拉脱法测液体表面张力系数的误差分析

对拉脱法测量液体表面张力系数实验的原理和仪器做了简要的介绍,并着重对该实验误差的来源进行了分析探讨。     

Ab initio study of the linear and nonlinear optical responses in BiAlO3

The linear and non-linear optical properties of BiAlO₃ are studied by employing the density functional perturbation theory within the local density and generalized gradient approximations. The computations are based on the electronic structure obtained within density functional theory. The optical properties such as the dielectric function, refractive index, spectral reflectivity, absorption coefficient and electron energy-loss spectrum are obtained in the energy region of up to 30 eV. The calculated value of the birefringence for BiAlO₃ shows that it is a uniaxial negative crystal and has a large birefringence. We also report our studies on the second harmonic generation response coefficient over a large frequency range for BiAlO₃ crystal. The predicted second-order optical spectra indicate pronounced structures related to of 1ω and 2ω frequency resonances. Furthermore, the non-linear optic and linear electro-optic coefficients are computed by employing 2n + 1 theorem applied to an electric-field dependent energy functional. The results are compared with the available calculations.     

松花江冰下声学试验技术研究

北极区域极具战略意义与商业价值,随着各国的广泛关注,针对北极地区开展的科考科研活动逐渐增多。其中北极海域的相关研究尤为重要,特别是北极水声学,是保障北极军事存在以及正常科考科研活动的重要支撑。课题组于2015年1月在哈尔滨松花江进行了冰下声学试验,主要内容包括冰下信道测试、冰层散射系数测量以及冰下水声通信试验,实现了冰下半波导现象的初步观测、冰层前向散射系数的测量、基于能量检测器的低信噪比扩频通信、基于时反镜判决反馈均衡技术的高速水声通信以及冰下12用户多址水声通信等内容。本文对本次冰下声学试验情况进行介绍,并给出了相应的试验结果及经验总结。     

遥测振动信号EMD-WVD分布应用研究

飞行器飞行试验采集的遥测振动信号频段丰富、成分构成复杂,合理有效地解读其包括的时频信息在分析飞行器结构和环境特性方面至关重要。依托经验模态分解(EMD)方法将复杂信号分解成准单分量信号,借助相关系数法将伪分量信号剔除,保证分解信号的有效性。通过EMD和 WVD方法的结合,将保留的准单分量信号进行WVD变换并做平滑伪处理,从而获得复杂信号的时频分布。EMD-WVD组合模型经在仿真信号上的应用检验,能够检测信号自身的时频特性,进一步应用其在遥测振动信号上,同平滑伪WVD抑制交叉项方法进行了比较,结果表明EMD-WVD组合模型更加有效,能够反映复杂工程信号的时频分布特性。     

Remarks on sufficient conditions for fixed points of multivalued nonexpansive mappings

In recent papers [S. Dhompongsa, T. Domínguez-Benavides, A. Kaewcharoen, A. Kaewkhao, B. Panyanak, The Jordan–von Neumann constants and fixed points for multivalued nonexpansive mappings, J. Math. Anal. Appl. 320 (2006) 916–927; S. Dhompongsa, A. Kaewcharoen, A. Kaewkhao, The Domínguez–Lorenzo condition and multivalued nonexpansive mappings, Nonlinear Anal. 64 (2006) 958–970], two sufficient conditions, namely the Domínguez–Lorenzo condition and property (D$D$), for fixed points of multivalued nonexpansive mappings are introduced. The authors also give some sufficient conditions for the Domínguez–Lorenzo condition and property (D$D$). In their proofs, it seems reasonable to use the James and von Neumann–Jordan constants. With slight modifications, significant improvements are obtained. Some new estimates are tight in Hilbert spaces.     

Synthesis of novel Y-type polyurethane containing azomethine moiety, as non-linear optical chromophore and their properties

3,4-Di-(2′-hydroxyethoxy)-4′-nitrobenzylidene II was prepared by condensation reaction of 3,4-dihydroxy-4′-nitrobenzylidene I with 1-chloro-2-ethanol. Monomer II was reacted with p-phenylene diisocyanate to yield polyurethane containing the non-linear optical chromophore 3,4-di-(2′-hydroxyethoxy)-4′-nitrobenzylidene. Polymer III shows thermal stability up to 300 °C in TGA thermogram. T_g value of the polymer obtained from DSC thermogram was 110 °C. The resulting polyurethane III was soluble in common organic solvents such as acetone, DMF and DMSO. The values of electro optic coefficient d₃₃ and d₃₁ of the poled polymer film were 3.15 × 10 ⁻⁷ and 1.5 × 10 ⁻⁷ esu, respectively.     

Syntheses and lipophilicity measurement of N/N-terminus-1,1-dihydroperfluoroalkylated α-amino acids and small peptides

(1,1-Dihydroperfluoroalkyl)phenyliodonium N,N-bis(trifluoromethylsulfonyl)imides (4, n = 0-2) were synthesized and used to transfer the corresponding 1,1-dihydroperfluoroalkyl groups to the α-amino group of (l)tyrosine. The obtained N^α-2,2,2-trifluoroethylated (l)tyrosine (6, n = 0) was further used as the N-terminus in the solid phase peptide synthesis of leucine enkephalin analogue. The lipophilicity of the N^α-1,1-dihydroperfluoroalkylated (l)tyrosines (6, n = 0-2) and N-terminus-2,2,2-trifluoroethylated leucine enkephalin analogue (7), as well as the corresponding parent compounds, was measured.     

Volumetric coefficients,internal pressure,and cohesion energy density of <Emphasis Type="Italic">n</Emphasis>-alcohols

Changes in the thermal expansion coefficient and isothermal compressibility in homological series of n-alcohols at 298 K are discussed. It is shown that only methanol exhibits abnormal behavior. Volumetric coefficients of hypothetical solvents such as pseudo-water and pseudo-methanol are determined. Internal pressure values of liquids are calculated. The internal pressure of pseudo-water exceeds that of water, whereas the situation is opposite for the cohesion energy density.     

Temperature dependencies of amide 1H- and 15N-chemical shifts in hyaluronan oligosaccharides

Temperature coefficients (Deltadelta/DeltaT) of amide chemical shifts of N-acetylglucosamine residues have been measured in a range of oligosaccharides of the important vertebrate polysaccharide hyaluronan. Odd- and even-numbered oligosaccharides with glucuronic acid, Delta-4,5-unsaturated glucuronic acid and N-acetylglucosamine at the termini were investigated. All amide proton temperature coefficients were only slightly less negative (-6.9 to - 9.1 ppb/ degrees C) than those of amide protons in free exchange with water (approximately equal to -11 ppb/ degrees C), indicating an absence of persistent intramolecular hydrogen bonds. With the exception of amide groups in reducing-terminal N-acetylglucosamine rings, all amide proton environments have the same temperature coefficient (-6.9 ppb/ degrees C), irrespective of differences in amide group chemical shifts and (3)J(HH) coupling constants, i.e. they do not sense subtle differences in orientation of the amide group. Amide nitrogen temperature coefficients report the same phenomena but with greater sensitivity. These data provide a set of reference values for temperature coefficients measured in other carbohydrates with acetamido sugars.     

最小风险组合证券非负投资比例系数的确定

研究非负投资比例系数约束条件下,实现风险最小化的组合证券投资问题.应用罚函数法,对最小风险组合证券的非负投资比例系数进行研究.实例表明:这一方法是可行的、有效的.