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81.
82.
CHANG Da-Wei 《理论物理通讯》2007,47(6):1143-1144
In this note, we would like to point out that (i) of Corollary 1 given by Zhang et al. (cf Commun. Theor. Phys. 39 (2003) 381) is incorrect in general. 相似文献
83.
84.
Tomislav Bali Marija Paurevi Marta Po
kaj Martina Medvidovi-Kosanovi Dominik Goman Aleksandar Szchenyi Zsolt Preisz Sndor Kunsgi-Mt 《Molecules (Basel, Switzerland)》2022,27(12)
The century-old, well-known odd–even effect phenomenon is still a very attractive and intriguing topic in supramolecular and nano-scale organic chemistry. As a part of our continuous efforts in the study of supramolecular chemistry, we have prepared three novel aromatic alcohols (1,2-bis[2-(hydroxymethyl)phenoxy]butylene (Do4OH), 1,2-bis[2-(hydroxymethyl)phenoxy]pentylene (Do5OH) and 1,2-bis[2-(hydroxymethyl)phenoxy]hexylene (Do6OH)) and determined their crystal and molecular structures by single-crystal X-ray diffraction. In all compounds, two benzyl alcohol groups are linked by an aliphatic chain of different lengths (CH2)n; n = 4, 5 and 6. The major differences in the molecular structures were found in the overall planarity of the molecules and the conformation of the aliphatic chain. Molecules with an even number of CH2 groups tend to be planar with an all-trans conformation of the aliphatic chain, while the odd-numbered molecule is non-planar, with partial gauche conformation. A direct consequence of these structural differences is visible in the melting points—odd-numbered compounds of a particular series display systematically lower melting points. Crystal and molecular structures were additionally studied by the theoretical calculations and the melting points were correlated with packing density and the number of CH2 groups. The results have shown that the generally accepted rule, higher density = higher stability = higher melting point, could not be applied to these compounds. It was found that the denser packaging causes an increase in the percentage of repulsive H‧‧‧H interactions, thereby reducing the stability of the crystal, and consequently, the melting points. Another interesting consequence of different molecular structures is their electrochemical and antioxidative properties—a non-planar structure displays the highest oxidation peak of hydroxyl groups and moderate antioxidant activity. 相似文献
85.
Hooman Moradpour Mohsen Javaherian Ebrahim Namvar Amir Hadi Ziaie 《Entropy (Basel, Switzerland)》2022,24(6)
Relying on the quantum tunnelling concept and Maxwell–Boltzmann–Gibbs statistics, Gamow shows that the star-burning process happens at temperatures comparable to a critical value, called the Gamow temperature () and less than the prediction of the classical framework. In order to highlight the role of the equipartition theorem in the Gamow argument, a thermal length scale is defined, and then the effects of non-extensivity on the Gamow temperature have been investigated by focusing on the Tsallis and Kaniadakis statistics. The results attest that while the Gamow temperature decreases in the framework of Kaniadakis statistics, it can be bigger or smaller than when Tsallis statistics are employed. 相似文献
86.
Jaime Aspas-Caceres Marc Rico-Pasto Isabel Pastor Felix Ritort 《Entropy (Basel, Switzerland)》2022,24(7)
Nonequilibrium work relations and fluctuation theorems permit us to extract equilibrium information from nonequilibrium measurements. They find application in single-molecule pulling experiments where molecular free energies can be determined from irreversible work measurements by using unidirectional (e.g., Jarzynski’s equality) and bidirectional (e.g., Crooks fluctuation theorem and Bennet’s acceptance ratio (BAR)) methods. However, irreversibility and the finite number of pulls limit their applicability: the higher the dissipation, the larger the number of pulls necessary to estimate G within a few . Here, we revisit pulling experiments on an RNA three-way junction (3WJ) that exhibits significant dissipation and work-distribution long tails upon mechanical unfolding. While bidirectional methods are more predictive, unidirectional methods are strongly biased. We also consider a cyclic protocol that combines the forward and reverse work values to increase the statistics of the measurements. For a fixed total experimental time, faster pulling rates permit us to efficiently sample rare events and reduce the bias, compensating for the increased dissipation. This analysis provides a more stringent test of the fluctuation theorem in the large irreversibility regime. 相似文献
87.
研究了一类具有Hassell-Varely功能性反应函数的食饵-捕食模型的回馈控制系统,利用比较连续定理和一致度定理,证明了系统正周期解的存在性,并通过构造Lyapunov函数给出了系统全局稳定性的充分条件和证明. 相似文献
88.
梯度是磁共振成像(MRI)的关键环节.通过采集谱仪梯度波形信号并进行分析,提取出各通道波形的特征点,从而有助于快速准确地判断谱仪梯度硬件电路或脉冲序列编写是否存在问题.采用虚拟仪器LabVIEW软件控制高速采集卡DAQ-2005设计实现多路采集系统,对谱仪的梯度输出进行采集.通过对波形数据进行直方图统计、滤波、差分计算等分析,提取出波形的特征点,这些特征点包含时间与幅度信息.使用实验室自主研发的谱仪进行了多次实验,对该方法进行验证,证明了该方法的有效性,也为谱仪研制和脉冲序列开发提供了一种辅助测试方法. 相似文献
89.
采用鞍点截断变分方法和鞍点复数转动技术,计算和分析了锂洞原子双激发共振态[1s(2s2p)3P]2P0的鞍点能量和波函数.计算结果表明这种理论计算方法是获得高精度的能量值的重要保证. 相似文献
90.
Der Geometriefaktor von radioaktiven umschlossenen oder offenen Strahlenquellen hängt bei der Messung mittels einer Kernstrahlungsmeßsonde von der räumlichen Anordnung der Strahlenquelle zu der strahlenexponierten wirksamen Fläche des Detektors und von der Geometrie der Strahlenquelle selbst ab. Fūr punktförmige Strahler in verschiedenen Positionen, Geraden, Kreisflächen und Zylinder wurde in möglichst einheitlicher Vorgehensweise die Berechnung der Geometriefaktoren bezüglich kreisförmiger ebener Detektionsflächen vorgenommen und rechentechnisch in Form von BESM 6-Algolprogrammen realisiert. Die Berechnungsergebnisse sind untereinander konsistent und wurden möglichst durch unabhängige Verfahren oder experimentelle Werte kontrolliert. Die Rechengenauigkeit kann gemäß den vorliegenden Anforderungen frei gewählt werden. 相似文献