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81.
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83.
质子探针在流体包裹体分析中的应用 总被引:3,自引:1,他引:2
本文着重阐述了质子探针无标样定量分析流体包裹体的方法原理、技术要点和分析时注意的问题。作者对我国斑岩铜矿石英中的流体包裹体进行了分析,还就国内外质子探针分析流体包裹体的现状进行了评述和展望。 相似文献
84.
建立了反相高效液相色谱法测定褪黑激素(MLT)与羟丙基-β-环糊精(HP-β-CD)、甲基-β-环糊精(M-β-CD)以及取代度为1、4、7的3种磺丁基醚-β-环糊精(SBE1-β-CD、SBE4-β-CD、SBE7-β-CD)共5种不同β-环糊精衍生物所形成的超分子包合物中褪黑激素含量的分析方法。采用Agilent Extend C18色谱柱(4.6mm×150mm,5μm),流动相为甲醇-水(40∶60),流速0.8mL/min,柱温:室温,检测波长278nm。结果表明:褪黑激素在5.05—202μg/mL浓度范围内线性关系良好(r=1.000);平均加标回收率分别为99.8%、99.0%、100.4%、99.9%、100.6%;RSD分别为0.53%、1.0%、0.71%、0.94%、0.86%。本方法可用于各类褪黑激素超分子包合物的含量分析。 相似文献
85.
采用荧光光谱法研究了β-CD衍生物对氟比洛芬的包结作用。实验考察了β-CD衍生物种类及其浓度、乙醇含量、离子强度及pH等因素对包结作用的影响。实验结果表明:随β-CD衍生物浓度的增大,荧光强度逐渐增强,其中HP-β-CD的增强效果最明显,即表明HP-β-CD对氟比洛芬的包结作用最强。1/(F-F0)对1/[CD]所作的双倒数曲线为直线,说明氟比洛芬与环糊精形成1∶1的包合物。随离子强度增大,包合作用增强;溶液中乙醇比例和pH越大,HP-β-CD与氟比洛芬包结物的包合作用越弱。 相似文献
86.
Melamine is a toxic compound to both animals and human beings, and is connected to various diseases, such as kidney stones and bladder cancer. For the efficient detection of melamine, we have developed a novel sensitive cucurbit[7]uril (CB7) sensor with a detection limit at 0.20 μg mL−1, and applied it to detect melamine in tainted milk. Fluorescence studies indicate that CB7 forms complex with melamine in a 1:1 mole ratio. The binding constant at various temperatures has been calculated and the interaction mechanism has been discussed based on molecular modeling result. 相似文献
87.
Jan Eisner 《Journal of Mathematical Analysis and Applications》2010,365(1):176-2982
We consider a reaction-diffusion system of activator-inhibitor or substrate-depletion type which is subject to diffusion-driven instability. We show that obstacles (e.g. a unilateral membrane) for both quantities modeled in terms of inequalities introduce a new bifurcation of spatially non-homogeneous steady states in the domain of stability of the trivial solution of the corresponding classical problem without obstacles. 相似文献
88.
In this paper, we consider an extension of the notion of well-posedness by perturbations, introduced by Zolezzi for a minimization problem, to a mixed variational inequality problem in a Banach space. We establish some metric characterizations of the well-posedness by perturbations. We also show that under suitable conditions, the well-posedness by perturbations of a mixed variational inequality problem is equivalent to the well-posedness by perturbations of a corresponding inclusion problem and a corresponding fixed point problem. Also, we derive some conditions under which the well-posedness by perturbations of a mixed variational inequality is equivalent to the existence and uniqueness of its solution. 相似文献
89.
Let R be a ring with unity. The inclusion ideal graph of a ring R, denoted by In(R), is a graph whose vertices are all nontrivial left ideals of R and two distinct left ideals I and J are adjacent if and only if I ? J or J ? I. In this paper, we show that In(R) is not connected if and only if R ? M 2(D) or D 1 × D 2, for some division rings, D, D 1 and D 2. Moreover, we prove that if In(R) is connected, then diam(In(R)) ≤3. It is shown that if In(R) is a tree, then In(R) is a caterpillar with diam(In(R)) ≤3. Also, we prove that the girth of In(R) belongs to the set {3, 6, ∞}. Finally, we determine the clique number and the chromatic number of the inclusion ideal graph for some classes of rings. 相似文献
90.
Fluorescence, circular dichroism and molecular mechanics have been used to study the complexation of 2,3-dimethyl naphthalenedicarboxylate
with 2-hydroxypropyl-α-, -β and -γ-cyclodextrins (HPCDs) in aqueous solution. Emission spectra upon excitation of the naphthalenedicarboxylate group show two bands whose intensity
ratio R is quite sensitive to polarity. From the change of R and lifetimes averages <τ> with HPCD concentration and temperature were obtained the stoichiometry, the association constants and the enthalpy and entropy changes
during the complexation. R, <τ> and the fluorescence anisotropies (r) extrapolated at [HPCD]→∞ allows us to estimate the polarity and microviscosity of the media surrounding the guest when complexed. In addition,
the analysis of quenching and induced circular dichroism experiments and molecular mechanics calculations in the presence
of water, provide information about the forces responsible for the complexation and the geometry of the complexes. 相似文献