Design and synthesis of novel indoline-(thio)urea hybrids

Abstract

A series of novel indoline-(thio)urea were designed and prepared using indoline(s) as a new platform and tested as organocatalysts in the Michael and Morita–Baylis–Hillman reactions. Most of the compounds were found to be very active catalysts although they did not promote the enantioselectivity. As agents for the conversion of thiocarbonyl compounds into carbonyl compounds, potentials of PIFA and DDQ were also displayed. Furthermore, DFT calculations rationalized the experimentally observed non-enantioselectivity of the catalysts.     

Some MnIII-porphyrins with de-polymerization activity toward humic acid

Four Mn^III-porphyrin complexes, chloro(tetraphenylporphinato)Mn^III(1,6-diaminohexane), bromo(tetraphenylporphinato)Mn^III(1,6-diaminohexane), azido(tetraphenylporphinato)Mn^III(1,6-diaminohexane), and thiocyanato(tetraphenylporphinato)Mn^III(1,6-diaminohexane), have been synthesized. These complexes have been characterized using UV-Vis, IR, ESI-mass spectra, elemental analyses, magnetic susceptibility measurements, and conductivity measurement. The molar conductance values of these complexes in ethanol indicate non-electrolytes. The utility of these complexes in de-polymerization of coal using humic acid as the coal model has been tested by the optical density method.     

Three‐dimensional computation for flow‐induced vibrations in in‐line and cross‐flow directions of a circular cylinder

We present numerical results for in‐line and cross‐flow vibrations of a circular cylinder, which is immersed in a uniform flow and is elastically supported by damper‐spring systems to compute vibrations of a rigid cylinder. In the case of a circular cylinder with a low Scruton number, it is well‐known that two types of self‐excited vibrations appear in the in‐line direction in the range of low reduced velocities. On the other hand, a cross‐flow vibration of the circular cylinder can be excited in the range of high reduced velocities. Therefore, we compute the flow‐induced vibrations of the circular cylinder in the wide range of the reduced velocities at low and high Scruton numbers and discuss about excitation mechanisms in the in‐line and cross‐flow directions. Copyright © 2011 John Wiley & Sons, Ltd.     

Phonon spectra in one-dimensional quasicrystals

The propagation of phonons in one-dimensional quasicrystals is investigated. We use the projection method which has been recently proposed to generate almost periodic tilings of the line. We define a natural Laplace operator on these structures, which models phonon (and also tight-binding electron) propagation. The selfsimilarity properties of the spectrum are discussed, as well as some characteristic features of the eigenstates, which are neither extended nor localized. The long-wavelength limit is examined in more detail; it is argued that one is the lower critical dimension for this type of models.     

On some measurements of the propagation properties of thermal waves in the Nb-H and Ta-H systems

Summary By means of an experimental technique based on a nonsteady-state method,i.e. on the propagation of thermal waves, we have measured at room temperature for oscillation frequencies between 6 and 30 mHz the thermal diffusivity, the lateral thermal-loss coefficient and the ?fractional heat loss? in Nb and Ta wires as a function of hydrogen doping. The appearance of hydride formation and precipitation notably changes the behaviour of these quantities. From these measurements it was also possible to calculate the propagation velocity and attenuation coefficient of thermal waves. It was found that the increase of the hydrogen concentration in the solid solution produces a gradual decrease in the velocity and increase in the attenuation coefficient until the solubility limit is reached. For larger hydrogen concentrations, the velocity showed a tendency to increase towards the value of the pure metal, while the attenuation coefficient decreased below the value of the pure metal. These results as a whole appear quite promising for studying the properties of hydrogenated systems. This work was supported by the Gruppo Nazionale di Struttura della Materia of the Consiglio Nazionale delle Ricerche and by the Centro Interuniversitario di Struttura della Materia of the M.P.I., Roma (Italia).     

Some solvable models of nonuniform classical fluids

A model classical fluid is constructed by assuming that the direct correlation functionc(r – r) is independent of any applied external field. Thermodynamic consistency requires thatc(r – r) 0, and permits explicit representation of the model by a many-body interaction potential. In the canonical ensemble, the model shows a phase transition to an infinite density condensed phase, but in the grand canonical ensemble only an anomalous transition to zero density vapor is found to stably exist.     

Transition radiation from polarization charges

Summary A treatment of transition radiation is presented. This is based on the fields produced by the polarization charges in the radiation zone. These charges are extracted from the exact forms of the fields which were derived previously. A distinction is found between the radiation in the forward and in the backward regions. This would call for experimental verification. Comparison with other treatments shows similarity in the general features but important differences in the details.

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Riassunto Si presenta una trattazione della radiazione transitoria. Essa è basata sui campi emessi nella regione asintotica dalle cariche di polarizzazione. Queste cariche sono estratte dalle forme esatte di campi che erano stati precedentemente derivati. Si verifica una distinzione chiara fra la radiazione nella direzione avanti e indietro. Questo neccesiterebbe una verifica sperimentale. Il confronto con altri trattamenti mostra una somiglianza nelle linee generali ma anche importanti differenze nei dettagli.

     

Diffraction integral for misaligned systems and interference effects of optical arrays

Summary In the present paper, a diffraction integral formula for a misaligned optical system is derived. The interference effects of opticalelement arrays are studied by means of such a formula. The possibility of eliminating interference fringes is discussed. The conclusion is that the interference fringes could be eliminated when the αβγδ condition for arrays is satisfied. The synthetical aberration is simultaneously eliminated. However, in this case, the synthetical image coincides with the individual images. For some special application, the synthetical image does not coincide with the individual images and the αβγδ condition is not fulfilled. But the interference fringes may disappear in some special cases.

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Riassunto La formula di Collins, che esprime il cammino ottico fra un punto del piano oggetto e un punto del piano immagine nel caso di un sistema ottico centrato, è generalizzata al caso di un sistema ottico disallineato. La formula cosí ottenuta è applicata allo studio del fenomeno d’interferenza che ha luogo nel piano della cosiddetta ?immagine sintetica? fra i vari fasci emergenti da una cortina di elementi ottici. Si discutono infine le condizioni in cui non si hanno frange d’interferenza sull’immagine sintetica.

     

Effect of random density irregularities on nonlinear evolution of Langmuir waves in interplanetary medium

The evolution of nonlinear Langmuir waves in the interplanetary medium is investigated by appropriately accounting for the random density irregularities of the medium. A pair of modified Zakharov equations, which describe these waves, is solved numerically as an initial value problem for large scale (≫ 10² km) initial pertubations. For an ion acoustic-Langmuir solitary wave, the random irregularities damp the Langmuir wave by way of scattering and let the ion density perturbation radiate away in a few days. However an initial solitary or shock-like Langmuir wave excites the ion density perturbations within a fraction of a second, and then itself gets damped. These effects will strongly decelerate the collapse of large scale Langmuir waves. The possibility of detecting these processes, by means of interplanetary scintillation, is discussed. The authors felicitate Prof. D S Kothari on his eightieth birthday and dedicate this paper to him on this occasion.