随机游动的阶梯高度和最大值及其在风险理论中的应用

该文研究了均值为负的实值随机游动的阶梯高度及最大值, 在指数估计的条件不满足的情况下,得到了它们分布的局部渐近估计和尾渐近估计, 并将这些结果应用到风险理论中的Sparre Andersen 风险模型上, 得到了一些关于破产概率的新结果.     

CONCERTED H-BONDING TEMPLATE SYNTHESIS OF AN ORDERED LADDER POLYSILSESQUIOXANE

A novel soluble regular ladder poly（benzoyl-3-aminopropyl） silsesquioxane （LPBAS） was facilely prepared under effective assistance of concerted H-bonding self-assembly of amido groups of side chains and silanol groups, respectively, of a new template monomer [1,3-bis（benzoyl-3-aminopropyl）-1,1,3,3-tetraethoxydisiloxane] （M）. The ordered ladder structure of LPBAS is manifested in： （1） the presence of two Bragg peaks representing the ladder width （d） and ladder thickness （t） in X-ray diffraction （XRD） pattern; （2） narrow base-line width （w = 6） of resonance absorption for -CH2SiO3/2 moiety in 29Si-NMR and （3） high glass transition temperature Tg = 1 12℃ in differential scanning calorimetry （DSC） analysis.     

ARCHITECTURE OF LADDER,TUBULAR AND SIEVE-PLATE POLYMERS PREPARED BY STEPWISE COUPLING POLYMERIZATION

"Stepwise-coupling polymerization" (SCP) is a very useful approach for preparing microstructure-controllableordered network polymers, including soluble one-dimensional ladderlike polymers (LP) and tubular polymers (TP), and two-dimensional sieve-plate polymers. The novel reactive LPs are important precursors of micro-structure controllable polymerssuch as "fishbone-" or "rowboat-"like mesomorphic polymers and their metal complexes as well as tubular polymers (TPs).They are full of great potential for use as advanced materials.     

Structural Fusion Yields Guest Acceptors that Enable Ternary Organic Solar Cells with 18.77 % Efficiency

The design and selection of a suitable guest acceptor are particularly important for improving the photovoltaic performance of ternary organic solar cells (OSCs). Herein, we designed and successfully synthesized two asymmetric silicon–oxygen bridged guest acceptors, which featured distinct blue-shifted absorption, upshifted lowest unoccupied molecular orbital energy levels, and larger dipole moments than symmetric silicon–oxygen-bridged acceptor. Ternary devices with the incorporation of 14.2 wt % these two asymmetric guest acceptors exhibited excellent performance with power conversion efficiencies (PCEs) of 18.22 % and 18.77 %, respectively. Our success in precise control of material properties via structural fusion of five-membered carbon linkages and six-membered silicon–oxygen connection at the central electron-donating core unit of fused-ring electron acceptors can attract considerable attention and bring new vigor and vitality for developing new materials toward more efficient OSCs.     

浅埋偏压隧道出口变形机理及稳定性分析

以皖南某公路浅埋偏压隧道出口段高边坡为研究对象,提出了"零开挖进洞"的施工方案,并结合洞口的工程地质条件,采取必要的加固措施。通过对该边坡现场工程地质条件的系统调查,首先对边坡的岩体结构类型及其成因机制、结构面与坡面组合特征进行细致研究,在此基础上通过FLAC^3D数值模拟,结合工程地质条件分析,对其变形破坏机制进行深入探讨。研究结果表明,边坡的变形首先以隧道内侧存在的软弱岩体(挤压错动带、断层)的不均匀压缩为先导,进而引起上部岩体产生由NE向陡缓结构面构成的阶梯状滑动,这将会使隧道构筑物及隧道外壁承受较大的压应力,当压应力超过隧道构筑物及外壁的极限强度时将产生破坏,从而诱发上部岩体产生更大规模的地质灾害。基于此,隧道进洞开挖前首先应对上部岩体进行加固处理,避免隧道构筑物及隧道外壁产生应力集中现象。     

A Bifunctional Lewis Acidic Spacer in Self-Assembled Molecular Stairs and Ladders

Depending on the stoichiometry , diindacycle 1 and pyrazine in THF reversibly form a stair- or a ladderlike self-organized coordination polymer. In both cases, the building blocks are assembled at angles close to 90°.     

A mercury(II)-radical complex with a 1D ladder structure

Interaction of HgI₂ with a new long rigid nitronyl nitroxide radical ligand, 2-[4-(2-pyridin-4-yl-vinyl)phenyl]-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide (L), leads to the formation of the mercury-radical complex [Hg₂I₄L₂] _n (1). The single crystal structure analysis reveals that 1 exhibits a one-dimensional (1D) ladder structure. Magnetic susceptibility data of 1 were simulated by a uniform chain model composed of the NIT–NIT dimers, indicating that there exist an antiferromagnetic exchange between the nitroxides within the dimer (J ₁ = ?8.41 cm^?1) and a very weak interdimer antiferromagnetic interaction (J _c = ?0.39 cm^?1).     

更新风险模型和延迟更新风险模型中破产概率的若干结果

本文进一步研究更新风险模型和延迟更新风险模型中的破产概率ψ(χ),这里χ是保险公司的初始资本.在假定个体索赔分布是重尾的前提下,得到了与经典模型相一致的破产概率ψ(χ)的一个尾等价关系.     

阶梯电极离子阱质量分析器的结构与性能

本研究从理论上优化了一种新型结构的线型离子阱质量分析器-阶梯电极离子阱质量分析器,它是由2对阶梯电极与1对端盖电极组成。与传统平板电极矩形离子阱长阶梯电极离子阱相比,具有调节电场分布的优点,同时在几何结构设计上更接近于双曲面电极结构,但比双曲面电极更容易加工。通过改变阶梯电极结构的高度、宽度、场半径比例等几何参数,实现了对离子阱内部电场分布的优化,从而实现离子阱性能的优化。理论模拟研究结果表明,根据几何结构和电场分布优化获得的阶梯电极离子阱质量分析器(X0×Y0=9 mm×5 mm),可以在225 Da/ s 扫速下获得10150的质量分辨率。阶梯电极离子阱结构简单,分辨能力明显高于矩形离子阱。初步的实验结果表明,阶梯电极离子阱具有较好的串级质谱分析性能。     

一种含苯并菲侧基的“毛-棒”状梯形聚倍半硅氧烷LB膜研究(英文)

一种新的含烷基取代的苯并菲侧基的"毛-棒"状(hairy-rod)梯形聚倍半硅氧烷(LPSQ)可以在空气-水界面形成稳定的单分子层,研究了温度、铺展溶剂和浓度对π-A等温曲线的影响.在适当的表面压下,以甲苯为铺展溶剂该单分子层可以被成功地转移至疏水的硅片或石英片上形成均一稳定的Y-型LB膜,其紫外吸收强度在几个月内均保持不变,说明该LB膜具有良好的稳定性,AFM图像表明其形成了均一致密的膜.通过偏振紫外光谱和荧光光谱研究了其面内各向异性,发现LPSQ的分子链采取了平行于拉膜方向的优先取向,最优取向因子S为0.42.