接点在接触过程是否有振动现象存在。所以 ,此方法是一种多用途的继电器动态参数测量方法 相似文献
107.
The shear-induced band texture of conventional end-on fixed side group liquid crystalline polymers (LCPs) has been investigated by using polarizing optical microscopy (POM), small angle light scattering (SALS) and infra-red dichroism techniques. The band spacing is about 1 μm, which increases very slightly on increasing the temperature of shearing and is independent of shearing rate within the range studied. The band texture is not seen to exhibit an interchange of dark and bright bands on rotation of the sample with respect to the polarizer/analyser, but a typical periodical structure is reflected by the SALS patterns of the band texture. The relaxation behaviour of the bands indicates that the band texture formed here is the result of the orderly aligning of domains exhibiting the focal-conic texture, and this is totally different from the case of main chain LCPs where the band texture is substantially an optical effect of the periodic zigzag or sinusoidal structure of parallel aligned microfibrils. Infra-red dichroism and rotating parallel-plate shearing measurements show that the axes of the backbone of the polymer tend to orient in the shearing direction and the end-on fixed mesogenic side groups tend to align perpendicular to the shearing direction. 相似文献
108.
Thixotropic materials are widely used in a variety of industrial applications. The constitutive relations to describe these materials are based on one-dimensional experiments in which the material is subjected to a shear motion and there is no unique methodology to obtain proper three-dimensional models. The path towards generalization to a three-dimensional framework is invariably carried out in a ad hoc manner. Here we propose a three-dimensional model that stems from a general thermodynamic framework that has proved to be quite robust in the development of constitutive relations, namely the application of the second law of thermodynamics together with the maximization of the entropy production. This leads to a constitutive equation that has the same form of a generalized Upper Convected Maxwell equation, if we require that changes of microstructure due to the deformation of each Maxwell element that comprises the model are reversible. Changes in microstructure are governed by a potential that is a measure of the difference between the current structure and the equilibrium structure associated with it. The equilibrium structure associated with the current structure is determined by the current value of stress, considered the main break up agent. We assume that the state of equilibrium would be achieved in a Motion With Constant Stress History, starting from the current stress state, until a steady state where the kinematics is not changing. 相似文献
109.
Matthew Thompson Carolyn Carkner Adrian Bailey Nicholas J. Mosey Nadia Kapernaum 《Liquid crystals》2013,40(9):1246-1260
Two sterically equivalent series of phenoxy-terminated 5-alkoxy-2-(4-alkoxyphenyl)pyrimidine liquid crystals were synthesised, and their mesogenic properties were characterised by polarised optical microscopy and differential scanning calorimetry (DSC). The phenoxy end-group causes a significant increase in melting point and inhibits – at least partially – the mesomorphism of these materials relative to the parent isomers; in most cases, the broad enantiotropic SmC phase formed by the parent isomers is suppressed by the addition of the phenoxy end-group. However, detailed analyses by small-angle X-ray scattering and monodomain 2D X-ray scattering suggest that these compounds form a SmA phase with a partially intercalated bilayer structure in which the phenoxy end-groups are nanosegregated. Such an intercalated bilayer structure might enable the tuning of smectogenic properties by appropriate substitution of the phenoxy end-groups. 相似文献
110.
Electrospinning of poly(lactic acid): Theoretical approach for the solvent selection to produce defect‐free nanofibers 下载免费PDF全文
Raffaella Casasola Noreen L. Thomas Stella Georgiadou 《Journal of Polymer Science.Polymer Physics》2016,54(15):1483-1498
In this study an integrated methodology was proposed for the selection of solvent systems to produce electrospinnable solutions that form defect‐free poly(lactic acid) (PLA) fibers with narrow diameter distributions. The solvent systems were chosen using a thermodynamic approach, combined with electrical and rheological property criteria. More specifically, the three step methodology includes (1) initial choice of solvent by solubility evaluation to meet thermodynamic criteria, (2) electrical properties, that is, conductivity and dielectric constant adjustment by using solvent mixtures to meet electrical property criteria, and (3) critical entanglement concentration (Ce) determination by viscosity measurements, supported by elastic and plastic moduli measurements, followed by concentration adjustment to meet rheological criteria. All three criteria need to be met to ensure defect‐free nanofiber morphology. The methodology was demonstrated using PLA solutions that were characterized in terms of thermodynamic properties, conductivity, surface tension, and viscosity measurements. These data were analyzed and related to the nanofiber morphology and diameter as determined from scanning electron microscopy (SEM). Measurements of the elastic (G′) and the plastic (G″) moduli of PLA solutions showed a sharp increase of G′ at the chain entanglement concentration. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2016 , 54, 1483–1498 相似文献