On the uniqueness of measuring elastoplastic properties from indentation: The indistinguishable mystical materials

Indentation is widely used to extract material elastoplastic properties from the measured force-displacement curves. One of the most well-established indentation techniques utilizes dual (or plural) sharp indenters (which have different apex angles) to deduce key parameters such as the elastic modulus, yield stress, and work-hardening exponent for materials that obey the power-law constitutive relationship. However, the uniqueness of such analysis is not yet systematically studied or challenged. Here we show the existence of “mystical materials”, which have distinct elastoplastic properties yet they yield almost identical indentation behaviors, even when the indenter angle is varied in a large range. These mystical materials are, therefore, indistinguishable by many existing indentation analyses unless extreme (and often impractical) indenter angles are used. Explicit procedures of deriving these mystical materials are established, and the general characteristics of the mystical materials are discussed. In many cases, for a given indenter angle range, a material would have infinite numbers of mystical siblings, and the existence maps of the mystical materials are also obtained. Furthermore, we propose two alternative techniques to effectively distinguish these mystical materials. The study in this paper addresses the important question of the uniqueness of indentation test, as well as providing useful guidelines to properly use the indentation technique to measure material elastoplastic properties.     

On oblique contact of creeping solids

Oblique indentation of power-law creeping solids by a rigid die is analysed in three dimensions with perfectly plastic behaviour emerging as an asymptotic case. Indenter profiles are prescribed to be axisymmetric for simplicity but not by necessity. Invariance and generality is aimed at, as the problem is governed by only four essential parameters, i.e. the die profile, p, the indentation angle, γ, the power-law exponent, n, and the coefficient of friction, μ. The solution strategy is based on a self-similar transformation resulting in a reduced problem corresponding to flat die indentation of complete contact. The reduced auxiliary problem, being independent of loading, history and time, was solved by a three-dimensional finite element analysis characterized by high accuracy. Subsequently, cumulative superposition was used to resolve the original problem and global and invariant relations between force, depth and contact area were determined. Detailed results are given for the location and shape of the contact region and stick/slip contours as well as for local states of surface stresses and deformation at flat and spherical indenters. Due to the asymmetry prevailing, it was found that in the spherical case, contact contours proved to be oval and shifted, although with normal and tangential forces only weakly coupled. Finite friction as compared to full adhesion proved to have only a minor effect on global relations. The framework laid down may be applied to the contact of structural assemblies subjected especially to elevated temperatures and also to various issues such as compaction of powder aggregates, flattening of rough surfaces and plastic impact.     

Influence of friction in material characterization in microindentation measurement

A comprehensive computational study is undertaken to identify the influence of friction in material characterization by indentation measurement based on elasto- plastic solids. The impacts of friction on load versus indentation depth curve, and the values of calculated hardness and Young’s modulus in conical and spherical indentations are shown in this paper. The results clearly demonstrate that, for some elasto-plastic materials, the curves of load versus indentation depth obtained either by spherical or conical indenters with different friction coefficients, cannot be distinguished. However, if utilizing the parameter β (see text for details), to quantify the deformation of piling-up or sinking-in, it is easy to find that the influence of friction on piling-up or sinking-in in indentation is significant. Therefore, the material parameters which are related to the projected area will also have a large error caused by the influence of friction. The maximum differences on hardness and Young’s modulus can reach 14.59% and 6.78%, respectively, for some elastic materials shown in this paper. These results do not agree with those from researchers who stated that the instrumented indentation experiments are not significantly affected by friction.     

Characterization by ultra-micro indentation of an oxidized epoxy polymer: Correlation with the predictions of a kinetic model of oxidation

This study aims to understand better the influence of thermo-oxidation on the degradation of an epoxy resin used as the matrix of aeronautical composite laminates. Neat epoxy resin plates have been aged at 150 °C, under vacuum and ambient air. Using an instrumented ultra-micro indentation device, modifications of mechanical properties due to oxidation at elevated temperature are characterized through the measurements of elastic indentation modulus, Vickers hardness and indentation creep. By using a kinetic model of oxidation developed specifically for this epoxy resin, the local values of oxidation product concentration are calculated and correlated to experimental indentation measurements.     

Numerical and experimental investigations of micromechanical processes during wire sawing

In the following paper the mechanisms of the slurry-based wire sawing process at micro level are studied by numerical simulations. For the simulation a new approach in simulating the wire sawing process is presented. A discrete element method (DEM) with polyhedral particles is used to simulate the movement of the abrasive particles as well as the wire during the process. The results are verified by direct observations of the sawing channel of an experimental setup. The presented numerical model is applied for a detailed study of the influence of different process parameters.     

Crack propagation in glass coatings under expanding spherical contact

The growth of transverse cracks under expanding spherical contact in a model system consisted of soda-lime glass bonded to a polycarbonate substrate is observed in situ from below or from the polished edge of the bilayer. Abrasion or chemical etching is employed on the coating surfaces to control the initial fracture. In the limit case of monoliths, the crack mouth becomes fully engulfed by the expanding contact, which results in a much steeper crack angle compared to the classical Hertzian cone case. As the coating thickness is reduced, flexure stresses are set in the coating which drive the cone crack to well away from the contact circle and initiate semi-elliptical-like radial cracks at the subsurface, right under the contact. Common to all three fracture modes is an initial unstable propagation phase following by a stable growth, with detrimental failure associated with severe damage to the top surface and/or delamination at the coating/substrate interface taking place at loads several times the fracture initiation loads.LEFM in conjunction with a large-strain FEM contact code is used to study the post-initiation fracture, with the crack path controlled by the principal stress trajectory or zero-mode II S.I.F. The analysis exposes the leading geometric and material parameters in each fracture mode, which may be useful in the design of bilayer structures for optimal mechanical performance. The well-known Auerbach law governing the initial fracture of monoliths is found to apply also to the bilayer crack systems within a certain range of the problem parameters. The numerical prediction for the crack profiles and the fracture envelopes generally collaborate well with the tests.     

Superhard silicon nanospheres

Successful deposition and mechanical probing of nearly spherical, defect-free silicon nanospheres has been accomplished. The results show silicon at this length scale to be up to four times harder than bulk silicon. Detailed measurements of plasticity evolution and the corresponding hardening response in normally brittle silicon is possible in these small volumes. Based upon a proposed length scale related to the size of nanospheres in the 20- radii range, a prediction of observed hardnesses in the range of 20- is made. The ramifications of this to computational materials science studies on identical volumes are discussed.     

Explicit approximations of the indentation modulus of elastically orthotropic solids for conical indenters

The elastic problem of the contact between an axisymmetric indenter and a general anisotropic (21 independent elastic constants) half space has not been solved explicitly in closed form. Implicit methods to determine the indentation modulus originate from the work of Willis [J. Mech. Phys. Solids 14 (1966) 163]; and are now available for conical, parabolic and spherical indenters [Philos. Mag. A 81 (2001) 447; J. Mech. Phys. Solids 51 (2003) 1701]. The particular case of orthotropy has also been investigated [ASME J. Tribol. 115 (1193) 650, 125 (2003) 223]. This paper proposes an explicit solution for the indentation moduli of a transversely isotropic medium and a general orthotropic medium under rigid conical indentation in the three principal material symmetry directions. The half-space Green’s functions are interpolated from their exact extreme values, then integrated and finally simplified. The proposed closed form expressions are in very good agreement with the implicit solution schemes of [Philos. Mag. A 81 (2001) 447; J. Mech. Phys. Solids 51 (2003) 1701].     

Gradient plasticity constitutive model reflecting the ultrafine micro-structure scale: the case of severely deformed copper

A further development of the mechanism-based strain gradient plasticity model well established in literature is reported. The major new element is the inclusion of the cell size effect in dislocation cell forming materials. It is based on a ‘phase mixture’ approach in which the dislocation cell interiors and dislocation cell walls are treated as separate ‘phases’. The model was applied to indentation testing of copper severely pre-strained by equal channel angular pressing. The deformation behaviour and the intrinsic length scale parameter of the gradient plasticity model were related to the micro-structural characteristics, notably the dislocation cell size, resulting from the deformation history of the material.