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101.
《Arabian Journal of Chemistry》2020,13(11):8347-8360
FeN -co-doped TiO2 photocatalysts are prepared by sol–gel method using titanium tetraisopropoxide, urea and iron(II) acetylacetonate as precursors of titania, nitrogen and iron, respectively. The prepared samples are analysed from chemical-physical point of view by X-ray diffraction (XRD), Raman spectroscopy, UV–Vis diffuse reflectance spectroscopy (UV–Vis DRS), specific surface area measurements and scanning electron microscopy (FESEM). UV–Vis DRS spectra evidence that the co-doping of TiO2 with N and Fe leads to the narrowing of the band gap value (2.7 eV) with respect to Fe-doped TiO2 (2.8 eV) and N-doped TiO2 (2.9–3 eV). XRD patterns show that photocatalysts are mainly in anatase phase and Fe and N ions are successfully incorporated into the TiO2 lattice. The average crystallite size of Fe-N co-doped TiO2 is slightly lower than the other samples and equal to about 7 nm and the specific surface area of the co-doped sample results to be 117 m2 g−1. Photocatalytic performances of all prepared samples are evaluated by analysing the degradation of Acid Orange 7 azo dye under visible light irradiation. Photocatalytic efficiency obtained using FeN co-doped TiO2 strongly increases compared to undoped TiO2, N-doped TiO2 and Fe-doped TiO2 photocatalysts. In detail, using the co-doped photocatalyst, dye discoloration and mineralization result equal to about 90 and 83% after 60 min of LEDs visible light irradiation, underlining the best performances of the FeN co-doped TiO2 photocatalyst both in terms of treatment time and electric energy consumption. 相似文献
102.
研制了酸度在线检测装置,并应用于溶液酸度在线检测,溶液酸度在线检测装置,设有防污过滤器,自动采样器,蠕动泵,小型管道pH传感器和控制电路等,其特点为防污除油,随机自动采样,定时检测,全部管道化,可单独使用和计算机控制系统联网,适用于溶液酸在线分析,测定精度〈pH0.05。 相似文献
103.
104.
Patrizia Calaminici Victor D. Domínguez-Soria Gerald Geudtner Elizabeth Hernández-Marín Andreas M. Köster 《Theoretical chemistry accounts》2006,115(4):221-226
The parallelization of the three-center electron repulsion integrals arising from the variational fitting of the Coulomb potential
is presented. A scheme for dynamical load balancing of the corresponding loop structure is discussed. The implementation in
the density functional theory program deMon using the message passing interface is described. The efficiency of the parallelization
is analyzed by selected benchmark calculations 相似文献
105.
Improved quantification limits in chiral capillary electrochromatography by peak compression effects
The peak compression effect has been applied to improve quantification limits in chiral capillary electrochromatography (CEC). A stationary phase based on the chiral selector vancomycin (Chirobiotic V) was used for separations of the enantiomers of mianserin. By adding solvents with a low dielectric constant, e.g. 2-propanol or tetrahydrofuran, to the sample solution, peak compression could be induced. The plate numbers for the minor enantiomer increased from approximately 100,000 to 1.4-1.6 million plates/m, when the composition of the mobile phase was adjusted so that the analyte eluted within either one of two system zones originating from the sample solution. A 10-fold improvement in the quantification limit for the minor enantiomer was obtained compared to elution under non-focused conditions. 相似文献
106.
Crude extracellular invertase fromSclerotium rolfsii, when coupled to glutaraldehyde activated Indion 48-R, retained 70–80% activity of the soluble enzyme. Immobilization resulted
in a decrease in the pH and temperature optima but it increased the temperature stability. Km and Vmax also increased as a result of immobilization. Both soluble and immobilized invertase showed inhibition at high substrate
concentrations. The bound enzyme showed excellent stability to repeated use and retained approx 90% of its initial activity
after 8 cycles of use. 相似文献
107.
以常见的阴、阳离子的检验为例,研究了如何实施基于标准的教学。校本教材的开发为标准、教材、教学、评价的一致性提供保障;以学生应知的和能做的驱动课堂活动;根据达成标准应有怎样的质量表现,试卷编制先于教学设计。课堂上,“教”“学”双方都明确学习目标,教师提供多种策略来满足学生多样的学习需要,如提供工具,搭建脚手架,并以“微”研究性学习的方式展开教学,给学生提供了充分的进步空间。 相似文献
108.
We prove two new upper bounds on the size of binary codes with a minimum distance of three, namelyA(10, 3)76 andA(11, 3)152. 相似文献
109.
Tamás F. Móri 《Journal of Theoretical Probability》1995,8(1):139-164
Considering an infinite string of i.i.d. random letters drawn from a finite alphabet we define the cover timeW
n
as the number of random letters needed until each pattern of lenghtn appears at least once as a substring. Sharp weak and a.s. limit results onW
n
are known in the symmetric case, i.e., when the random letters are uniformly distributed over the alphabet. In this paper we determine the limit distribution ofW
n
in the nonsymmetric case asn. Generalizations in terms of point processes are also proved.Dedicated to Endre Csáki on his 60th birthday. 相似文献
110.
Alexander Koldobsky 《Journal of Theoretical Probability》1994,7(1):135-145
Let μ be a measure in a Banach spaceE, f be an even function onR. We consider the potentialg(a)=f E f(‖x?a‖)dμ(x). The question is as follows: For whichf does the potentialg determine μ uniquely? In this article we give answers in the cases whereE=l ∞ n and wheref(t)=|t| p andE is a finite dimensional Banach space with symmetric analytic norm. Calculating the Fourier transform of the functionf(‖x‖ ∞) we give a new proof of the J. Misiewicz's result that the functionf(‖x‖ ∞) is positive definite only iff is a constant function. 相似文献