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91.
We have studied antimony and selenium atomization processes including a chemical matrix modifier (palladium-containing activated
carbon) during their determination by electrothermal atomic absorption spectrometry. We have developed and fine-tuned an experimental
setup for determining the kinetic characteristics (activation energy and frequency factor) for element atomization processes
from measurements in the initial section of the analytical signal. We provide a rationale for the most likely mechanism for
the interactions that occur. The results of the kinetic studies of the atomization processes showed that the modifier we developed
was highly effective, as a result of formation of a thermally stable condensed system C-Pd-A (where A is the analyte).
__________
Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 73, No. 4, pp. 530–534, July–August, 2006. 相似文献
92.
讨论了刚性常微分方程组(1)的解析解和数值解,给出了解的一般形式和应用该算法的数值例子. 相似文献
93.
由于储存环中各种元件误差的存在, 机器的实际运行模式与设计模式有一定的偏差. 目前广泛开展的响应矩阵方法研究, 可以分析出磁铁元件以及束流位置测量元件的误差, 使束流基本参数得到校正. 介绍了用响应矩阵分析方法, 在BEPC储存环上进行的局部轨道校正的实验研究, 以及BEPC储存环束流参数校正的模拟研究. 相似文献
94.
对称正交反对称矩阵反问题解存在的条件 总被引:25,自引:1,他引:24
戴华 《高等学校计算数学学报》2002,24(2):169-178
矩阵反问题和矩阵特征值反问题在科学和工程技术中具有广泛的应用,有关它们的研究已取得了许多进展[1,2].[3]和[4]分别研究了反对称矩阵反问题和双反对称矩阵特征值反问题等.本文研究一类更广泛的对称正交反对称矩阵反问题.用Rn×m(Cn×m)表示n×m实(复)矩阵的全体,ASRn×n表示n阶反对称矩阵的全体,ABSRn×n表示n阶双反对称矩阵的全体,ORn×n表示n阶正交矩阵的全体.A+表示矩阵A的Moore-Penrose广义逆.In表示n阶单位矩阵.ei表示n阶单位矩阵的第i列,Sn=[en,en-1, 相似文献
95.
S. M. Arabei D. V. Novik T. A. Pavich K. N. Solov’ev 《Journal of Applied Spectroscopy》2006,73(4):511-521
We have studied the fluorescence and fluorescence excitation spectra at 300 K, 77 K, and 4.2 K for silicate gel matrices colored
with meso-tetrapropylporphin by impregnation of the matrix with a solution of the pigment. Comparison of the data obtained
with the absorption spectra in acidified solutions and analysis of the low-temperature fine-structure vibronic spectra, and
also taking into account data obtained earlier for octaethylporphin in a xerogel showed formation of two cationic forms of
meso-tetrapropylporphin in the gel matrix: the short-wavelength form has a dicationic structure, while the long-wavelength form
has a monocationic structure. We have traced out the correlations of the vibrational structure in the spectra of the dicationic
form with data for the porphin dication, and we have drawn a number of conclusions concerning the normal vibrational modes
that are active in the vibronic fluorescence and absorption spectra of the studied cationic forms. Using the AM1 semiempirical
quantum chemical method, we optimized the geometry of the mesotetrapropylporphin dication: the most stable of the possible
conformers is the dication structure with saddleshaped macrocycle nonplanarity.
__________
Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 73, No. 4, pp. 453–461, July–August, 2006. 相似文献
96.
97.
Yongge Tian 《Journal of Mathematical Analysis and Applications》2002,266(2):333-341
We present an alternative expression for the parallel sum of k Hermitian nonnegative definite matrices by using the Moore-Penrose inverse of a block matrix. 相似文献
98.
99.
CHENDAOQI 《高校应用数学学报(英文版)》1994,9(1):35-43
In this paper, the normative matrices and their double LR transformation with origin shifts are defined, and the essential relationship between the double LR transformation of a normative matrix and the QR transformation of the related symmetric tridiagonal matrix is proved. We obtain a stable double LR algorithm for double LR transformation of normative matrices and give the error analysis of our algorithm. The operation number of the stable double LR algorithm for normative matrices is only four sevenths of the rational QR algorithm for reed symmetric tridiagonal matrices. 相似文献
100.
TAN Xiaojiang 《数学年刊B辑(英文版)》2002,23(4):531-538
Lei X be an arbitrary smooth irreducible complex projective curve, E (?) X a rank two vector bundle generated by its sections. The author first represents E as a triple {D1,D2,f}, where D1 , D2 are two effective divisors with d = deg(D1) + deg(D2), and f ∈ H0(X, [D1] |D2) is a collection of polynomials. E is the extension of [D2] by [D1] which is determined by f. By using f and the Brill-Noether matrix of D1 + D2, the author constructs a 2g X d matrix WE whose zero space gives Im{H0(X,[D1]) (?) H0(X, [D1] |D1)}(?)Im{H0(X, E) (?) H0(X,[D2]) (?) H0(X,[D2] |D2)}. From this and H0(X,E) = H0(X, [D1]) (?) Im{H0(X, E) (?) H0(X, [D2])}, it is got in particular that dimH0(X, E) = deg(E) - rank(WE) + 2. 相似文献