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61.
Over 8000 line positions and intensities of phosphine (PH3) at 3 μm have been measured at 0.0115 cm−1 resolution with the McMath-Pierce Fourier Transform spectrometer at Kitt Peak. The observed line intensities ranged from 4.13 × 10−6 to 4.69 × 10−2 cm−2 atm−1 at 296 K, for line positions between 2724.477 and 3601.652 cm−1. This region spans eight interacting vibrational states: 3ν2 (2940.8 cm−1), 2ν2 + ν4 (3085.6 cm−1), ν2 + 2ν4 (3214.9 cm−1), ν1 + ν2 (3307.6 cm−1), ν2 + ν3 (3310.5 cm−1), 3ν4 (∼3345 cm−1), ν1 + ν4 (3426.9 cm−1), and ν3 + ν4 (3432.9 cm−1). Assignments have been determined for all the bands except 3ν4 (a weak band in a highly congested area) for a total of 4232 transitions. The total integrated intensity for this region is 5.70 cm−2 atm−1 near 296 K, and assigned lines account for 79% of the observed absorption. The two strongest bands in the region are ν1 + ν4 and ν3 + ν4 with band strengths at 296 K of 1.61 and 2.01 cm−2 atm−1, respectively. An empirical database of PH3 line parameters (positions, intensities, and assignments) is now available. Lower state energies (corresponding to assignments from this study) and line widths from the literature are included; default values are used for unassigned features. 相似文献
62.
John A. Ford Yasushi Narushima Hiroshi Yabe 《Computational Optimization and Applications》2008,40(2):191-216
Conjugate gradient methods are appealing for large scale nonlinear optimization problems, because they avoid the storage of
matrices. Recently, seeking fast convergence of these methods, Dai and Liao (Appl. Math. Optim. 43:87–101, 2001) proposed a conjugate gradient method based on the secant condition of quasi-Newton methods, and later Yabe and Takano (Comput.
Optim. Appl. 28:203–225, 2004) proposed another conjugate gradient method based on the modified secant condition. In this paper, we make use of a multi-step
secant condition given by Ford and Moghrabi (Optim. Methods Softw. 2:357–370, 1993; J. Comput. Appl. Math. 50:305–323, 1994) and propose two new conjugate gradient methods based on this condition. The methods are shown to be globally convergent
under certain assumptions. Numerical results are reported. 相似文献
63.
We show that the conjectures by Matthews and Sumner (every 4-connected claw-free graph is Hamiltonian), by Thomassen (every 4-connected line graph is Hamiltonian) and by Fleischner (every cyclically 4-edge-connected cubic graph has either a 3-edge-coloring or a dominating cycle), which are known to be equivalent, are equivalent to the statement that every snark (i.e. a cyclically 4-edge-connected cubic graph of girth at least five that is not 3-edge-colorable) has a dominating cycle.We use a refinement of the contractibility technique which was introduced by Ryjá?ek and Schelp in 2003 as a common generalization and strengthening of the reduction techniques by Catlin and Veldman and of the closure concept introduced by Ryjá?ek in 1997. 相似文献
64.
Otfried Cheong Xavier Goaoc Andreas Holmsen Sylvain Petitjean 《Discrete and Computational Geometry》2008,39(1-3):194-212
We prove Helly-type theorems for line transversals to disjoint unit balls in ℝ
d
. In particular, we show that a family of n≥2d disjoint unit balls in ℝ
d
has a line transversal if, for some ordering ≺ of the balls, any subfamily of 2d balls admits a line transversal consistent with ≺. We also prove that a family of n≥4d−1 disjoint unit balls in ℝ
d
admits a line transversal if any subfamily of size 4d−1 admits a transversal.
Andreas Holmsen was supported by the Research Council of Norway, prosjektnummer 166618/V30. Otfried Cheong and Xavier Goaoc
acknowledge support from the French-Korean Science and Technology Amicable Relationships program (STAR). 相似文献
65.
J. Jayapandian 《Applied Surface Science》2008,255(1):104-107
Automation of positron beam experiment with a single chip embedded design using a programmable system on chip (PSoC) which provides easy interfacing of the high-voltage DC power supply is reported. Virtual Instrument (VI) control program written in Visual Basic 6.0 ensures the following functions (i) adjusting of sample high voltage by interacting with the programmed PSoC hardware, (ii) control of personal computer (PC) based multi channel analyzer (MCA) card for energy spectroscopy, (iii) analysis of the obtained spectrum to extract the relevant line shape parameters, (iv) plotting of relevant parameters and (v) saving the file in the appropriate format. The present study highlights the hardware features of the PSoC hardware module as well as the control of MCA and other units through programming in Visual Basic. 相似文献
66.
Our understanding of interfacial phenomena at the surfaces of critical systems, and in particular at the surfaces of critical binary liquid mixtures, has improved significantly in the past decade. There is now substantial agreement between theory and experiment. In this paper we review recent experimental progress, provide a conceptual framework within which the majority of these experiments can now be understood, and discuss critically any remaining unresolved discrepancies between experiments or with theory. 相似文献
67.
Anna de Mier 《Discrete Mathematics》2005,301(1):57-65
We prove that if a graph H has the same Tutte polynomial as the line graph of a d-regular, d-edge-connected graph, then H is the line graph of a d-regular graph. Using this result, we prove that the line graph of a regular complete t-partite graph is uniquely determined by its Tutte polynomial. We prove the same result for the line graph of any complete bipartite graph. 相似文献
68.
David P. Kratz 《Journal of Quantitative Spectroscopy & Radiative Transfer》2008,109(6):1060-1080
Over the last quarter century, improvements in the determination of the spectroscopic characteristics of the infrared-active trace species have enhanced our ability to retrieve quantitative distributions of temperatures, clouds, and abundances for various trace species within the Earth's atmosphere. These improvements have also allowed for refinements in the estimates of climatic effects attributed to changes in the Earth's atmospheric composition. Modeling efforts, however, have frequently experienced significant delays in assimilating improved spectroscopic information. Such is the case for highly parameterized models, where considerable effort is typically required to incorporate any revisions. Thus, a line-by-line radiative transfer model has been used to investigate the magnitude of the effects resulting from modifications to the spectroscopic information. Calculations from this line-by-line model have demonstrated that recent modifications to the HITRAN (High Resolution Transmission) line parameters, the continuum formulation, and the CO2 line-mixing formulation can significantly affect the interpretation of the high spectral resolution radiance and brightness temperature retrievals. For certain moderate-resolution satellite remote sensing channels, modifications to these spectroscopic parameters and formulations have shown the capacity to induce changes in the calculated radiances equivalent to brightness temperature differences of 1-2 K. Model calculations have further shown that modifications of the spectroscopic characteristics tend to have a modest effect on the determination of spectrally integrated radiances, fluxes, and radiative forcing estimates, with the largest differences being of order 1 W m−2 for the total thermal infrared fluxes, and of order 2-3% of the calculated radiative forcing at the tropopause attributed to the combined doubling of CO2, N2O, and CH4. The results from this investigation are intended to function as a guide to differentiate between cases where older parameterizations provide acceptable results, within specified accuracy bounds, and cases where upgrades to the latest spectroscopic database are necessary. 相似文献
69.
M.A. Koshelev 《Journal of Quantitative Spectroscopy & Radiative Transfer》2011,112(3):550-552
Broadening and shifting of the 211-202 transition of H216O, H217O, H218O by pressure of water, nitrogen and oxygen were precisely measured at room temperature using spectrometer with radio-acoustic detection of absorption. Shift parameters for all studied lines as well as broadening parameters of H217O, H218O lines were measured for the first time. Comparison of obtained results with previously known experimental and theoretical data is presented. 相似文献
70.
Two-dimensional (2D) rod-type photonic crystal (PC) line defect waveguide (LDW) laser cavities based on three types of line defect modes with zero group velocity are studied by using finite-difference time-domain (FDTD) method. These laser cavities have high quality (Q) factor, better localization of light, non-uniform gain distribution and small overlap between gain medium and light field. Therefore, they have the advantages over conventional and air-bridge PC cavities with uniform gain, such as low threshold, single mode lasing and effectively avoiding thermal effect. From their comparison, one can find the mode at middle Brillouin zones (BZ) is the best one to be used as lasing mode. Its dynamic lasing process and lasing features are demonstrated by the numerical experiment where the FDTD method coupling Maxwell's equations with the rate equations of electronic population is used. 相似文献