Theoretical study of the electronic structure of LiNa and LiNa<Superscript>+</Superscript> molecules

Adiabatic potential energy, spectroscopic constants, dipole moments, and vibrational levels of the lowest electronic states of the alkali dimer LiNa molecule dissociating into Na (3s, 3p, 4s, 3d, and 4p) + Li (2s, 2p, 3s, and 3p) in ^1,3Σ, ^1,3Π, and ^1,3Δ symmetries are presented. Adiabatic results are also reported for ²Σ, ²Π, and ²Δ electronic states of the molecular ion LiNa⁺ dissociating into Li (2s, 2p, 3s, and 3p) + Na⁺ and Li⁺  + Na(3s, 3p, 4s, 3d, and 4p). We use an ab initio approach involving a non-empirical pseudopotential for the Li (1s²) and Na (1s²2s²2p⁶) cores and core valence correlation correction. A very good agreement is obtained for some lowest states of the LiNa and LiNa⁺ molecules for spectroscopic constants with the available theoretical works. The existence of numerous avoided crossings between electronic states of ²Σ and ²Π symmetries is related to the charge transfer process between the two ionic systems Li⁺Na and LiNa⁺.     

Spectral and temporal features of multiple spontaneous NMR-maser emissions

When a system composed of dissolved laser-polarized xenon with negative spin temperature is put inside a high field NMR magnet, a series of spontaneous maser emissions can be observed. We report here their spectral and temporal features using a processing model derived from the solution of the Bloch equations in the presence of radiation damping. We show, in particular, that by combining Fourier transformation and squared modulus, a parameter allowing the characterization of the burst of transverse magnetization can be determined. This parameter is shown to be correlated with the radiated energy. Moreover, this processing clearly reveals features which can probably be assigned to effects resulting from distant dipolar fields. Finally, the analysis of the experimental data reveals an unexpected behavior of the ¹²⁹Xe transverse self-relaxation.     

利用BP神经网络光谱分类法研究肉品新鲜度

利用自行设计的一种光纤探头式生物表面光谱测试系统 ,对肉品进行测量。建立用于肉品新鲜度的自动分类和识别的 BP神经网络 ,准确率达到 93.3%。试验表明 ,利用光谱分析法测量肉品的新鲜度快捷、准确 ,可用于实际肉品检测     

激发态1，2-二硫环丁烯去活性和异构化机理的理论研究

运用完全活性空间多组态CASSCF方法研究了激发态1,2-二硫环丁烯（1,2-Dithiete）势能面交叉机理．自旋．轨道耦合（SOC）常数采用完全Pauli-Breit旋轨耦合算符（包括单电子和双电子项）进行计算,其强度为198．37或211．35cm^-1,对不同自旋态跃迂起着重要作用．研究结果表明：光激发1,3-dithiol-2-one导致形成主要产物trans—dithioglyoxal（Trans-MinS0）和次级产物thiolthioketene．计算与实验观察结果一致．     

灰度图像复原的一种空间适应性向前向后扩散模型

该文考虑退化灰度图像复原问题. 首先, 作者利用时滞正则化方法定义退化图像去噪过程和去模糊过程之间的权重函数, 将激波过滤器边缘增强模型与水平集运动去噪模型相结合, 建立一种新的图像磨光增强偏微分方程. 然后, 证明该偏微分方程初值问题黏性弱解的存在唯一性. 最后, 给出该模型的部分数值算例.     

基于非凸正则化项的合成孔径雷达图像分割新算法

合成孔径雷达图像中乘性噪音的存在使合成孔径雷达图像分割变得非常困难.针对这一难题,本文以提高分割准确度,保护图像的几何结构边缘和提高算法的鲁棒性为目的,提出了一种适用于处理合成孔径雷达图像分割的新模型.新模型结合合成孔径雷达图像的区域和边缘信息,首先通过引入非凸的正则化项,定义了能量泛函;然后极小化能量泛函,建立了水平集函数演化的偏微分方程;最后对水平集演化方程的数值求解,实现了对合成孔径雷达图像感兴趣区域的分割.分别采用仿真图像和实测合成孔径雷达图像对新模型进行验证,结果表明,新模型对合成孔径雷达图像具有很强的边缘定位能力,能使目标区域分割更完整.     

水生植物与水体混合像元的反射高光谱特征分析

研究了水生植物与水体混合像元的反射高光谱特征,并设计了一个3因素2水平的正交试验,F检验表明:对于单因素,波段和混合像元面积比均对混合像元的反射高光谱影响显著,而探测角不显著;对于交互作用,则波段与混合像元面积比、探测角与混合像元面积比也均对反射高光谱影响显著,而探测角与波段不显著。本文对影响混合像元反射高光谱特征的因素及其交互作用进行了定量分析,为混合像元的深入研究提供了一种新的方法。     

Noisy image segmentation based on nonlinear diffusion equation model

This paper addresses the segmentation problem in noisy image based on nonlinear diffusion equation model and proposes a new adaptive segmentation model based on gray-level image segmentation model. This model also can be extended to the vector value image segmentation. By virtue of the prior information of regions and boundary of image, a framework is established to construct different segmentation models using different probability density functions. A segmentation model exploiting Gauss probability density function is given in this paper. An efficient and unconditional stable algorithm based on locally one-dimensional (LOD) scheme is developed and it is used to segment the gray image and the vector values image. Comparing with existing classical models, the proposed approach gives the best performance.