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71.
Separation and concentration of sulfonylurea herbicides in milk by ionic‐liquid‐based foam flotation solid‐phase extraction 下载免费PDF全文
Liyuan Zhang Bocheng Cao Di Yao Runzhong Yu Changqing Yu Hanqi Zhang Aimin Yu 《Journal of separation science》2015,38(10):1733-1740
The ultrasound‐assisted ionic liquid foam flotation solid‐phase extraction of sulfonylurea herbicides in milk was developed and validated. The proteins and lipids were isolated from the sample matrix by adding salt and adjusting the pH value. The target analytes eluted from the solid‐phase extraction cartridge were determined by high‐performance liquid chromatography. Some experimental parameters, including the pH value of sample solution, amount of NaCl, ionic liquid type, extraction time, flow rate of carrier gas, flotation time, and solid‐phase extraction cartridge type were investigated and optimized. Under the optimized experimental conditions, the limits of detection for metsulfuron, pyrazosulfuron, chlorimuron‐ethyl, and nicosulfuron were 1.3, 0.6, 0.7, and 1.1 μg/L, respectively. When the present method was applied to the analysis of milk samples the recoveries of the analytes ranged from 84.3 to 105.2% and relative standard deviations were >5.7%. 相似文献
72.
CB[n](n=6-8) is a family of synthetic macrocyclic host molecules composed of n glycoluril units, which can be employed as molecular reactor. N-phenyloxypropyl-N'-ethyl-4,4'-bipyridium (1) was designed to form a host-guest inclusion complex with CB[n](n=6-8), subsequently, the bromination reaction of 1 and its corresponding inclusion complexes was investigated in this work. In the case of 1/CB[8], the folded including mode is quite helpful to acquire 1-bormination product completely through intramolecular charge transfer (ICT), and CB[8] can provide a safe bromination environment for 1. 相似文献
73.
A heavy and hard peak-shaped inclusion in an elastic body provokes to concentration of eigenvalues in the low-frequency range of the spectrum and localization of the corresponding eigenmodes near the peak tip. To cite this article: S.A. Nazarov, C. R. Mecanique 335 (2007). 相似文献
74.
On the interaction between a dislocation and a circular inhomogeneity with imperfect interface in antiplane shear 总被引:1,自引:0,他引:1
L. J. Sudak 《Mechanics Research Communications》2003,30(1):115
The solution of appropriate elasticity problems involving the interaction between inclusions and dislocations plays a fundamental role in many practical and theoretical applications, namely, it increases the understanding of material defects thereby providing valuable insight into the mechanical behavior of composite materials.Although the problem of a three-phase circular inclusion interacting with a dislocation in antiplane shear has been presented [Xiao and Chen, Mech. Mater. 32 (2000) 485], the analysis is limited to the classical perfect bonding condition. The current paper considers the solution for a homogeneous circular inclusion interacting with a dislocation under thermal loadings in antiplane shear. The bonding along the inhomogeneity–matrix interface is considered to be imperfect with the assumption that the interface imperfections are constant. It is found that when the inhomogeneity is soft, regardless of the level of interface imperfection, the inhomogeneity will always attract the dislocation. As a result, no equilibrium positions are available. Alternatively, when the inhomogeneity is hard, an unstable equilibrium position is found which depends on the imperfect interface condition and the shear moduli ratio μ2/μ1. 相似文献
75.
Morales A Santana A Althoff G Melendez E 《Journal of organometallic chemistry》2011,696(13):2519-2527
The possible inclusion complexes of Cp2NbCl2 into calixarenes hosts have been investigated. The existence of a true inclusion complex in the solid state was confirmed by a combination of NMR, ab-initio calculations, thermogravimetric analysis, FTIR, Raman and PXRD. Ab-initio calculations, 1H NMR solution and solid state 13C CP-MAS NMR results demonstrated that p-sulfonic calix[6]arene does form an inclusion complex with Cp2NbCl2. Raman spectroscopy showed, for the inclusion compound of p-sulfonic calix[6]arene-Cp2NbCl2, a band between 500 and 850 cm−1 characteristic of Nb-O vibration. This result suggests that Nb(V) may engage in coordination with the oxygen of the sulfonate group, as part of the host-guest interaction. However, it is important to mention that the niobocene dichloride (Cp2NbCl2) dissolves in water and undergoes oxidation and hydrolysis processes to yield Cp2NbCl2(OH) species. For that reason this band does not exclude that the Nb-O band belongs to Cp2NbCl2(OH). Solid State 13C CP-MAS NMR and solution 1H NMR spectroscopies together with ab-initio results showed that Cp2NbCl2 is included in the p-sulfonic calix[6]arene cavity, with both Cp rings inside the cavity. In contrast, the solution 1H NMR results demonstrated that calix[6]arene does not form inclusion complex with Cp2NbCl2 in CDCl3 solution. Cp2NbCl2 is not included in the calix[6]arene cavity, possibly due to the lack of sulfonate heads which promote Nb-O interactions and assist the inclusion of Cp2NbCl2 into the cavity. 相似文献
76.
En Ju Wang Guang Ying Chen 《中国化学快报》2011,22(7):847-850
The inclusion complex ofβ-cyclodextrin(β-CD) with 4-chlorobenzoic acid was synthesized and its crystal structure was determined by single crystal X-ray diffraction under cryogenic condition.The complex contains twoβ-CDs,two 4-chlorobenzoic acids and twenty-nine water molecules in the asymmetric unit,and can be formulated as 2(C42H70O35)·2(C7H5O2Cl)·29(H2O).In the crystal lattice,twoβ-CDs form a face-to-face dimer jointed together through hydrogen bonding between the secondary hydroxyl groups ofβ-CDs.Two 4-chlorobenzoic acid molecules which contact by C-Cl…πinteractions are included in theβ-CD dimer cavity.Theβ-CD dimers are arranged in brickwork-like pattern along the crystallographic a-axis.The effect of guest molecule length on the inclusion geometry was discussed by comparative study of someβ-CD complexes containing similar guests. 相似文献
77.
The consecutive k-out-of-r-from-n: F system was generalized to multi-state case. This system consists of n linearly ordered components which are at state below j if and only if at least kj components out of any r consecutive are in state below j. In this paper we suggest bounds of increasing multi-state consecutive-k-out-of-r-from-n: F system (k1 ? k2 ? ? ? kM) by applying second order Boole–Bonferroni bounds and applying Hunter–Worsley upper bound. Also numerical results are given. The programs in V.B.6 of the algorithms are available upon request from the authors. 相似文献
78.
Ionic liquid–salt aqueous two-phase flotation (ILATPF) is a novel, green, non-toxic and sensitive samples pretreatment technique. ILATPF coupled with high-performance liquid chromatography (HPLC) was developed for the analysis of chloramphenicol, which combines ionic liquid aqueous two-phase system (ILATPS) based on imidazolium ionic liquid (1-butyl-3-methylimidazolium chloride, [C4mim]Cl) and inorganic salt (K2HPO4) with solvent sublation. In ILATPF systems, phase behaviors of the ILATPF were studied for different types of ionic liquids and salts. The sublation efficiency of chloramphenicol in [C4mim]Cl–K2HPO4 ILATPF was influenced by the types of salts, concentration of K2HPO4 in aqueous solution, solution pH, nitrogen flow rate, sublation time and the amount of [C4mim]Cl. Under the optimum conditions, the average sublation efficiency is up to 98.5%. The mechanism of ILATPF contains two principal processes. One is the mechanism of IL–salt ILATPS formation, the other is solvent sublation. This method was practical when applied to the analysis of chloramphenicol in lake water, feed water, milk, and honey samples with the linear range of 0.5–500 ng mL−1. The method yielded limit of detection (LOD) of 0.1 ng mL−1 and limit of quantification (LOQ) of 0.3 ng mL−1. The recovery of CAP was 97.1–101.9% from aqueous samples of environmental and food samples by the proposed method. Compared with liquid–liquid extraction, solvent sublation and ionic liquid aqueous two-phase extraction, ILATPF can not only separate and concentrate chloramphenicol with high sublation efficiency, but also efficiently reduce the wastage of IL. This novel technique is much simpler and more environmentally friendly and is suggested to have important applications for the concentration and separation of other small biomolecules. 相似文献
79.
Juan Gu Shao‐Ming Chi Yong Zhao Ping Zheng Qiong Ruan Yan Zhao Hong‐You Zhu 《Helvetica chimica acta》2011,94(9):1608-1617
The inclusion‐complexation behavior of coenzyme Q10 (CoQ10) with the three polyamine‐modified β‐cyclodextrins (CDs) 1 – 3 was investigated in both solution and the solid state by means of NMR, XRD, and FT‐IR spectroscopy. The results showed that the apparent solubility of CoQ10 increased linearly upon addition of hosts 1 – 3 , giving AL‐type phase‐solubility curves. These hosts 1 – 3 were able to solubilize CoQ10 to high levels, up to 1.35, 1.52, and 1.44 mg/ml (calculated as CoQ10), respectively. The host 2 with a moderate‐length chain is the most suitable for inclusion complexation of CoQ10. Accroding to the ROESY experiments, the MeO groups of CoQ10 and the tether of 2 can be co‐included into the cavity of β‐CD through the induced‐fit interaction between host and guest. The binding ability of modified β‐CDs 1 – 3 upon complexation with CoQ10 are discussed from the viewpoints of the size/shape‐matching relationship and the induced‐fit concept between host CDs and guest CoQ10 molecule. 相似文献
80.
The interactions of hydroxypropyl-α-cyclodextrin (HP-α-CD) with 1-alkanols and with some α,ω-alkanediols have been studied by calorimetric titration at 298.15 K. This technique enables the determination of the enthalpy and association constant for the complex formation, from which Gibbs energy and entropy can be derived. The results are compared to those reported for the complex formation between the native α-cyclodextrin (α-CD) and 1-alkanols or α,ω-alkanediols in the literature. Thermodynamic parameters corresponding to the transfer process of the alkanol from the native to the modified α-CD are also calculated. The results clearly show that the hydrophobic interactions are important in this process, but there are other effects like the size of the alkanol that are also of some importance. 相似文献