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41.
Donglei Sun Jiantao Fu Yinglin Lu Lijun Chen Hengliang Gong Huanhuan Zhao 《International journal of environmental analytical chemistry》2017,97(8):783-795
The neonicotinoid imidacloprid is a very important insecticide in maize cultivation in China. A laboratory experiment was conducted to investigate its absorption, transportation and distribution in maize plants. Plants were exposed to an aqueous solution of imidacloprid at five concentrations (10, 20, 50, 100 and 200 μg/mL). The residues of imidacloprid in different plant parts were determined by using a quick and effective method of high-performance liquid chromatography. Results showed that the average recoveries ranged from 85.16% to 102.23%, with relative standard deviations of 1.82–4.40% at three different spiking levels in each different matrix. The half-lives of imidacloprid in hydroponic maize water were from 5.33 to 11.55 days. The concentrations in roots, stems and leaves were from 5.61 to 7.48, 1.03 to 4.03 and 0 to 30.57 μg/mL after 6 h–7 days exposed in 10 μg/mL imidacloprid aqueous solutions, respectively. Our study showed that imidacloprid was strongly absorbed by roots and mainly accumulated in leaves. Quantity ratio and bioconcentration factors (BCFs) were also used to estimate the distribution and accumulation in maize. The values of quantity ratios were the highest in the leaves while lowest in the root after 7 days treatments, with the ranking of leaves > stem > root. The BCFs were 0.63–1.66, 0.52–0.92 and 3.20–6.78 in root, stem and leaves, respectively. These results demonstrated that the exposed time and imidacloprid application concentrations were also the main factors influencing the absorption. This study enhances our understandings of the uptake and distribution of imidacloprid in maize plants. 相似文献
42.
43.
运用第一性原理的密度泛函理论,结合非平衡格林函数,研究了氮原子取代掺杂手性单壁(6,3)碳纳米管的电子结构和输运特性.计算结果表明:不同构形和不同数目的氮原子取代掺杂对手性碳管的输运性质有很复杂的影响.研究发现,氮原子掺杂明显改变了碳管的电子结构,使金属型手性碳管的输运性能降低,电流-电压曲线呈非线性变化,而且输运性能随着杂质原子间间距的变化而发生显著改变.在一定条件下,金属型碳管向半导体型转变.
关键词:
手性单壁碳纳米管
氮掺杂
电子结构
输运性能 相似文献
44.
In this work, we will take the standard Gaussian measure as the reference measure and study the variation of optimal transport maps in Sobolev spaces with respect to it; as a by-product, an inequality which gives a precise link between the variation of entropy, Fisher information between source and target measures, with the Sobolev norm of the optimal transport map will be given. As applications, we will construct strong solutions to Monge–Ampère equations in finite dimension, as well as on the Wiener space, when the target measure satisfies the strong log-concavity condition. A result on the regularity on the optimal transport map on the Wiener space will be obtained. 相似文献
46.
提出了一种新的能反映决策者满意度的随机变量序关系,并据此研究了随机不等式的确定性等价类,方法被称为满意度方法.最后将其应用于带凹性生产成本运输问题的求解中,并将方法与常用的机会约束方法进行比较,说明满意度法不仅合理可行,而且当决策者对约束条件的要求越高时,它所得最优值越优于机会约束法所得最优值. 相似文献
47.
Wei LIU 《应用数学学报(英文版)》2011,(4)
In this paper,based on the recent results of Gozlan and Léonard we give optimal transportationentropy inequalities for several usual distributions on R,such as Bernoulli,Binomial,Poisson,Gamma distributions and infinitely divisible distributions with positive or negative jumps. 相似文献
48.
《Optimization》2012,61(6):879-888
A variant for checking a solvability eriterion for multilevel multisort transportation problem is given. 相似文献
49.
城市交通疏导的优化算法及应用研究 总被引:1,自引:0,他引:1
城市交通是一个随机性很强、复杂的系统.影响城市交通顺畅的因素很多,针对目前交通存在的问题,由具体实例到抽象特性,从城市局部到整体进行了研究分析.在现有硬件设施的基础上,采用最优化算法,对比现有算法存在的缺点提出新的优化策略,便于智能交通管理. 相似文献
50.
J. C. Raines J. P. Schmidt J. P. Burelbach H. K. Fauske 《Journal of Thermal Analysis and Calorimetry》2006,85(1):53-55
Hydrogen
peroxide is a very versatile oxidizing agent, and it is also environmentally
compatible considering that the products of its exothermic decomposition are
oxygen and water.When kept in a clean temperature-controlled environment,
the self-reaction (decomposition) rate is extremely low. However, it is well
known that even a small amount of contamination will dramatically increase
the reaction rate. This paper describes the use of the fast thermal activity
interpreter (FTAI) instrument to examine the chemical reactivity of commercially
available 50% hydrogen peroxide at two different temperatures (30 and 40°C)
both with and without contamination. The results show that at 30°C a small
amount of rust (330 ppm) increases the reaction rate of 50% hydrogen peroxide
by a factor of 50. When the temperature is increased to 40°C, the reaction
rate is further increased by almost a factor of four. The implication for
reactivity management is that at this contamination level most practical vessel
sizes would require emergency venting capability.
An evaluation
was then performed to determine the emergency venting requirement for the
safe transportation or storage of the contaminated hydrogen peroxide. It was
determined that for quantities of the material less than 5 gallons, conventional
breather vents would be sufficient to accommodate the gas evolved. However,
for larger quantities, a safety relief device would be needed. For example,
for a 400-gallon tote bin at 40°C the required minimum vent area is estimated
to be 4.3 in2, corresponding to a minimum vent
diameter of 2.3 inches. 相似文献